非贵金属催化剂催化硼氢化钠水解制氢的研究进展

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Abstract Hydrogen production by hydrolysis of sodium borohydride has the advantages of safety and convenience, moderate hydrogen release temperature, easy control of the reaction, and high purity of hydrogen production. It has become a research hotspot in hydrogen production technology. Hydrogen production speed of pure sodium borohydride hydrolysis is slow and the hydrogen production rate is low. Suitable catalysts are often added to improve the rate of hydrogen liberation from sodium borohydride hydrolysis. Metal catalysts have been widely studied because of their high catalytic activity. Among them, noble metals limit their use due to their high prices, while non-noble metals are low in price and high in reserves. Moreover, in recent years, studies have found that the catalytic activity of some non-noble metal catalysts has been significantly improved. Therefore, from an economic point of view, it is highly desirable to use non-noble metals to catalyze the hydrolysis of sodium borohydride to produce hydrogen. In this paper, the research progress of unsupported catalysts and supported catalysts was introduced based on the development status of non-noble metal catalysts for hydrolysis of sodium borohydride at home and abroad in recent years, and its future development trend was prospected.

Key words： catalyst non-noble metals hydrolysis hydrogen production sodium borohydride

Published: 16 July 2021

CLC number:	O643.36
	TQ116.2

Fund:Sichuan Provincial Department of Education (18ZB0133), Sichuan Province Engineering Center for Powder Metallurgy(SC-FMYJ2018-05), Sichuan Applied Basic Research Program (2018JY0062) and Chengdu University Research Project (2018XZB17).

About author:: Xiaolian Wang received his Ph.D. degree in materials science from the School of Materials Science and Engineering, Sichuan University, in 2016. He is currently a full teacher in Chengdu University. His research inte-rests are hydrogen energy and fuel cell technology, powder metallurgy materials and quantum chemical calculations.Mao Yang received his B.S. degree from Chengdu University in 2020. He is currently pursuing his M.E. at the School of Mechanical Engineering, Chengdu University under the supervision of Dr. Xiaolian Wang. His research has focused on chemical hydrogen storage mate-rials.。

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	WANG Xiaolian
	YANG Mao
	LIU Yonghui
	ZHANG Yubin
	FENG Wei

Cite this article:

WANG Xiaolian,YANG Mao,LIU Yonghui, et al. Research Progress of Hydrogen Production by Hydrolysis of Sodium Borohydride Catalyzed by Non-Noble Metal Catalysts[J]. Materials Reports, 2021, 35(Z1): 21-28.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/21

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