PbO2-MnO2共沉积电化学行为研究*

doi:10.11896/j.issn.1005-023X.2017.08.008

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Abstract The influences of concentration of Mn(NO₃)₂, HNO₃, Pb(NO₃)₂ and solution temperature on PbO₂-MnO₂ co-de-position were studied by cyclic voltammetry using rotating disk electrode, and the theoretical optimum conditions of the PbO₂ and MnO₂ co-deposition were obtained. The experiments concerning the effects of rotation rate of the electrode on the co-deposition process of PbO₂ and MnO₂ indicate that the behavior of PbO₂ and MnO₂ co-deposition process is mainly determined by the electrochemical process. Scanning electron microscopy (SEM) was applied to observe the surface morphology of PbO₂-MnO₂ layer and the results confirmed the spherical structure of the PbO₂-MnO₂ layer. Besides, a ternary-phase-mixed crystal phase of α-MnO₂, α-PbO₂ and β-PbO₂ in the PbO₂-MnO₂ layer was detected by X-ray diffraction (XRD) technology.

Key words： rotating disk electrode lead dioxide manganese dioxide cyclic voltammetry

Published: 25 April 2017 Online: 2018-05-02

CLC number:

TQ153.2

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	Articles by authors
	WANG Jiong
	XU Ruidong
	YU Bohao
	HAN Sha
	HE Shiwei
	CHEN Buming

Cite this article:

WANG Jiong,XU Ruidong,YU Bohao, et al. Investigation on Electrochemical Behavior of PbO₂ and MnO₂ Co-deposition[J]. Materials Reports, 2017, 31(8): 35-40.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.08.008 OR https://www.mater-rep.com/EN/Y2017/V31/I8/35

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