层层自组装技术的研究进展及应用情况<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.05.007

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Abstract The layer-by-layer self-assembly method is a fast developing technique. Compared with the traditional film forming technology, the assembly materials of LbL is varied (such as polyelectrolyte, nanoparticles and organic small molecules) and LbL can control precisely surface structure and size of thin film using template. Film performance and mechanical performance can be fully assembled by controlling materials, the number of sediments, the assembly condition, etc. Based on this, the layer-by-layer self-assembly method is reviewed according to the type of self-assembly interaction and its application in electrochemical capacitor, photosensitive microcapsule, separation membrane, biological chemistry and drug release. Furthermore, the development prospect was described in the paper.

Key words： layer-by-layer self-assembly thin film electrochemical capacitor photosensitive microcapsule biosensor separation membrane bioreactor drug release

Published: 10 March 2017 Online: 2018-05-02

CLC number:

O631

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	ZHANG Zhongda
	YANG Wenfang

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ZHANG Zhongda,YANG Wenfang. Research Progress and Application of Layer-by-layer Self-assembly Technology[J]. Materials Reports, 2017, 31(5): 40-45.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.05.007 OR https://www.mater-rep.com/EN/Y2017/V31/I5/40

1 Ariga K, Hill J P, Lee M V, et al. Challenges and breakthroughs in recent research on self-assembly[J]. Sci Technol Adv Mater,2008,9(1):70.
2 Mai Y, Eisenberg A. Self-assembly of block copolymers[J]. Chem Soc Rev,2012,41(18):5969.
3 Babu S S, Prasanthkumar S, Ajayaghosh A. Self-assembled gelators for organic electronics[J]. Angew Chem Int Ed,2012,51(8):1766.
4 Ramanathan M, S Michael Kilbey I I, Ji Q, et al. Materials self-assembly and fabrication in confined spaces[J]. J Mater Chem,2012,22(21):10389.
5 Iler R K. Multilayers of colloidal particles[J]. J Colloid Interface Sci,1966,21(6):569.
6 Baumeister W, Vogell W. Electron microscopy at molecular dimensions: State of the art and strategies for the future [M]. Berlin: Springer,1980.
7 Gölander C G, Arwin H, Eriksson J C, et al. Heparin surface film formation through adsorption of colloidal particles studied by ellipsometry and scanning electron microscopy[J]. Colloids Surf,1982,5(1):1.
8 Decher G, Hong J D, Schmitt J. Buildup of ultrathin multilayer films by a self-assembly process: Ⅲ. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces[J]. Thin Solid Films,1992,210:831.
9 Decher G, Lehr B, Lowack K, et al. New nanocomposite films for biosensors: Layer-by-layer adsorbed films of polyelectrolytes, proteins or DNA[J]. Biosensors Bioelectron,1994,9(9):677.
10 Donath E, Sukhorukov G B, Caruso F, et al. Novel hollow polymer shells by colloid-templated assembly of polyelectrolytes[J]. Angew Chem Int Ed,1998,37(16):2201.
11 Caruso F, Caruso R A, Möhwald H. Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating[J]. Science,1998,282(5391):1111.
12 Decher G. Fuzzy nanoassemblies: Toward layered polymeric multicomposites[J]. Science,1997,277(5330):1232.
13 Lvov Y, Ariga K, Ichinose I, et al. Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption[J]. J Am Chem Soc,1995,117(22):6117.
14 Caruso R A, Susha A, Caruso F. Multilayered titania, silica, and laponite nanoparticle coatings on polystyrene colloidal templates and resulting inorganic hollow spheres [J]. Chem Mater,2001,13(2):400.
15 Hansda C, Dutta B, Chakraborty U, et al. Photophysical behavior of layer-by-layer electrostatic self-assembled film of azo dye chromotrope-2R and a polycation[J]. J Luminescence, 2016,178:347.
16 Tong Weijun, Gao Changyou. Layer-by-layer assembled microcapsules: Fabrication, stimuli-responsivity, loading and release[J]. Chem J Chin Universities,2008(7):1285(in Chinese).
仝维鋆,高长有. 层层组装微胶囊的制备及其智能响应与物质包埋释放性能[J]. 高等学校化学学报,2008(7):1285.
17 Wang L, Wang Z, Zhang X, et al. A new approach for the fabrication of an alternating multilayer film of poly (4-vinylpyridine) and poly (acrylic acid) based on hydrogen bonding[J]. Macromol Rapid Commun,1997,18(6):509.
18 Hwangbo S, Jeong H, Heo J, et al. Antibacterial nanofilm coatings based on organosilicate and nanoparticles[J]. Reactive Funct Polym,2016,102:27.
19 Sham A Y W, Notley S M. Graphene-polyelectrolyte multilayer film formation driven by hydrogen bonding[J]. J Colloid Interface Sci,2015,456:32.
20 Sukhishvili S A, Granick S. Layered, erasable, ultrathin polymer films[J]. J Am Chem Soc,2000,122(39):9550.
21 Sukhishvili S A, Granick S. Layered, erasable polymer multilayers formed by hydrogen-bonded sequential self-assembly[J]. Macromo-lecules,2002,35(1):301.
22 Meier H. Conjugated oligomers with terminal donor-acceptor substitution[J]. Angew Chem Int Ed,2005,44(17):2482.
23 Shimazaki Y, Nakamura R, Ito S, et al. Molecular weight depen-dence of alternate adsorption through charge-transfer interaction[J]. Langmuir,2001,17(3):953.
24 Wang Yibing, Lu Fei, Wei Pinghui, et al. Preparation and spectroscopic study of the self-assembled monolayer of TCNQ and TMB[J]. J Light Scattering,2006,18(2):151(in Chinese).
王一兵,芦菲,魏平慧,等.TCNQ 和 TMB 电荷转移配合物自组装膜的制备及光谱研究[J]. 光散射学报,2006,18(2):151.
25 Zhang Y, He H, Gao C, et al. Covalent layer-by-layer functionalization of multiwalled carbon nanotubes by click chemistry[J]. Langmuir,2009,25(10):5814.
26 Li Y, An Q, Hu Y, et al. A facile method for the construction of covalently cross-linked layered double hydroxides layer-by-layer films: Enhanced stability and delayed release of guests[J]. Chem Phys Lett,2015,631:118.
27 Amigoni S, Taffin de Givenchy E, Dufay M, et al. Covalent layer-by-layer assembled superhydrophobic organic-inorganic hybrid films[J]. Langmuir,2009,25(18):11073.
28 Li D Q, Smith D C, Swanson B I, et al. Synthesis and properties of novel ruthenium thin-film materials: Self-assembled multilayer approaches[J]. Chem Mater,1992,4(5):1047.
29 Liu M, Kira A, Nakahara H. Silver (I) ion induced monolayer formation of 2-substituted benzimidazoles at the air/water interface[J]. Langmuir,1997,13(18):4807.
30 Wei Tong, Su Baowei, Gao Xueli, et al. Layer by layer self-assembly forward osmosis membrane preparation based on coordination[J]. Membrane Sci Technol,2015(5):35(in Chinese).
魏桐,苏保卫,高学理,等.基于配位作用的层层自组装正渗透膜及其制备方法[J].膜科学与技术,2015(5):35.
31 Yu B, Liu X, Cong H, et al. Fabrication of stable ultrathin transparent conductive carbon nanotube micropatterns using layer-by-la-yer self-assembly[J]. Fullerenes, Nanotubes Carbon Nanostructures,2015,23(4):320.
32 Gao Lizhen. “Host-guest chemistry”, “supramolecular chemistry” and “heterogeneous catalysis”[J]. Chin J Chem Education,1990,11(1):12(in Chinese).
高利珍.“主—客体化学”、“超分子化学”与“多相催化”[J]. 化学教育,1990,11(1):12.
33 Li Huimei. Wang Jie, Ni Yunzhou, et al. Synthesis of a linear-hyperbranched supramolecular polymer and its light-responsive self-assembly behavior[J]. Acta Chim Sin,2016,74(5):415(in Chinese).
李惠梅,王洁,倪云洲,等.“线性-超支化” 超分子聚合物的制备及光响应性自组装行为研究[J]. 化学学报, 2016,74(5):415.
34 Zhang Wanzhen, Cheng Cong, Zhang Hongsu, et al. Preparation and characterization of surface-modified poly (ethylenimine)-methoxy poly (ethylene glycol) /α-cyclodextrin hollow microsphere[J]. Polym Mater Sci Eng,2014(8):119(in Chinese).
张婉贞,程从,张红素,等.表面改性聚乙烯亚胺-聚乙二醇/α-环糊精空心微球的制备与表征[J].高分子材料科学与工程,2014 (8):119.
35 Yu G, Xue M, Zhang Z, et al. A water-soluble pillar [6] arene synthesis, host-guest chemistry, and its application in dispersion of multiwalled carbon nanotubes in water[J]. J Am Chem Soc,2012,134(32):13248.
36 Yue Shiyu, Zhou Yujuan, Yao Yong, et al. Pillar[n]arenes: From synthesis, host-guest chemistry to self-assembly properties and applications[J]. Acta Chimica Sinica,2014,72(10):1053(in Chinese).
岳诗雨,周玉娟,姚勇,等.柱芳烃化学: 从合成, 主客体性质到自组装性能的研究进展[J].化学学报,2014,72(10):1053.
37 Bowden N B,Weck M,et al.Molecule-mimetic chemistry and mesoscale self-assembly[J]. Accounts Chem Res,2001,34(3):231.
38 Bico J, Roman B, Moulin L, et al. Adhesion: Elastocapillary coalescence in wet hair[J]. Nature,2004,432(7018):690.
39 Wang F, Ma N, Chen Q, et al. Halogen bonding as a new driving force for layer-by-layer assembly[J]. Langmuir,2007,23(19):9540.
40 Johnston A P R, Mitomo H, Read E S, et al. Compositional and structural engineering of DNA multilayer films[J]. Langmuir,2006,22(7):3251.
41 Pereira E. Enhancement of the poly (o-methoxyaniline)-poly (3-thiophene acetic acid) self-assembled electrochemical capacitor stabi-lity[C]//229th ECS Meeting. San Diego,2016.
42 Lee T, Yun T, Park B, et al. Hybrid multilayer thin film supercapacitor of graphene nanosheets with polyaniline importance of establishing intimate electronic contact through nanoscale blending[J]. J Mater Chem,2012,22(39):21092.
43 Zhao J, Fei J, Gao L, et al. Bioluminescent microcapsules: Applications in activating a photosensitizer[J]. Chemistry—A Eur J,2013,19(14):4548.
44 Chen P Y, Ladewski R, Miller R, et al. Layer-by-layer assembled porous photoanodes for efficient electron collection in dye-sensitized solar cells[J]. J Mater Chem A,2013,1(6): 2217.
45 Zou Jian, Sun Benhui, Chen Cuixian. Polyelectrolyte membranes for pervaporation[J]. Polym Bull,2001(5):44(in Chinese).
邹健,孙本惠,陈翠仙.聚电解质渗透汽化膜[J]. 高分子通报,2001(5):44.
46 Kraus W,Nolze G.Powder cell-A program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns[J]. J Appl Crystallography,1996,29(3):301.
47 Stroeve P, Vasquez V, Coelho M A N, et al. Gas transfer in supported films made by molecular self-assembly of ionic polymers[J]. Thin Solid Films,1996,284:708.
48 Du Zi’ang, Qin Zhenping, Guo Hongxia, et al. Performances of PDDA/CMCNa-PAN composite nanofiltration membrane prepared by self-assembly method[J]. Membrane Sci Technol,2015,35(1):64(in Chinese).
杜子昂,秦振平,郭红霞,等.静电自组装 PDDA/CMCNa 聚电解质复合纳滤膜及其性能[J]. 膜科学与技术,2015,35(1):64.
49 Kim D, Tzeng P, Barnett K J, et al. Highly size-selective ionically crosslinked multilayer polymer films for light gas separation[J]. Adv Mater,2014,26(5):746.
50 Ji Shulan, Wang Lu, Wang Naixin, et al. Covalent crosslinked assembly of multilayer organic-inorgainc compesite membranes for pervaporation performance[J]. J Beijing University of Chemical Technology,2014,40(4):634(in Chinese).
纪树兰,王路,王乃鑫,等.共价反应型多层有机-无机复合膜组装及其渗透汽化性能[J]. 北京工业大学学报,2014,40(4):634.
51 Onda M, Ariga K, Kunitake T. Activity and stability of glucose oxidase in molecular films assembled alternately with polyions[J]. J Biosci Bioeng,1999,87(1):69.
52 Sun Jun, Zhu Zhengyi, Lai Jianping, et al. Layer-by-layer assembled graphene/polyaniline nanocomposite film and applied in electrochemical sensing[J]. Chem J Chin Universities,2015,36(3):581(in Chinese).
孙军,朱正意,赖健平,等.层层自组装法制备石墨烯/聚苯胺复合薄膜及在传感器中的应用[J].高等学校化学学报,2015,36(3):581.
53 Li P, Zhang B, Cui T. TiO₂ and shrink induced tunable nano self-assembled graphene composites for label free biosensors[J]. Sensors Actuators B: Chem,2015,216:337.
54 Sakr O S, Jordan O, Borchard G. Sustained protein release from hydrogel microparticles using layer-by-layer (LbL) technology[J]. Drug Delivery,2016,23(8):2747.
55 Jiang Lei, Li Yanbao, Yao Song, et al. Synthesis of chitosan/graphene oxide microcapsules as drub carriers[J]. J Funct Mater,2015,46(16):16119(in Chinese).
蒋雷,李延报,姚松,等.作为药物载体的壳聚糖/氧化石墨烯中空微胶囊的制备[J].功能材料,2015,46(16):16119.
56 Xiao W, Chen W H, Zhang J, et al. Design of a photoswitchable hollow microcapsular drug delivery system by using a supramolecular drug-loading approach[J]. J Phys Chem B,2011,115(46):13796.