钙钛矿太阳能电池:从高效率到稳定性<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.05.003

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1496KB)
Export: BibTeX | EndNote (RIS)

Abstract Perovskite solar cells (PSCs) have attracted much attention because of its simple process, low cost, high efficiency and flexibility for devices. The conversion efficiency of perovskite solar cells has been constantly renewed in recent years. Due to its higher efficiency compared to polycrystalline silicon solar cells, perovskite solar cells have enormous potential for commercial application. However, the stability of perovskite solar cells still need further improvement. According to recent progress on perovskite solar cells, this paper describes the construction of PSCs, places emphasis on the approaches to obtaining high efficiency perovskite solar cells, and summarizes the appropriate strategies to improve the stability of perovskite solar cells. The trends in development of pero-vskite solar cells are proposed as well.

Key words： solar cell perovskite material transporting material stability high efficiency

Published: 10 March 2017 Online: 2018-05-02

CLC number:

TQ174

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	WAN Tingting
	ZHU Ankang
	GUO Youmin
	WANG Chunchang

Cite this article:

WAN Tingting,ZHU Ankang,GUO Youmin, et al. Perovskite Solar Cells: From High Efficiency to Stability[J]. Materials Reports, 2017, 31(5): 16-22.

URL:

https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.05.003 OR https://www.mater-rep.com/EN/Y2017/V31/I5/16

1 Kojima A, Teshima K, Shirai Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells [J]. J Am Chem Soc,2009,131:6050.
2 Li X, Bi D, Yi C, et al. A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells[J]. Science,2016,359(6294):58.
3 Yang W S, Noh J H, Jeon N J, et al. High-performance photovol-taic perovskite layers fabricated through intramolecular exchange [J]. Science,2015,348:1234.
4 Bai Y B, Wang Q Y, Lu R T, et al. Progress on perovskite-based solar cells[J]. Chin Sci Bull, 2016,61(Z1):489(in Chinese).
白宇冰,王秋莹,吕瑞涛,等.钙钛矿太阳能电池研究进展[J].科学通报,2016,61(Z1):489.
5 Wang Y X, Luo J, Guo P C, et al. Application and development of hybird perovskite materials in the field of solar cells[J]. J Inorg Mater,2015,30(7):673(in Chinese).
王艳香,罗俊,郭平春,等.杂化钙钛矿材料在太阳电池中的应用与发展[J].无机材料学报,2015,30(7):673.
6 Yao Xin, Ding Y L, Zhang X D, et al. A review of the perovskite solar cells[J]. Acta Phys Sin,2015,64(3):038805
7 Zhao Y, Li H, Guan L L, Wu J D, et al. Perovskite solar cells: History and latest researche[J]. Mater Rev: Rev,2015,29(6):17(in Chinese).
赵雨,李惠,关雷雷,等.钙钛矿太阳能电池技术发展历史与现状[J].材料导报:综述篇,2015,29(6):17.
8 Green M A, Ho Baillie A, Snaith H J. The emergence of perovskite solar cells[J]. Nat Photon,2014,8:506.
9 Wang D, Wright M, Elumalai N K, et al. Stability of perovskite solar cells [J]. Sol Energy Mater Sol Cells,2016,147:255.
10 Wang B, Xiao X, Chen T. Perovskite photovoltaics: A high-efficiency newcomer to the solar cell family [J]. Nanoscale,2014,6:12287.
11 Ju C G, Zhang B, Feng Y Q. Organolead halide perovskite solar cells[J]. Prog Chem,2016(2):219(in Chinese).
琚成功,张宝,冯亚青.有机卤化铅钙钛矿太阳能电池[J]. 化学进展,2016(2):219
12 Zhou H P, Chen Q, Li G, et al. Interface engineering of highly efficient perovskite solar cells[J]. Science,2014,345:542.
13 Wojciechowski K, Saliba M, Leijtens T, et al. Sub-150 ℃ processed meso-superstructured perovskite solar cells with enhanced efficiency [J]. Energy Environ Sci,2014,7:1142.
14 Im J H, Jang I H, Pellet N, et al. Growth of CH₃NH₃PbI₃ cuboids with controlled size for high-efficiency perovskite solar cells[J]. Nat Nanotechnol,2014,9:927.
15 Liu D Y, Kelly T L. Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J]. Nat Photon,2014,8:133.
16 Im J H, Lee C R, Lee J W, et al. 6.5% efficient perovskite quantum-dot-sensitized solar cell[J]. Nanoscale,2011,3:4088.
17 Kim H S, Lee C R, Im J H, et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J]. Sci Rep,2012,2:591.
18 Liu M Z,Johnston M B,Snaith H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature,2013,501:395.
19 Im J H, Kim H S, Park N G. Morphology-photovoltaic property correlation in perovskite solar cells: One-step versus two-step deposition of CH₃NH₃PbI₃[J]. APL Mater,2014,2:081510.
20 Chen C W, Kang H W, Hsiao S Y, et al. Efficient and uniform planar-type perovskite solar cells by simple sequential vacuum deposition[J]. Adv Mater,2014,26:6647.
21 Chen Q, Zhou H, Hong Z, et al. Planar heterojunction perovskite solar cells via vapor-assisted solution process[J]. J Am Chem Soc,2014,136:622.
22 Zhao Y X, Zhu K. Efficient planar perovskite solar cells based on 1.8 eV band gap CH₃NH₃PbI₂Br nanosheets via thermal decomposition [J]. J Am Chem Soc,2014,136:12241.
23 Zhao Y X, Zhu K. Three-step sequential solution deposition of PbI₂-free CH₃NH₃PbI₃ perovskite [J]. J Mater Chem A,2015,3:9086.
24 Ding H J, Ni Lu, Ma S B, et al. Progress in electron-transport materials in application of perovskite solar cells[J]. Acta Phys Sin,2015,64:038802(in Chinese).
丁雄傑,倪露,马圣博,等.钙钛矿太阳能电池中电子传输材料的研究进展[J].物理学报,2015,64:038802.
25 Conings B, Baeten L, Jacobs T, et al. An easy-to-fabricate low-temperature TiO₂ electron collection layer for high efficiency planar he-terojunction perovskite solar cells [J]. APL Mater,2014,2:081505.
26 Wang J T W, Ball J M, Barea E M, et al. Low-temperature processed electron collection layers of graphene/TiO₂ nanocomposites in thin film perovskite solar cells [J]. Nano Lett,2014,14:724.
27 Xiao Z, Dong Q, Bi C, et al. Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement [J]. Adv Mater,2014,26:6503.
28 Qin P, Domanski A L, Chandiran A K, et al. Yttrium-substituted nanocrystalline TiO₂ photoanodes for perovskite based heterojunction solar cells [J]. Nanoscale,2014,6:1508.
29 Shao Y, Yuan Y, Huang J. Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells [J]. Nat Energy,2016,1:15001.
30 Yang Y, Gao J, Cui J R, et al. Research progress of perovskite solar cells[J]. J Inorg Mater,2015,30(11):1311(in Chinese).
杨英,高菁,崔嘉瑞,等.钙钛矿太阳能电池的研究进展[J]. 无机材料学报,2015,30(11):1311
31 Song Z H, Wang S R, Xiao Y, et al. Progress of research on new hoie transporting materials used in perovskite solar cells[J]. Acta Phys Sin,2015,64(3):1(in Chinese).
宋志浩,王世荣,肖殷,等.新型空穴传输材料在钙钛矿太阳能电池中的研究进展[J].物理学报,2015,64(3):1.
32 Christians J A, Fung R C M, Kamat P V. An inorganic hole conductor for organo-lead halide perovskite solar cells: Improved hole conductivity with copper iodide[J]. J Am Chem Soc,2014,136:758.
33 Qin P, Tanaka S, Ito S, et al. Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency [J]. Nat Commun,2014,5:3834
34 Zhu Z L, Bai Y, Zhang T, et al. High-performance hole-extraction layer of sol-gel-processed NiO nanocrystals for inverted planar pe-rovskite solar cells [J]. Angew Chem,2014,126:12779.
35 Liu C,Yuan S,Zhang H L,et al.p-type CuI films grown by iodination of copper and their application as hole transporting layer for inverted perovskite solar cells[J]. J Inorg Mater,2016,31:358(in Chinese).
刘畅,苑帅,张海良,等.铜膜碘化法制备p型CuI薄膜及其用作空穴传输层的反型钙钛矿电池性能[J].无机材料学报,2016,31(4):358.
36 Yin X T, Chen P, Que M D, et al. Highly efficient flexible perovskite solar cells using solution-derived NiO_x hole contacts [J]. ACS Nano,2016,10:3630.
37 Chandiran A K, Yella A, Mayer M T, et al. Sub-nanometer conformal TiO₂ blocking layer for hgh efficiency solid-state perovskite absorber solar cells[J]. Adv Mater,2014,26:4309.
38 Ogomi Y, Kukihara K, Qing S, et al. Control of charge dynamics through a charge-separation interface for all-solid perovskite-sensitized solar cells[J]. Chem Phys Chem,2014,15:1062.
39 Dong J, Zhao Y H, et al. Impressive enhancement in the cell performance of ZnO nanorod-based perovskite solar cells with Al-doped ZnO interfacial modification [J]. Chem Commun,2014,50:13381.
40 Jeng J Y, Chen K C, Chiang T Y, et al. Nickel oxide electrode interlayer in CH₃NH₃PbI₃ perovskite/PCBM planar-heterojunction hybrid solar cells [J]. Adv Mater,2014,26:4107.
41 Laban W A, Etgar L. Depleted hole conductor-free lead halide iodide heterojunction solar cells [J]. Energy Environ Sci,2013,6:3249.
42 Noh J H, Im S H, Heo J H, et al. Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells[J]. Nano Lett,2013,13:1764.
43 Smith I C, Hoke E T, Solis Ibarra D, et al. A layered hybrid pero-vskite solar-cell absorber with enhanced moisture stability[J]. Angew Chem Int Ed,2014,53:11232.
44 Cao D H, Stoumpos C C, Farha O K, et al. 2D homologous perovskites as light-absorbing materials for solar cell applications[J]. J Am Chem Soc,2015,137:7843.
45 Kagan C R, Mitzi D B, Dimitrakopoulos C D. Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors[J]. Science,1999,286:945.
46 Tsai H, Nie W, Blancon J C, et al. High-efficiency two-dimensional Ruddlesden-Popper perovskite solar cells[J]. Nature,2016,536:312
47 Saparov B, Hong F, Sun J P, et al. Thin-film preparation and characterization of Cs₃Sb₂I₉: A lead-free layered perovskite semiconductor[J]. Chem Mater,2015,27:5622.
48 Lee J W, Kim D H, Kim H S, et al. Formamidinium and cesium hybridization for photo-and moisture-stable perovskite solar cell [J]. Adv Energy Mater,2015,5:1501310.
49 Li X, Ibrahim Dar M, Yi C, et al. Improved performance and stabi-lity of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides [J]. Nat Chem,2015,7:703.
50 Cui X M, Zuo C Y, Lan D J, et al. Preparation and electrical propertries of TiO₂/SnO₂ nanocrystalline films[J]. J Inorg Mater,2013,28(1):1233(in Chinese).
崔旭梅,左承阳,蓝德均,等.TiO₂/SnO₂纳米晶膜的制备及其电学性能研究[J].无机材料学报,2013,28(1):1233.
51 Pathak S K, Abate A, Ruckdeschel P, et al. Performance and stability enhancement of dye-sensitized and perovskite solar cells by Al doping of TiO₂ [J]. Adv Funct Mater,2014,24:6046.
52 Song J, Zheng E, Bian J, et al. Low-temperature SnO₂-based electron selective contact for efficient and stable perovskite solar cells[J]. J Mater Chem A,2015,3:10837.
53 Zhang M, Lyu M Q, Yu H, et al. Stable and low-cost mesoscopic CH₃NH₃PbI₂Br perovskite solar cells by using a thin poly (3-hexylthiophene) layer as a hole transporter [J]. Chemistry—A Eur J,2015,21:434.
54 Kim J H, Liang P W, Williams S T, et al. High-performance and environmentally stable planar heterojunction perovskite solar cells based on a solution-processed copper-doped nickel oxide hole-transporting layer [J]. Adv Mater,2015,27:695.
55 You J B, Meng L, Song T B, et al. Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers [J]. Nat Nanotechnol,2016,11:75.
56 Guarnera S, Abate A, Zhang W, et al. Improving the long-term stability of perovskite solar cells with a porous Al₂O₃ buffer layer [J]. J Phys Chem Lett,2015,6:432.
57 Ito S, Tanaka S, Manabe K, et al. Effects of surface blocking layer of Sb₂S₃ on nanocrystalline TiO₂ for CH₃NH₃PbI₃ perovskite solar cells [J]. J Phys Chem C,2014,118:16995.
58 Zheng L L, Chung Y H, Ma Y Z, et al. A hydrophobic hole transporting oligothiophene for planar perovskite solar cells with improved stability[J]. Chem Commun,2014,50:11196.