木质素基碳纤维制备的研究进展

doi:10.11896/j.issn.1005-023X.2018.03.010

Abstract
Figure/Table
References
Related Citation (15)

Download:

richhtml

Full Text ( PDF ) (1402KB)
Export: BibTeX | EndNote (RIS)

Abstract

Lignin is rich in nature, it is also renewable and with high carbon content. The application of lignin in the preparation of carbon fiber has an unparalleled cost advantage.The development of lignin-based carbon fiber is briefly introduced. The progress of the source, structure difference and carbon fiber preparation methods of kraft lignin, organosolv lignin and steam-explosion lignin is discussed in detail. As a result, the kraft lignin has been chosen as the best raw material for the preparation of low cost carbon fiber. Furthermore, the future direction of lignin-based carbon fiber is pointed out, which aims to provide reference for the initial research of lignin-based carbon fiber.

Key words： kraft lignin organosolv lignin carbon fiber preparation methods structure and properties

Published: 10 February 2018 Online: 2018-02-10

CLC number:

TB34

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Lanyan LIU
	Jun SONG
	Bowen CHENG
	Wenchi XUE
	Yunbo ZHENG

Cite this article:

Lanyan LIU,Jun SONG,Bowen CHENG, et al. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405-411.

URL:

https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.03.010 OR https://www.mater-rep.com/EN/Y2018/V32/I3/405

1	Frank E, Hermanutz F, Buchmeiser M R . Carbon fibers: Precursors, manufacturing, and properties[J]. Macromolecular Materials & Engineering, 2012,297(6):493.
2	Wei H Q, Zhang L M . Research status of lignin-based low-cost carbon fibers[J]. Synthetic Fiber in China, 2016,45(1):32(in Chinese).
2	魏慧卿, 张黎明 . 木质素基低成本碳纤维的研究现状[J]. 合成纤维, 2016,45(1):32.
3	Baker D A, Rials T G . Recent advances in low-cost carbon fiber manufacture from lignin[J]. Journal of Applied Polymer Science, 2013,130(2):713.
4	Wang H Y . Development foreground and market analyse of carbon fiber[J]. Hi-Tech Fiber & Application, 2007,32(4):23(in Chinese).
4	王海英 . 碳纤维的发展前景与市场分析[J]. 高科技纤维与应用, 2007,32(4):23.
5	Qiu W H, Chen H Z . Structure, function and high value utilization of lignin[J]. Journal of Cellulose Science and Technology, 2006,14(1):52(in Chinese).
5	邱卫华, 陈洪章 . 木质素的结构、功能及高值化利用[J]. 纤维素科学与技术, 2006,14(1):52.
6	Norgren M, Edlund H . Lignin: Recent advances and emerging applications[J]. Current Opinion in Colloid & Interface Science, 2014,19(5):409.
7	Ten E, Vermerris W . Recent developments in polymers derived from industrial lignin[J]. Journal of Applied Polymer Science, 2015,132(24):42069.
8	Naseem A, Tabasum S, Zia K M , et al. Lignin-derivatives based polymers, blends and composites: A review[J]. International Journal of Biological Macromolecules, 2016,93(A):296.
9	Otani S, Fukuoka Y, Igarashi B , et al. Method for producing carbonized lignin fiber: US, 3461082 A[P]. 1969.
10	Fukuoka Y . Carbon fiber made from lignin (kayacarbon)[J]. Japan Chemical Quartly, 1969,5(3):63.
11	Cha L S . Development of the preparation of lignin-based carbon fiber[J].Carbon, 1992(4):44(in Chinese).
11	查刘生 . 木质素基碳纤维的研制情况[J].炭素, 1992(4):44.
12	Wang X, Jiang S N, Chen M Z , et al. Review of research progress on lignin-based carbon fibers[J]. Journal of Forestry Engineering, 2016,1(1):83(in Chinese).
12	王翔, 蒋帅南, 陈敏智 , 等. 木质素基碳纤维研究进展[J]. 林业科技开发, 2016,1(1):83.
13	Da G, Liu P T . Lignin based carbon fiber[J]. Synthetic Fiber in China, 2012,41(3):43(in Chinese).
13	大谷朝男, 刘辅庭 . 木质素基碳纤维[J]. 合成纤维, 2012,41(3):43.
14	Zhang J H . Preparation, configuration and properties characterization of carbon fiber from liquefied bamboo[D]. Beijing:Beijing Forestry University, 2011(in Chinese).
14	张建辉 . 竹材液化物碳纤维的制备、结构与性能表征[D]. 北京:北京林业大学, 2011.
15	Tang W F . Study on the general carbon fiber preparation of liquefied lignin[D]. Beijing:Beijing University of Chemical Technology, 2012(in Chinese).
15	唐文峰 . 木质素液化物制备通用级碳纤维的工艺研究[D]. 北京:北京化工大学, 2012.
16	Dong L B . The research of production process of lignin based carbon fiber and influence of lignin structure[D]. Jinan:Qilu University of Technology, 2013(in Chinese).
16	董立斌 . 木素基碳纤维制备工艺及木素结构对其影响的研究[D]. 济南:齐鲁工业大学, 2013.
17	Zhang T . Preparation and properties research of lignin-phenol-for-maldehyde based macroporous activated carbon fiber[D]. Shanghai:Donghua University, 2009(in Chinese).
17	张涛 . 木质素酚醛树脂大孔活性碳纤维的制备与表征[D]. 上海:东华大学, 2009.
18	Jin Y C, Li Z Z . Structure Characteristics of dissolved lignin from Na2S pretreatment kraft pulping[J]. Journal of Nanjing Forestry University:Natural Sciences Edition, 2000,24(6):17(in Chinese).
18	金永灿, 李忠正 . 预处理硫酸盐制浆溶出木质素的结构特性[J]. 南京林业大学学报:自然科学版, 2000,24(6):17.
19	Jin Y C, Li Z Z . The changes of characteristics of dissolved lignin from kraft cooking[J]. Journal of Cellulose Science and Technology, 2001,9(1):28(in Chinese).
19	金永灿, 李忠正 . 硫酸盐蒸煮过程中溶出木质素特性的变化[J]. 纤维素科学与技术, 2001,9(1):28.
20	Kadla J F, Kubo S, Venditti R A , et al. Lignin-based carbon fibers for composite fiber applications[J]. Carbon, 2002,40(15):2913.
21	Kadla J F, Kubo S . Miscibility and hydrogen bonding in blends of poly(ethylene oxide) and kraft lignin[J]. Macromolecules, 2003,36(20):7803.
22	Kubo S, Kadla J F . Lignin-based carbon fibers: Effect of synthetic polymer blending on fiber properties[J]. Journal of Polymers & the Environment, 2005,13(2):97.
23	Seydibeyo?lu M ? . A novel partially bio-based PAN-lignin blend as a potential carbon fiber precursor[J]. Journal of Biomedicine & Biotechnology, 2012,2012(4):598324.
24	Wang S, Li Y, Xiang H , et al. Low cost carbon fibers from bio-renewable lignin/poly(lactic acid) (PLA) blends[J]. Composites Science & Technology, 2015,119:20.
25	Thunga M, Chen K, Grewell D , et al. Bio-renewable precursor fibers from lignin/polylactide blends for conversion to carbon fibers[J]. Carbon, 2014,68(2):159.
26	Glasser W G, Sarkanen S . Lignin: Properties and materials[M]. Washington:American Chemical Society, 1989: 35.
27	Kubo S, Kadla J F . Kraft lignin/poly(ethylene oxide) blends: Effect of lignin structure on miscibility and hydrogen bonding[J]. Journal of Applied Polymer Science, 2005,98(3):1437.
28	Norberg I . Carbon fibres from kraft lignin[D]. Stockholm:KTH Royal Institute of Technology, 2012.
29	Nordstr?m Y . Development of softwood kraft lignin based carbon fibers[D]. Lulea:Lulea University of Technology, 2012.
30	?hman F . Precipitation and separation of lignin from kraft black liquor[D]. Goteborg:Chalmers University of Technology, 2006.
31	Brodin I, Sj?holm E, Gellerstedt G . Kraft lignin as feedstock for chemical products: The effects of membrane filtration[J]. Holzforschung, 2010,63(3):290.
32	Nordstr?m Y, Norberg I, Sj?holm E , et al. A new softening agent for melt spinning of softwood kraft lignin[J]. Journal of Applied Polymer Science, 2013,129(3):1274.
33	Norberg I, Nordstr?m Y, Drougge R , et al. A new method for stabilizing softwood kraft lignin fibers for carbon fiber production[J]. Journal of Applied Polymer Science, 2013,128(6):3824.
34	Sun Q, Khunsupat R, Akato K , et al. A study of poplar organosolv lignin after melt rheology treatment as carbon fiber precursors[J]. Green Chemistry, 2016,18(18):5015.
35	Zhang M, Ogale A . Carbon fibers from dry-spinning of acetylated softwood kraft lignin[J]. Carbon, 2014,69(4):626.
36	Zhang M, Jin J, Ogale A A . Carbon fibers from UV-assisted stabilization of lignin-based precursors[J]. Fibers, 2015,3(2):184.
37	Zhang M, Ogale A A . Effect of temperature and concentration of acetylated-lignin solutions on dry-spinning of carbon fiber precursors[J]. Journal of Applied Polymer Science, 2016,133(45):43663.
38	Park C W, Youe W J, Han S Y , et al. Solubility of kraft lignin-g-polyacrylonitrile copolymer in various ionic liquids and characterization of its solution[J]. Wood Science & Technology, 2017,51(1):151.
39	Dallmeyer I, Kadla J F . Electrospinning of technical lignins for the production of fibrous networks[J]. Journal of Wood Chemistry & Technology, 2010,30(4):315.
40	Ma X, Kolla P, Zhao Y , et al. Electrospun lignin-derived carbon nanofiber mats surface-decorated with MnO2, nanowhiskers as binder-free supercapacitor electrodes with high performance[J]. Journal of Power Sources, 2016,325:541.
41	Svinterikos E, Zuburtikudis I . Carbon nanofibers from renewable bioresources (lignin) and a recycled commodity polymer [poly(ethylene terephthalate)][J]. Journal of Applied Polymer Science, 2016,133(37):43936.
42	Youe W J, Lee S M, Lee S S , et al. Characterization of carbon nanofiber mats produced from electrospun lignin-g-polyacrylonitrile copolymer[J]. International Journal of Biological Macromolecules, 2016,82(3):497.
43	Lao J B . Organic solvent pulping of poplar[J]. Heilongjiang Pulp & Paper, 2003,31(1):23(in Chinese).
43	劳嘉葆 . 杨木的有机溶剂制浆[J]. 黑龙江造纸, 2003,31(1):23.
44	Kubo S, Uraki Y, Sano Y , et al. Thermomechanical analysis of isolated lignins[J]. Holzforschung, 1996,50(50):144.
45	Kubo S, Uraki Y, Sano Y . Preparation of carbon fibers from softwood lignin by atmospheric acetic acid pulping[J]. Carbon, 1998,36(7-8):1119.
46	Uraki Y, Kubo S, Nigo N , et al. Preparation of carbon fibers from organosolv lignin obtained by aqueous acetic acid pulping[J]. Holzforschung, 1995,49(4):343.
47	Foston M, Nunnery G A, Meng X , et al. NMR a critical tool to study the production of carbon fiber from lignin[J]. Carbon, 2013,52(2):65.
48	Lin J, Kubo S, Yamada T , et al. Chemical thermostabilization for the preparation of carbon fibers from softwood lignin[J]. Bioresour-ces, 2012,7(4):5634.
49	Lin J, Koda K, Kubo S , et al. Improvement of mechanical properties of softwood lignin-based carbon fibers[J]. Journal of Wood Chemistry & Technology, 2014,34(34):111.
50	Feng Y , Aorigele. Preparation of lignin-based nanofibers by electrospinning[J]. Paper Science & Technology, 2009,28(5):29(in Chinese).
50	冯玉, 敖日格勒 . 静电纺丝法制备木质素基纳米纤维[J]. 造纸科学与技术, 2009,28(5):29.
51	Lallave M, Bedia J, Ruiz-Rosas R , et al. Filled and hollow carbon nanofibers by coaxial electrospinning of Alcell lignin without binder polymers[J]. Advanced Materials, 2007,19(23):4292.
52	Ruiz-Rosas R, Bedia J, Lallave M , et al. The production of submicron diameter carbon fibers by the electrospinning of lignin[J]. Carbon, 2009,48(3):696.
53	Ding R, Wu H, Thunga M , et al. Processing and characterization of low-cost electrospun carbon fibers from organosolv lignin/polyacrylonitrile blends[J]. Carbon, 2016,100:126.
54	Lou P, Liu Z . Steam explosion of biomass as a pretreatment for conversion to ethanol[J]. Forestry Science & Technology, 2005,30(3):53(in Chinese).
54	罗鹏, 刘忠 . 蒸汽爆破法预处理木质纤维原料的研究[J]. 林业科技, 2005,30(3):53.
55	Lin J, Zhao G J . Review of research progress on lignin-based carbon fibers[J]. Journal of Beijing Forestry University, 2010,32(4):293.
55	林剑, 赵广杰 . 木质素基碳纤维的研究进展[J]. 北京林业大学学报, 2010,32(4):293.
56	Sudo K, Shimizu K . New carbon fiber from lignin[J]. Journal of Applied Polymer Science, 1992,44(1):127.
57	Sudo K, Shimizu K, Nakashima N , et al. A new modification me-thod of exploded lignin for the preparation of a carbon fiber precursor[J]. Journal of Applied Polymer Science, 1993,48(8):1485.
58	Chatterjee S, Saito T . Lignin derived advanced carbon materials[J]. Chemsuschem, 2015,8(23):3941.
59	Feng Y, Lan J, Ma P , et al. Chemical structure and thermal properties of lignin modified with polyethylene glycol during steam explosion[J]. Wood Science & Technology, 2017,51(1):135.
60	Zhang F, Lin J, Zhao G . Preparation and characterization of modified soda lignin with polyethylene glycol[J]. 2016,9(10):822.
61	Dong X, Lu C, Zhou P , et al. Polyacrylonitrile/lignin sulfonate blend fiber for low-cost carbon fiber[J]. RSC Advances, 2015,5(53):42259.
62	Sallem-Idrissi N, Sclavons M, Debecker D P , et al. Miscible raw lignin/nylon 6 blends: Thermal and mechanical performances[J]. Journal of Applied Polymer Science, 2016,133(6):42963.
63	Miao C, Hamad W Y . Controlling lignin particle size for polymer blend applications[J]. Journal of Applied Polymer Science, 2016,134(14):44669.
64	You X, Duan J, Koda K , et al. Preparation of electric double layer capacitors (EDLCs) from two types of electrospun lignin fibers[J]. Holzforschung, 2015,70(7):661.
65	Salmén L, Bergnor E, Olsson A M , et al. Extrusion of softwood kraft lignins as precursors for carbon fibres[J]. Bioresources, 2015,10(4):7544.
66	Imel A, Naskar A K, Dadmun M . Understanding the impact of polyethylene oxide on the assembly of lignin in solution towards improved carbon fiber production[J]. ACS Applied Materials & Interfaces, 2016,8(5):3200.
67	Wang S, Zhou Z, Xiang H , et al. Reinforcement of lignin-based carbon fibers with functionalized carbon nanotubes[J]. Composites Science & Technology, 2016,128:116.