氧化石墨烯水泥基复合材料的性能及研究进展

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Abstract Cement based materials are widely used in the construction field, while they have the disadvantages of low flexural strength, poor crack resistance and toughness. Therefore improving the properties of cement based materials has always been one of the research hotspots in the field of building materials. Graphene oxide (GO) is a two-dimensional derived graphene material modified with oxygen-containing functional groups on the base and edge of graphene. It has honeycomb-like structural morphology, good hydrophilicity, dispersion and reactivity. The GO to cement-based materials can facilitate the formation of flower-like morphology crystals, accelerate the nucleation rate of hydration process, and make it form a dense cross-linked structure, and subsequently refine the voids of cement paste. Thus, the mechanical properties of cement-based materials are enhanced, while the fluidity is reduced. Therefore, the previous researchers mainly investigated the microscopic mechanism of action, quasi-static mechanical properties and durability and other aspects, and achieved fruitful results.
The structural properties of GO with large specific surface area lead to poor rheological properties of cement-based composites. The GO is mo-dified by admixture such as silica fume (SF) and graphene oxide encapsulated silica fume (GOSF). Thus, the fluidity of GO cement paste is improved. Based on the mechanism of microscopic structure, the strength enhancement mechanism of GO cement composites and the effects of GO content, specimen size and water-cement ratio on the compressive and flexural strengths are analyzed. The increase rate of compressive strength, tensile strength and flexural strength of cement-based materials is different with the addition of GO, and the enhancement of flexural strength is the largest. It has been found that GO improves the mechanical properties of Portland cement more significantly than that of the magnesium potassium phosphate cement paste. For the dynamic mechanical properties, the crack growth path is different at different strain rates, and the enhancement effect GO at high strain rates is more significant. In the working environment of cement-based materials, various ionic compounds and pH have a negative effect on the matrix. GO can significantly improve the durability of its cement composites.
The research status of GO cement-based composites in recent years is reviewed in this paper. Microstructure mechanism, fluidity, mechanical properties and durability of GO cement matrix composites are summarized. The current domestic and overseas research progress and existing problems are expounded. Moreover, the future development of GO cement-based composites is prospected.

Key words： graphene oxide cement-based composites microscopic mechanism fluidity mechanical property

Published: 16 July 2021

CLC number:

TU528

Fund:National Natural Science Foundation of China (51708391), the Natural Science Foundation of Tianjin (18JCYBJC22700,20JCQDJC00850).

About author:: Jijun Zeng received his B.E.degree in applied civil engineering from Shandong Xiehe University in 2018. He is currently master's student in the School of Civil Engineering of Tianjin Chengjian University. At present, the main research area is graphene oxide concrete.Zhanyuan Gao received his Ph.D. degree in the college of architecture and civil engineering of Beijing University of Technology in 2014. After two-year postdocto-ral research at Tsinghua University, he is currently a lecturer in Tianjin Chengjian University. His research interests are preparation method, static properties and dynamic properties of graphene reinforced concrete. Dong Ruan is a professor and doctoral supervisor in Faculty of Science, Engineering and Technology, Swinburne University of Technology. She is deputy secretary general of international impact society. Her research interests are impact dynamic analysis, dynamic numerical simulation and experimental methods.

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Cite this article:

ZENG Jijun,GAO Zhanyuan,RUAN Dong. Properties and Research Progress of Graphene Oxide Cement-based Composites[J]. Materials Reports, 2021, 35(Z1): 198-205.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/198

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