高熵合金中间层应用于陶瓷连接的研究进展

doi:10.11896/cldb.25070126

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (10801KB)
Export: BibTeX | EndNote (RIS)

Abstract The demand for joining ceramic materials (e.g., SiC, ZrB₂-SiC) with metal components (e.g., superalloys) is becoming increasingly urgent in extreme service environments, such as thermal barrier coatings of aero-engines, leading edges of hypersonic vehicles, and advanced nuclear fuel claddings. Ceramics offer excellent high-temperature resistance, oxidation resistance, and radiation resistance. However, the significant differences in physical and chemical properties between ceramics and metals, particularly the notable mismatch in thermal expansion coefficients, the easy formation of brittle intermetallic compounds (IMCs) at the joint interface, and the resulting residual stress and cracks, severely limit the reliability and service life of composite components. High-entropy alloy (HEA) interlayers have shown significant advantages in addressing these challenges. The unique multi-principal-element synergistic effects of HEAs, such as high mixing entropy, lattice distortion, hysteresis diffusion, and cocktail effect, can effectively suppress the formation of brittle phases, regulate interface reaction kinetics, relieve residual thermal stress, and maintain high-temperature strength. This summary provides a systematic review of the latest research progress on the application of HEA interlayers in the field of ceramic joining, and elaborates on the design strategies of composition systems, key preparation technologies, primary joining processes, interface regulation strategies, and the joining performance of HEA interlayers, comparing them with traditional brazing fillers. Despite notable advancements in metal-ceramic joining using HEA interlayers, challenges remain. These include the absence of an atomic diffusion kinetics theoretical model for multi-component systems, difficulties in controlling the thickness and uniform coating of HEA interlayers in ultra-thin or complex components, and the lack of unified evaluation criteria for joint interface quality and process specifications, all of which impede engineering applications. Future directions suggest leveraging machine learning, thermodynamic calculations, and first-principles simulations to expedite HEA composition and process design;developing amorphous HEA interlayers to enhance toughness and prevent crystallization;and employing additive manufacturing for composition/structure gradients and integrated interlayer formation. These innovations could optimize stress distribution and expand HEA interlayer applications in extreme environments, such as nuclear reactor claddings (SiC/B₄C joining) and micro-nano joining in flexible electronic packaging.

Key words： high-entropy alloy ceramic joining interfacial reaction residual stress brazing diffusion bonding

Published: 25 July 2026 Online: 2026-08-12

CLC number:

TG47

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	YU Weiyuan
	HUANG Dongheng

Cite this article:

YU Weiyuan,HUANG Dongheng. Research Progress on the Application of High-entropy Alloy Interlayers in Ceramic Joining[J]. Materials Reports, 2026, 40(14): 25070126-12.

URL:

https://www.mater-rep.com/EN/10.11896/cldb.25070126 OR https://www.mater-rep.com/EN/Y2026/V40/I14/25070126

1 Xu J, Zhou X, Huang Q. Scripta Materialia, 2025, 264, 116721.
2 MunJ U, Raju K, Lee H K. Ceramics International, 2023, 49(1), 1529.
3 Chen B X, Zhu L L, Zhan T C, et al. Ceramics International, 2024, 50(24), 53048.
4 Liu P S, Yang X K, Yan L W, et al. Ceramics International, 2025, 51(4), 5077.
5 Ji X S, Liu C Q, Huang J Y, et al. Journal of Nuclear Materials, 2025, 604, 155501.
6 Liu K Q, Wang J X, Wang J, et al. Journal of the European Ceramic Society, 2025, 45(5), 117156.
7 Golosov M A, Utkin A V, Lozanov V V, et al. Ceramics International, 2024, 50(23), 51447.
8 Rajendran S H, Lee G A, Park J Y, et al. Materials Chemistry and Physics, 2024, 313, 128732.
9 Wang B, Pan Z H, Zhao Z Y, et al. Journal of Non-Crystalline Solids, 2025, 647, 123297.
10 Zhou B, Zhao Z Y, Zhang H, et al. Journal of Alloys and Compounds, 2024, 986, 174131.
11 Li P X, Zhang J K, Yang T L, et al. Journal of Manufacturing Processes, 2024, 110, 303.
12 Zhang X T, Wang J, Xu Q, et al. Journal of Materials Research and Technology, 2024, 33, 8425.
13 Soundararajan R, Ramkumar K R, Sivasankaran S, et al. Materials Science & Engineering A, 2022, 832, 142481.
14 Wang X C, Saunders T G, Wang Y C, et al. Journal of the European Ceramic Society, 2024, 44(2), 815.
15 Yin K X, Yiliti Y, Li S T, et al. Intermetallics, 2025, 184, 108838.
16 Lu Y S, Chen J Y, Bui T X, et al. Materials Characterization, 2025, 224, 115024.
17 Shao B Q, Zhao S, Wang P, et al. Journal of Materials Research and Technology, 2024, 33, 491.
18 Wang M, Wang W, Yang Y L, et al. Acta Aeronautica et Astronautica Sinica, 2022, 43(4), 525057(in Chinese).
王秒, 王微, 杨云龙, 等. 航空学报, 2022, 43(4), 525057.
19 Liang Y Z, Dong K W, Yang Y, et al. Materials Science & Engineering A, 2022, 854, 143815.
20 Sharma A, Ahn B. Scientific Reports, 2021, 11(1), 9345.
21 Jiang X, Zhang G F, Wang K M, et al. Composites Part A, 2024, 185, 108370.
22 Wei H F, Zhang H, Xu D, et al. Journal of the American Ceramic Society, 2024, 107(10), 6985.
23 Zhang S Z, Zhao G X, Zhang C J, et al. Intermetallics, 2023, 162, 108043.
24 Chen Y N, Wang J T, Wang J Q, et al. Journal of Materials Research and Technology, 2024, 32, 792.
25 Luo W Y, Liu Y Z, Tu C. Journal of Materials Science & Technology, 2021, 78, 192.
26 Lin D Y, Hu J X, Song X G, et al. Materials Characterization, 2023, 204, 113199.
27 Nai X, Chen H Y, Zhao S, et al. Materials Letters, 2022, 322, 132488.
28 Zhang Y, Guo W, Mei H, et al. Materials Characterization, 2025, 222, 114849.
29 Zhao S, Nai X, Chen H Y, et al. Materials Science & Engineering A, 2024, 891, 145914.
30 Zhao S, Chen H Y, Nai X, et al. Journal of Manufacturing Processes, 2023, 85, 132.
31 Yang Y L, Wang G, He R J, et al. Journal of the American Ceramic Society, 2021, 104(7), 2992.
32 Mu R J, Wang Y, Niu S Y, et al. Journal of Materials Processing Technology, 2024, 324, 118253.
33 Li H X, Cheng C, Shi L, et al. Materials Characterization, 2022, 194, 112350.
34 Malinverni C, Casalegno V, Bertrand P, et al. Journal of the European Ceramic Society, 2025, 45(7), 117231.
35 Mi H B, Ma J G, Feng L Y, et al. Journal of Manufacturing Processes, 2025, 141, 829.
36 Yuan L, Jiang F Y, Hao D, et al. Journal of Materials Science & Technology, 2025, 222, 152.
37 Nai X, Wang P, Zhao S, et al. Journal of Materials Research and Technology, 2024, 33, 3334.
38 Nai X, Zhang H B, Zhao S, et al. Ceramics International, 2024, 50(20), 38107.
39 Nai X, Chen H Y, Zhao S, et al. Materials Science & Engineering A, 2023, 877, 145190.
40 Zhao S, Wang P C, Chen H Y, et al. Transactions of Materials Research, 2025, 1(2), 100017.
41 Wu L F, Wang X C, Xiao X, et al. Materials Characterization, 2024, 216, 114324.
42 Luo Z Y, Wang G, Zhao Y, et al. Ceramics International, 2022, 48(16), 23325.
43 Zhao S, Nai X, Chen H Y, et al. Materials Characterization, 2024, 209, 113773.
44 Zhang L X, Shi J M, Li H W, et al. Materials and Design, 2016, 97, 230.
45 Li Y F, Nie J L, Zhou J H, et al. Materials Letters, 2024, 373, 137152.
46 Li H, Li B J, Li Y Y, et al. Journal of Iron and Steel Research International, 2024, 31, 2590.
47 Zheng M S, Si X Q, Chen L, et al. Journal of Alloys and Compounds, 2025, 1028, 180693.
48 Luo Z Y, Wang G, Zhao Y, et al. Ceramics International, 2023, 49(24), 40073.
49 Hu J X, Lin D Y, Li X Y, et al. Materials Science & Engineering A, 2022, 854, 143895.
50 Jiang W, Yu K, Zhao R Q, et al. Acta Materiae Compositae Sinica, 2025, 42(8), 4719(in Chinese).
姜伟, 于康, 赵瑞晴, 等. 复合材料学报, 2025, 42(8), 4719.
51 Jiang W, Shen X, Jiang Y L, et al. Materials Today Communications, 2025, 46, 112700.
52 Ma K, Feng L, Zhao Y C, et al. Rare Metal Materials and Engineering, 2024, 53(10), 2747.
53 Wang P C, Liu W H, Gu L, et al. Transactions of Materials Research, 2025, 1(1), 100012.
54 Wang P C, Shi W T, Gu L, et al. Journal of Materials Science & Technology, 2026, 244, 46.
55 Shen L, Chen Z C, Ren H, et al. Infrared Technology, 2023, 45(8), 808(in Chinese).
沈练, 陈正超, 任海, 等. 红外技术, 2023, 45(8), 808.
56 Nai X, Chen H Y, Zhao S, et al. Materials Characterization, 2023, 196, 112573.
57 Cao Y, Xu C G, Shen P. Ceramics International, 2024, 50(21), 41956.
58 Wang R P, Wang G, Ran S L, et al. Journal of the European Ceramic Society, 2023, 43, 1853.
59 Zhou L, Li C, Zhang C H, et al. Journal of the European Ceramic Society, 2024, 44, 3767.
60 Wang X C, Fu L. International Journal of Refractory Metals and Hard Materials, 2023, 117, 106398.
61 Zhou L, Li C, Chen Y X, et al. Journal of Manufacturing Processes, 2024, 121, 260.
62 Liu Y H, Wang G, Zhao Y, et al. Journal of the European Ceramic Society, 2022, 42(5), 1995.
63 Kimura Y, Utsumi K, Tohmyoh H. Applied Thermal Engineering, 2024, 255, 124009.
64 Liu Y H, Wang G, Zhou X B, et al. Journal of Materials Engineering, 2023, 51(9), 140(in Chinese).
刘一贺, 王刚, 周小兵, 等. 材料工程, 2023, 51(9), 140.
65 Wang G, Liu Y H, Wang M, et al. Journal of Materials Research and Technology, 2023, 23, 5142.
66 Zhou L, Li C, Zhang C H, et al. Ceramics International, 2025, 51, 25379.
67 Liao C H, Shen T E, Hsu W C, et al. Materials & Design, 2024, 248, 113454.
68 Wang G, Yang Y L, Wang M, et al. Journal of the European Ceramic Society, 2021, 41, 54.
69 Lei Y, Li Y N, Cai Y C, et al. Vacuum, 2024, 230, 113670.
70 Mu R J, Wang Y, Niu S Y, et al. Journal of the European Ceramic Society, 2023, 43(16), 7263.
71 Huang C C, Chen J, Zhang H H, et al. Journal of the American Ceramic Society, 2024, 107(12), 8583.
72 Wang G, Yang Y L, He R J, et al. Journal of the European Ceramic Society, 2020, 40(9), 3391.
73 Wang P, Zhang H B, Chen H Y, et al. Materials Characterization, 2025, 221, 114768.
74 Tillmann W, Wojarski L, Stangier D, et al. Welding in the World, 2020, 64, 1597.
75 Zhao S, Wang P, Nai X, et al. Chinese Journal of Aeronautics, 2025, 38(7), 103521.
76 Zhao S, Chen H Y, Nai X, et al. Materials Characterization, 2022, 194, 112419.
77 Zhao S, Shao B Q, Chen H Y, et al. Journal of Materials Science & Technology, 2025, 233, 223.
78 Cheng J L, Wang G, Wang W, et al. Journal of Materials Research and Technology, 2025, 36, 9198.
79 Mu R J, Wang Ying, Niu S Y, et al. Ceramics International, 2025, 51, 20006.
80 Song Y Y, Liu D, Hu S P, et al. Journal of the European Ceramic Society, 2018, 39(4), 696.
81 Li P X, Wang Z Y, Chen Y C, et al. Carbon, 2025, 242, 120416.
82 Shi W, Qian H J, Huang Z Y, et al. Gas Turbine Experiment and Research, 2024, 37(1), 49(in Chinese).
石炜, 钱泓江, 黄志勇, 等. 燃气涡轮试验与研究, 2024, 37(1), 49.
83 Qiu H, Dong Z, Feng L T, et al. Materials Research and Application, 2025, 19(1), 155(in Chinese).
邱昊, 董真, 封立同, 等. 材料研究与应用, 2025, 19(1), 155.