正极富锂添加剂在锂离子电容器中的应用进展

doi:10.11896/cldb.25070095

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Abstract Lithium-ion capacitors have emerged as a research hotspot in the energy storage field due to their advantages of high power density, high energy density, and long cycle life. However, their electrochemical performance is significantly constrained by the initial coulombic efficiency of the anode during the first charge-discharge cycle. To overcome this bottleneck, cathode prelithiation technology, which introduces sacrificial lithium-containing materials, has become a key strategy. During the device activation stage, this approach compensates for the irreversible lithium ion loss caused by the formation of the solid electrolyte interphase on the anode. This review systematically summarizes the design principles and recent advancements in cathode prelithiation materials. Particular emphasis is placed on the application examples and performance advantages of binary lithium compounds, lithium-rich transition metal oxides, and organic lithium salts in lithium-ion capacitors. In addition, this review provides an in-depth analysis of the key challenges and potential development pathways associated with sacrificial lithium salt-based cathode prelithiation in practical applications. The aim is to provide theoretical guidance for the development of novel prelithiation materials with low working potentials and high irreversible capacities, and to lay a technical foundation for establishing structure-performance relationships between prelithiation processes and device-level electrochemical performance.

Key words： lithium-ion capacitors cathode activated carbon lithium-rich compound prelithiation

Published: 25 June 2026 Online: 2026-07-08

CLC number:

G304

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	Articles by authors
	XU Jianwei
	LIU Heqiang
	LIU Yang
	AN Yabin
	WANG Hao
	ZHANG Xiong

Cite this article:

XU Jianwei,LIU Heqiang,LIU Yang, et al. Progress in the Application of Lithium-rich Cathode Additives in Lithium-ion Capacitors[J]. Materials Reports, 2026, 40(12): 25070095-10.

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https://www.mater-rep.com/EN/10.11896/cldb.25070095 OR https://www.mater-rep.com/EN/Y2026/V40/I12/25070095

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