| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
| Control of Energy Storage Properties of Bi Doped SrTiO3 Thin Films by Amorphous Engineering |
| PENG Jinlin1,2, ZHOU Li2, GONG Yueqiu2,*
|
1 All-solid-state Energy Storage Materials and Devices Key Laboratory of Hunan Province, Hunan City University, Yiyang 413000, Hunan, China 2 School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, Hunan, China |
|
|
|
|
Abstract Low temperature amorphous films with excellent energy storage properties play an important role in silicon-based microelectronic applications. In this work, Sr(1-1.5x)BixTiO3(SBTx, x=0, 0.05, 0.1, 0.15) films were prepared on Pt/Ti/SiO2/Si substrates by sol-gel method and spin coating method. The control mechanism of bismuth content and annealing temperature on their energy storage properties was studied. XRD results show that the amorphous thin films are successfully prepared, and it is found that the Bi content can reduce the crystallization temperature of the thin films. When the annealing temperature is 500 ℃, the SBT0.05 thin films reach the critical amorphous state. At this time, the thin films have large dielectric constant and low dielectric loss and leakage current. Under the electric field of 4 100 kV/cm, the recoverable energy storage density of 20.79 J/cm3 and the energy storage efficiency of 80.13% are obtained, which is expected to provide a reference for the research of low-temperature prepared energy storage materials.
|
|
Published: 10 July 2026
Online: 2026-07-24
|
|
|
|
|
1 Luo Z, Bin H, Liu T, et al. Advanced Materials, 2018, 30(9), 1706124. 2 Bento N, Fontes M. Renewable and Sustainable Energy Reviews, 2019, 99, 66. 3 Li H, Riisager A, Saravanamurugan S, et al. ACS Catalysis, 2018, 8(1), 148. 4 Sarkodie S A, Adams S. Science of the Total Environment, 2018, 643, 1590. 5 Liu Y, Yao M, Yao X. Journal of Alloys and Compounds, 2021, 882, 160668. 6 Palneedi H, Peddigari M, Hwang G T, et al. Advanced Functional Materials, 2018, 28(42), 1803665. 7 Pan Z, Yao L, Zhai J, et al. ACS Sustainable Chemistry & Engineering, 2017, 5(6), 4707. 8 Li Y, Cao M. Materials & Design, 2016, 110, 99. 9 Yin J, Zhang Y, Lv X, et al. Journal of Materials Chemistry A, 2018, 6(21), 9823. 10 Diao C L, Dong L, Yang Y, et al. Materials Reports, 2019, 33(23), 3921 (in Chinese). 刁春丽, 董乐, 杨毅, 等. 材料导报, 2019, 33(23), 3921. 11 Diao C, Wang H, Wang B, et al. Journal of Materials Science: Materials in Electronics, 2022, 33(27), 21199. 12 Yue C, Sun H, Huang X, et al. Journal of Materials Science: Materials in Electronics, 2022, 33(14), 11236. 13 Hao X, Zhao Y, Zhang Q. The Journal of Physical Chemistry C, 2015, 119(33), 18877. 14 Wang Y, Hao X, Yang J, et al. Journal of Applied Physics, 2012, 112(3), 034105. 15 Sa T, Qin N, Yang G, et al. Materials Chemistry and Physics, 2013, 139(2), 511. 16 Balmuchu S P, Bora S, Dobbidi P. Journal of Materials Science: Materials in Electronics, 2022, 33(34), 25704. 17 Yan F, Zhou X, He X, et al. Nano Energy, 2020, 75, 105012. 18 Alkathy M S, Zabotto F L, Milton F P, et al. Journal of Materials Science: Materials in Electronics, 2022, 33(19), 15483. 19 Diao C, Li H, Yang Y, et al. Ceramics International, 2019, 45(9), 11784. 20 Liu J, Wang Y, Zhai X, et al. Materials, 2023, 16, 31. 21 Yang L, Kong X, Li F, et al. Progress in Materials Science, 2019, 102, 72. 22 Song B, Wu S, Li F, et al. Journal of Materials Chemistry C, 2019, 7(35), 10891. 23 Srikanth K S, Patel S, Vaish R. Journal of the Australian Ceramic Society, 2018, 54(3), 439. 24 Alkathy M S, Ali S M, Goud J P, et al. Journal of Materials Science: Materials in Electronics, 2023, 34(22), 1616. 25 Zhu X, Shi P, Kang R, et al. Chemical Engineering Journal, 2021, 420, 129808. 26 Zhao Y, Yang B, Wu Q, et al. Nanoscale, 2021, 13(38), 16226. 27 Zhou N J, Wu X S, Wen H J, et al. Materials Reports, 2025, 39(6), 18 (in Chinese). 周乃吉, 吴修胜, 温红娟, 等. 材料导报, 2025, 39(6), 18. 28 Liu Q, Ji M, Wang R, et al. Journal of Alloys and Compounds, 2023, 959, 170470. 29 Wang K, Zhang Y, Wang S, et al. ACS Applied Materials & Interfaces, 2021, 13(19), 22717. 30 Gao Y, Yuan M, Sun X, et al. Journal of Materials Science: Materials in Electronics, 2017, 28(1), 337. 31 Chen Y, Huang R, Tao C, et al. Journal of Materials Science: Materials in Electronics, 2023, 34(16), 1256. 32 McKenna K, Shluger A, Iglesias V, et al. Microelectronic Engineering, 2011, 88(7), 1272. 33 Ezhilvalavan S, Tseng T Y. Journal of Applied Physics, 1998, 83(9), 4797. 34 Joshi P C, Krupanidhi S B. Journal of Applied Physics, 1993, 73(11), 7627. 35 Peng Y, Yao M, Li F, et al. Journal of Materials Science: Materials in Electronics, 2016, 27(8), 8100. 36 Yang F, Dean J S, Hu Q, et al. Journal of Materials Chemistry A, 2020, 8(47), 25120. 37 Diao C, Liu H, Li Z, et al. Journal of Alloys and Compounds, 2020, 845, 155636. 38 Xie J, Liu H, Yao Z, et al. Journal of the European Ceramic Society, 2020, 40(4), 1243. 39 Chen L, Deng S, Liu H, et al. Nature Communications, 2022, 13(1), 3089. 40 Xie J, Yao Z, Hao H, et al. Journal of the American Ceramic Society, 2019, 102(7), 3819. 41 Wang F, Zhu C, Zhao S. Journal of Alloys and Compounds, 2021, 869, 159366. 42 Yang X, Li W, Zhang Y, et al. Journal of the European Ceramic Society, 2020, 40(3), 706. 43 Gao W, Yao M, Yao X. Ceramics International, 2017, 43(16), 13069. |
|
|
|