生物质衍生碳材料电化学传感器的构筑及在多巴胺检测中的应用

doi:10.11896/cldb.25060123

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Abstract As a renewable organic material, biomass is utilized extensively to fabricate electrochemical sensors for biomolecule detection because of its many sources, ease of preparation, and environmental friendliness. In this work, a spherical porous carbon material derived from ginkgo pulp (GP-SPC) was obtained through hydrothermal carbonization and freeze-drying treatment. An electrochemical sensor based on GP-SPC was constructed for the detection of dopamine (DA). Electrochemical techniques (cyclic voltammetry, differential pulse voltammetry, and chronoamperometry) were used to assess the performance of the sensor. Compared with bare glassy carbon electrode (GCE), the GP-SPC modified GCE (GP-SPC/GCE) exhibited superior electroanalytical performance in detecting the electroactive molecule DA, such as a wider linear range (5—2 725 μmol·L^-1) and a lower detection limit (0.21 μmol·L^-1), high stability and selectivity, which might be attributed to the advantages of high specific surface area and mesoporous structure of GP-SPC. Furthermore, GP-SPC/GCE showed the potential to simultaneously and accurately detect ascorbic acid (AA), DA, and uric acid (UA). Therefore, the novel and high-performance carbon material synthesized from the ginkgo pulp provides a new idea for constructing electrochemical sensors to detect DA, and also indicates the potential application prospects of the biosensor based on GP-SPC in the field of biomedicine.

Key words： biomass electrochemical sensor porous carbon material dopamine

Published: 10 July 2026 Online: 2026-07-24

CLC number:

O657.1

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	Articles by authors
	HEI Yashuang
	BA Lisi
	YANG Liqin
	SHI Xingwei
	WEN Sisi
	ZHENG Bingxiao
	ZHAO Zhiju
	XU Siwen

Cite this article:

HEI Yashuang,BA Lisi,YANG Liqin, et al. Construction of an Electrochemical Sensor Based on Biomass-derived Carbon Materials and Its Application in Dopamine Detection[J]. Materials Reports, 2026, 40(13): 25060123-7.

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https://www.mater-rep.com/EN/10.11896/cldb.25060123 OR https://www.mater-rep.com/EN/Y2026/V40/I13/25060123

1 Xue C, Han Q, Wang Y, et al. Biosensors and Bioelectronics, 2016, 49, 199.
2 Yu M, Bai Y, Wang M Y, et al. Journal of Chinese Practical Diagnosis and Therapy, 2024, 38(4), 420 (in Chinese).
于淼, 白岩, 王梅云, 等. 中华实用诊断与治疗杂志, 2024, 38(4), 420.
3 He X M, Wang R R. West China Medical Journal, 2021, 36(5), 698 (in Chinese).
何雪梅, 王儒蓉. 华西医学, 2021, 36(5), 698.
4 Wu Q Q. Perfrpntal cortical dopamine deficit causes impaired glucose metabolism in schizophrenia. Ph. D. Thesis, Central South University, China, 2023 (in Chinese).
邬琼琼. 前额叶多巴胺调控精神分裂症糖代谢的机制研究. 博士学位论文, 中南大学, 2023.
5 Li W, Xiao S F. Chinese Journal of Clinicians (Electronic Edition), 2015, 9(20), 3750.
李伟, 肖世富. 中华临床医师杂志(电子版), 2015, 9(20), 3750.
6 Chen J Y, Wang E A, Cepeda C, et al. Frontiers in Neuroscience, 2013, 7, 114.
7 Liu C H. The mechanism of Nurr1 mediatedcircadion regulation of midbrain dopamine signalling pathway and its effect on attention deficit hype-ractivity. Master′s Thesis, Soochow University, China, 2021 (in Chinese).
刘长红. Nurr1参与中脑多巴胺信号节律调控影响注意力缺陷多动症的机制研究. 硕士学位论文, 苏州大学, 2021.
8 Huang Y Q, Zang Y J, Ruan S J, et al. Microchemical Journal, 2021, 165, 106152.
9 Lin J M, Wang H T, Li H, et al. Journal of Chinese Mass Spectrometry Society, 2024, 45(1), 103 (in Chinese).
林嘉美, 王昊天, 李慧, 等. 质谱学报, 2024, 45(1), 103.
10 Zhang H, Zhang F H, Li S, et al. Ionics, 2017, 23, 2475.
11 Zhang L C. Preparation of sub-nano porous carbon materials and electrochemical energy storage research. Master′s Thesis, Lanzhou University of Technology, China, 2023 (in Chinese).
张利超. 亚纳米多孔碳材料的制备及电化学储能研究. 硕士学位论文, 兰州理工大学, 2023.
12 Liu S S. Preparation and application of electrochemical sensor based on biomass carbon materials. Master′s Thesis, Yanbian University, China, 2022 (in Chinese).
刘闪闪. 基于生物质碳材料的电化学传感器的制备及应用. 硕士学位论文, 延边大学, 2022.
13 Gao J B, Lu Y Q, Zhang H, et al. Chinese Journal of Organic Chemistry, 2024, 44(9), 2732.
高晋彬, 陆颖琪, 张辉, 等. 有机化学, 2024, 44(9), 2732.
14 Wang J S, Zhang X, Li Z, et al. Journal of Power Sources, 2020, 451, 227794.
15 Lin J H. Detection of heavy metals in enviromental water by biochar-based electrochemical sensors. Master’s Thesis, Dongguan University of Technology, China, 2024 (in Chinese).
林金毫. 基于生物炭的电化学传感器对环境水体中重金属的检测研究. 硕士学位论文, 东莞理工学院, 2024.
16 Wu H. Research on an electrochemical biosensor based on algal residue-derived carbon aerogel for dopamine detection. Master′s Thesis, Qingdao University, China, 2024 (in Chinese).
吴昊. 用于多巴胺检测的藻渣基碳气凝胶电化学生物传感器的研究. 硕士学位论文, 青岛大学, 2024.
17 Bao T S. Electrochemical sensing performance of three-dimensional biochar and its composite materials. Master′s Thesis, Shandong University of Technology, China, 2024 (in Chinese).
宝天爽. 三维生物质碳及其复合材料的电化学传感性能研究. 硕士学位论文, 山东理工大学, 2024.
18 Hei Y S, Li X Q, Zhou X, et al. Analytica Chimica Acta, 2018, 1003, 16.
19 Feng S. Preparation of N-doped mesoporous carbon/metal oxide compo-sites and electrochemical sensing for heavy metal ions. Master′s Thesis, Northeast Petroleum University, China, 2024 (in Chinese).
封硕. N掺杂介孔碳/金属氧化物复合材料的制备及面向重金属离子电化学传感的研究. 硕士学位论文, 东北石油大学, 2023.
20 Adeniyi A G, Ighalo J O. Journal of Environmental Chemical Engineering, 2019, 7(3), 103100.
21 Zhang Q. Study on process and properties of preparation of porous carbon and composite carbon nanofibers prepared based on black wolfberry twigs. Master′s Thesis, Lanzhou University of Technology, China, 2020 (in Chinese).
张琪. 基于黑枸杞枝条制备多孔炭和复合碳纳米纤维工艺及性能的研究. 硕士学位论文, 兰州理工大学, 2020.
22 Fan J Y, Kong X X, Li W, et al. Progress in Chemistry, 2023, 35(12), 1764.
范金玥, 孔祥鑫, 李伟, 等. 化学进展, 2023, 35(12), 1764.
23 Li C, Wu Z Y, Liang H W, et al. Small, 2017, 13(25), 1700453.
24 Ren Y, Xu Q, Zhang J, et al. ACS Applied Materials & Interfaces, 2014, 6(12), 9689.
25 Zhou J H, Sui Z J, Zhu J, et al. Carbon, 2007, 45(4), 785.
26 Gao S, Wang M, Chen Y, et al. Nano Energy, 2018, 45, 21.
27 Chen Y, Wang M, Tian M, et al. Nano Energy, 2017, 42, 314.
28 Wang D, Geng Z, Li B, et al. Electrochimica Acta, 2015, 173, 377.
29 Köseoğlu E, Akmil-Başar C. Advanced Powder Technology, 2015, 26(3), 811.
30 Nicholson R S. Analytical Chemistry, 1965, 37(11), 1351.
31 Hrapovic S, Liu Y, Male K B, et al. Analytical Chemistry, 2004, 76(4), 1083.
32 Li X X. Preparation of biomass derived carbon nanomaterials and their applications in electroanalytical chemistry. Master′s Thesis, Northeast Normal University, China, 2018 (in Chinese).
李秀秀. 生物质衍生碳纳米材料的制备及其在电分析化学中的应用. 硕士学位论文, 东北师范大学, 2018.
33 Feng S N, Yan M X, Xue Y, et al. Chemical Communications, 2022, 58(41), 6092.
34 Ni M J, Chen J, Wang C X, et al. Microchemical Journal, 2022, 178, 107410.
35 Wang M Y, Guo H, Wu N, et al. Colloids and Surfaces A, 2022, 634, 127928.
36 Kim D S, Kang E S, Baek S, et al. Scientific Reports, 2018, 8, 14049.
37 Choo S S, Kang E S, Song I, et al. Sensors, 2017, 17(4), 861.
38 Guo D J, Jin M. Russian Journal of Electrochemistry, 2019, 49, 200.
39 Panapimonlawat T, Phanichphant S, Sriwichai S. Polymers, 2021, 13(9), 1488.
40 Gu Q H. Construction ofcarbon based electrochemical sensor for capsaicinoids and its application in spiciness. Ph. D. Thesis, Jiangnan University, China, 2023 (in Chinese).
顾千辉. 碳基辣椒素类物质电化学传感器的构建及在休闲酱卤肉制品辣度分级中的应用. 博士学位论文, 江南大学, 2023.
41 Dong W Y, Hu X J, Chen Z C, et al. Materials Chemistry and Physics, 2020, 254, 123295.
42 Gao P P. Fabricating electrochemical sensor based on biomass carbon materials for simultaneous determination of ascorbic acid, dopamine and uric acid. Master′s Thesis, Chongqing University, China, 2022 (in Chinese).
高盼盼. 基于生物质碳材料构建电化学传感器实现对抗坏血酸、多巴胺和尿酸的同时检测. 硕士学位论文, 重庆大学, 2022.