| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Research Progress in Polymer Design of Precursors for ZrC-SiC Composite Ceramics |
| YUAN Lin1,2, HU Yang1,2, YU Mengdie1,2, ZHANG Zhaofu1,2, ZHANG Pengfei1,2,*
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1 Research Institute of Xi’ an Aerospace Composites Materials, Xi’ an 710025, China 2 Shaanxi Key Laboratory of Aerospace Composites, Xi’an 710025, China |
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Abstract Polymer infiltration and pyrolysis (PIP) has emerged as a promising and practical route for fabricating C/C-ZrC-SiC composites, owing to its flexibility, relatively simple equipment requirements, and suitability for complex structural components. As the fundamental element of the PIP process, ZrC-SiC multiphase ceramic precursors offer unique advantages in molecular-level design and compositional tunability, contributing to improved structural uniformity and performance of the resulting composites. This review systematically summarizes recent advances in ZrC-SiC multiphase ceramic precursor design strategies for PIP-based processes, with a particular emphasis on precursor hybridization, chemical modification, and single-source precursor synthesis. The mechanisms of precursor architecture, pyrolysis evolution, and the resulting ceramic phases are comparatively discussed. Finally, the challenges and future perspectives for the controllable synthesis and engineering application of ZrC-SiC multiphase ceramic precursors are highlighted, aiming to provide a theoretical foundation and technical reference for high-performance thermal structural composites.
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Published: 25 June 2026
Online: 2026-07-08
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