共价有机框架材料的热导和热电应用研究进展

doi:10.11896/cldb.24040129

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Abstract Covalent organic framework (COF) materials are a class of periodically ordered porous materials formed by light atoms (C, B, N, O, etc.) connected through covalent bonds, featuring adjustable thermal conductivity suitable for various thermal applications. COF materials with high thermal conductivity can be utilized in heat management modules like device heat sinks, while those with low thermal conductivity can leverage the thermoelectric effect to convert temperature gradients into voltage, thereby providing energy. This review discusses the influence of factors such as pore size, crystalline state, temperature, gas adsorption, etc., on the thermal conductivity of COF materials. It summarizes the range of thermal conductivity values of current COF materials and recent research on utilizing COF materials for thermal conduction or insulating properties and thermoelectricity properties. Finally, the review provides a summary and outlook on the development direction of COF in terms of thermal conduction, aiming to offer insights and inspiration for further advancements in COF-related thermal applications.

Key words： covalent organic framework porous material nanomaterials thermal conductivity thermoelectricity

Published: 25 June 2024 Online: 2024-07-17

CLC number:

TB34

Fund:National Natural Science Foundation of China (22103053).

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	WANG Zixiao
	XIONG Liangtao
	LI Haoyuan

Cite this article:

WANG Zixiao,XIONG Liangtao,LI Haoyuan. Research Progress on Thermal Conductivity and Thermoelectricity Applications of Covalent Organic Frameworks (COF) Materials[J]. Materials Reports, 2024, 38(12): 24040129-8.

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http://www.mater-rep.com/EN/10.11896/cldb.24040129 OR http://www.mater-rep.com/EN/Y2024/V38/I12/24040129

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