螺吡喃类刺激响应变色聚合物的研究进展

doi:10.11896/cldb.23060044

Abstract
Figure/Table
References
Related Citation (11)

Download:

Full Text ( PDF ) (15883KB)
Export: BibTeX | EndNote (RIS)

Abstract Spiropyrane, a class of compounds, displays diverse properties in response to a range of external stimuli encompassing physical, chemical, and biological factors. These stimuli induce changes in the structure, shape, and properties of spiropyran compounds. Within the spiropyran category, two isomers exist, namely a closed-loop spiropyran structure (SP) and an open-loop paroxycyanine structure (MC). Due to their uncomplicated structure, facile modification, and responsiveness to different stimuli, spiropyran compounds find extensive utility in the fabrication of stimuli-responsive polymers and chemical sensors. These versatile polymers and sensors have applications in various domains including construction, color-changing textiles, optical security, and ion detection. This paper presents a comprehensive review of the synthesis pathways employed for spiropyran compounds. The traditional three-step synthesis, one-pot synthesis, as well as newer techniques such as ultrasonic and microwave synthesis, are discussed. Furthermore, the paper delves into an examination of the photochromic, mechanochromic, solvatochromic, acidochromic, pressure chromism, and thermochromism exhibited by spiropyran polymers. The mechanism underlying these phenomena, factors influencing their manifestation, and practical applications are thoroughly discussed. Finally, the paper provides an outlook on the potential of spiropyran in the design and development of novel stimuli-response materials and chemical sensors.

Key words： stimuli-responsive polymers spiropyran photochromic mechanochromism chemical sensor

Published: 10 September 2024 Online: 2024-09-30

CLC number:

O62

Fund:National Natural Science Foundation of China (22378253,22078188) and Science and Technology Planning Project of Xianyang City (2021ZDZX-GY-0007).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	BAO Yan
	HAN Pei
	ZHANG Wenbo
	LIU Feng
	GAO Lu
	MA Jianzhong

Cite this article:

BAO Yan,HAN Pei,ZHANG Wenbo, et al. Research Progress of Spiropyrans Stimuli-responsive Chromotropic Polymers[J]. Materials Reports, 2024, 38(17): 23060044-9.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.23060044 OR http://www.mater-rep.com/EN/Y2024/V38/I17/23060044

1 Samanta S, Locklin J. Langmuir, 2008, 24, 9558.
2 Xiao M, Yan Z L, Wen X K, et al. Textile Auxiliaries, 2022, 39(4), 16 (in Chinese).
肖沭, 严智泷, 文馨可, 等. 印染助剂, 2022, 39(4), 16.
3 Wu J, Shen R B, Chen J Z, et al. Packaging Engineering, 2022, 43(9), 257 (in Chinese).
武军, 沈荣波, 陈俊忠, 等. 包装工程, 2022, 43(9), 257.
4 Ou Y M, Zhu R, Lyu X J, et al. Chemical Journal of Chinese Universities, 2019, 40(3), 576 (in Chinese).
欧阳密, 朱睿, 吕晓静, 等. 高等学校化学学报, 2019, 40(3), 576.
5 Wu J, Jiao X, Chen D, et al. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2021, 621, 126626.
6 Qi Y, Fan J, Chang Y, et al. Dyes and Pigments, 2021, 193, 109507.
7 Park S J, Juvekar V, Jo J H, et al. Chemical Science, 2020, 11, 596.
8 Zhang Y, Zhang Y, Song G, et al. Angewandte Chemie International Edition, 2019, 58, 18207.
9 Wang J X, Li C, Tian H. Coordination Chemistry Reviews, 2021, 427, 213579.
10 Chernyshev A V, Voloshin N A, Rostovtseva I A, et al. Dyes and Pigments, 2020, 178, 108337.
11 Kortekaas L, Browne W R. Chemical Society Reviews, 2019, 48, 3406.
12 Tran H M, Nguyen T H, Nguyen V Q, et al. Macromolecular Research, 2018, 27, 25.
13 Raeesi M, Alinejad Z, Hamrang V, et al. Journal of Colloid and Interface Science, 2020, 578, 379.
14 Zhou Y, Pang M, Zhu W, et al. Journal of Molecular Structure, 2020, 1219, 128574.
15 Zhao Q, Yang Y, Shen K, et al. Journal of Chemical Research, 2018, 42, 447.
16 Gorelik A М, Venidiktova О V, Kobeleva О I, et al. Dyes and Pigments, 2021, 184, 108833.
17 Kumar A, Kumar S. Journal of Molecular Structure, 2021, 1224, 129282.
18 Kinashi K, Ono Y, Naitoh Y, et al. Journal of Photochemistry and Photobiology A:Chemistry, 2011, 217, 35.
19 Liu A, Xiong C, Ma X, et al. Chinese Journal of Chemistry, 2019, 37, 793.
20 Rashidnejad H, Ramezanitaghartapeh M, Pesyan N N, et al. Journal of Molecular Structure, 2021, 1223, 129323.
21 Sarwar S, Park S, Dao T T, et al. Solar Energy Materials and Solar Cells, 2020, 210, 110498.
22 Li X, Wang Z, Chen K, et al. ACS Applied Materials & Interfaces, 2021, 13, 5312.
23 Guo J F, Zhao X L, Cao X Y, et al. Chemical Engineer, 2021, 35(9), 57 (in Chinese).
郭洁芬, 赵喜玲, 曹喜云, 等. 化学工程师, 2021, 35(9), 57.
24 Fischer E, Hirshberg Y. Journal of the Chemical Society, 1952, 11, 4522.
25 Fleming C L, Li S, Grotli M, et al. Journal of the American Chemical Society, 2018, 140, 14069.
26 Xia H, Xie K, Zou G. Molecules, 2017, 22, 12.
27 Ohya Y, Okuyama Y, Fukunaga A, et al. Supramolecular Science, 1998, 5, 21.
28 Beyer C, Wagenknecht H A. Journal of Organic Chemistry, 2010, 75, 2752.
29 Tomasulo M, Kaanumal S L, Sortino S, et al. Journal of Organic Chemistry, 2007, 72, 595.
30 Silvia T R, Ana V S L, González E A S. Synthetic Communications, 1995, 25, 105.
31 Ning T T. Journal of Luoyang Normal University, 2005(5), 54 (in Chinese).
宁婷婷. 洛阳师范学院学报, 2005(5), 54.
32 Laptev A V, Lukin A Y, Belikov N E, et al. Russian Chemical Bulletin, 2015, 63, 2026.
33 Galimov D I, Tuktarov A R, Sabirov D S, et al. Journal of Photochemistry and Photobiology A:Chemistry, 2019, 375, 64.
34 Solov'eva E V, Rostovtseva I A, Shepelenko K E, et al. Russian Journal of General Chemistry, 2018, 88, 968.
35 Laptev A V, Lukin A Y, Belikov N E, et al. Mendeleev Communications, 2013, 23, 145.
36 Ozhogin I V, Chernyavina V V, Lukyanov B S, et al. Journal of Molecular Structure, 2019, 1196, 409.
37 Dridi H, Boulmier A, Bolle P, et al. Journal of Materials Chemistry C, 2020, 8, 637.
38 May F, Peter M, Hutten A, et al. Chemistry, 2012, 18, 814.
39 Shi Z, Peng P, Strohecker D, et al. Journal of the American Chemical Society, 2011, 133, 14699.
40 Li W, Trosien S, Schenderlein H, et al. RSC Advances, 2016, 6, 109514.
41 Huang H M, Yang H B. Journal of Luoyang Normal University, 2010, 29(5), 72 (in Chinese).
黄华鸣, 杨红兵. 洛阳师范学院学报, 2010, 29(5), 72.
42 Metelitsa A, Chernyshev A, Voloshin N, et al. Dyes and Pigments, 2021, 186, 109070.
43 Pugachev A D, Ozhogin I V, Makarova N I, et al. Dyes and Pigments, 2022, 199, 110043.
44 Moldenhauer D, Grohn F. Chemistry, 2017, 23, 3966.
45 Burova A S, Venidiktova O V, Savelyev M A, et al. Materials Letters, 2021, 303, 130558.
46 Hammarson M, Andersson J, Li S, et al. Chemical Communications (Camb), 2010, 46, 7130.
47 Barachevsky V A, Valova T M, Atabekyan L S, et al. High Energy Chemistry, 2017, 51, 415.
48 Gao H, Guo T, Chen Y, et al. Journal of Molecular Structure, 2016, 1123, 426.
49 Zou W X, Tan Y F, Li X, et al. Chemical Journal of Chinese Universities, 2005(8), 1471 (in Chinese).
邹武新, 谈廷风, 李旭, 等. 高等学校化学学报, 2005(8), 1471.
50 Zhou Y, Yan Y, Du Y, et al. Sensors and Actuators B:Chemical, 2013, 188, 502.
51 Si L, Zhang Y, Yin Y, et al. Progress in Organic Coatings, 2021, 151, 106080.
52 Davis D A, Hamilton A, Yang J, et al. Nature, 2009, 459, 68.
53 O'Bryan G, Wong B M, McElhanon J R. ACS Applied Materials & Interfaces, 2010, 2, 1594.
54 Caruso M M, Davis D A, Shen Q, et al. Chemical Reviews, 2009, 109, 5755.
55 Lee C K, Davis D A, White S R, et al. Journal of the American Chemical Society, 2010, 132, 16107.
56 Ciardelli F, Ruggeri G, Pucci. Chemical Society Reviews, 2013, 42, 857.
57 Kim J W, Jung Y, Coates G W, et al. Macromolecules, 2015, 48, 1335.
58 Kingsbury C M, May P A, Davis D A, et al. Journal of Materials Chemistry, 2011, 21, 8381.
59 Li M, Zhang Q, Zhu S. Polymer, 2016, 99, 521.
60 Balasubramanian G, Schulte J, Müller-Plathe F, et al. Chemical Physics Letters, 2012, 554, 60.
61 Eilmes A J. Journal of Physical Chemistry A, 2013, 117, 2629.
62 Tian W, Tian J. Dyes and Pigments, 2014, 105, 66.
63 Kozlenko A S, Makarova N I, Ozhogin I V, et al. Mendeleev Communications, 2021, 31, 403.
64 Shiraishi Y, Takagi S, Yomo K, et al. ACS Omega, 2021, 6, 35619.
65 Abdollahi A, Mahdavian A R, Salehi-Mobarakeh H. Langmuir, 2015, 31, 10672.
66 Abdollahi A, Rad J K, Mahdavian A R. Carbohydr Polym, 2016, 150, 131.
67 Nam Y S, Yoo I, Yarimaga O, et al. Chemical Communications (Camb), 2014, 50, 4251.
68 Darwish T A, Evans R A, James M, et al. Chemistry, 2011, 17, 11399.
69 Genovese M E, Athanassiou A, Fragouli D. Journal of Materials Chemistry A, 2015, 3, 22441.
70 Wan S, Zheng Y, Shen J, et al. ACS Applied Materials & Interfaces, 2014, 6, 19515.
71 Wilson D G, Drickamer H G. The Journal of Chemical Physics, 1975, 63, 3649.
72 Funasako Y, Takaki A, Inokuchi M, et al. Chemistry Letters, 2016, 45, 1397.
73 Iqbal A, Iqbal G, Umar M N, et al. Royal Society Open Science, 2022, 9, 211385.
74 Liu G, Li Y, Cui C, et al. Journal of Photochemistry and Photobiology A:Chemistry, 2022, 424, 113658.
75 Shiraishi Y, Adachi K, Itoh M, et al. Organic Letters, 2009, 11, 3482.
76 Florea L, McKeon A, Diamond D, et al. Langmuir, 2013, 29, 2790.