基于组氨酸配合物的钯催化剂的制备及2-戊基蒽醌加氢性能

doi:10.11896/cldb.23030130

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Abstract In order to improve the catalytic activity and selectivity of the catalyst for anthraquinone hydrogenation, a series of Pd-his/SiO₂-T (his represents histidine, and T is the calcination temperature) catalysts were prepared by impregnation method, with the coordination complex of Pd-(NO₃)₂ and histidine as the precursor. The catalysts were prepared with SiO₂ as the support through impregnation method under different calcination temperatures, and applied in anthraquinone hydrogenation reaction. For comparison, a Pd/SiO₂-500 catalyst free of histidine was prepared with the optimal calcination temperature, and other conditions were kept the same. The SiO₂ support and all the catalysts were investigated by various characterization techniques in detail. It was found that, with the calcination temperature rising, the Pd dispersion of catalysts decreased during 300—400 ℃, however from 400 ℃ to 600 ℃, the Pd dispersion nearly kept the same. The content of residual carbon species shrank, while the ratio of Pd⁰ component and its electron cloud density increased. The evaluation of anthraquinone hydrogenation showed that the highest hydrogenation efficiency of the catalysts reached 12.8 g/L, which was 2.13 times as the Pd/SiO₂-500, and has a superior selectivity of 99.67%.

Key words： anthraquinone hydrogenation Pd histidine calcination temperature dispersion

Published: 25 June 2024 Online: 2024-07-17

CLC number:	TQ426.63
	TQ123.6

Fund:National Natural Science Foundation of China (21306184).

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	Articles by authors
	YAN Hua
	YANG Xiaoye
	ZHOU Junhong
	YUAN Zhongshan
	LI Defu
	WANG Shudong

Cite this article:

YAN Hua,YANG Xiaoye,ZHOU Junhong, et al. Preparation of Pd Catalysts with Histidine Coordination Complex and Their Catalytic Performances on 2-Amylanthraquinone Hydrogenation[J]. Materials Reports, 2024, 38(12): 23030130-6.

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http://www.mater-rep.com/EN/10.11896/cldb.23030130 OR http://www.mater-rep.com/EN/Y2024/V38/I12/23030130

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