基于静电和金属络合协同作用的MIL-101(Cr)-NH<sub>2</sub>高效吸附水中单宁酸

doi:10.11896/cldb.22100069

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Abstract An amino-functionalized MIL-101(Cr) (namely MIL-101(Cr)-NH₂) was prepared by hydrothermal method and its adsorption performance of tannic acid in aqueous solution was investigated by batch experiments. The structure and morphology of MIL-101(Cr)-NH₂ were characterized through powder X-ray diffraction instrument (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption-desorption isotherms. The effects of initial pH, adsorption time, initial concentration and ion strength on the adsorption performance of tannic acid were explored and the adsorption mechanism was studied. The adsorption capacity of tannic acid onto MIL-101(Cr)-NH₂ gradually increased with the increasing pH value and the optimal pH value was 7.0. The pseudo-second-order kinetic model, Freundlich model, and Temkin model fitted the adsorption data well, which indicated that tannic acid was adsorbed onto MIL-101(Cr)-NH₂ by multilayer adsorption and the adsorption process was dominated by chemisorption. The fitting results of diffusion models suggested that film diffusion and intra-particle diffusion affected the adsorption process together. At T=303 K and pH=7, the equilibrium adsorption capacity of MIL-101(Cr)-NH₂ was up to 2 031 mg/g. The main mechanism controlling the adsorption of tannic acid onto MIL-101(Cr)-NH₂ are the electrostatic interaction and Cr-O complexation interaction.

Key words： MIL-101(Cr)-NH₂ adsorption tannic acid electrostatic interaction complexation interaction

Published: 25 July 2024 Online: 2024-08-12

CLC number:	X52
	TQ46

Fund:Natural Science Foundation of Hebei Province (B2020208095), Youth Found of Education Department of Hebei Province (QN2022142), and Qinghai Haixi Science and Technology Bureau (Enterprise Innovation Fund Program 2019-104).

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	Articles by authors
	LI Yunlong
	LIU Yixian
	LIU Miao
	HAN Jilong
	ZHOU Lilong
	LI Zhengjie
	YUN Jimmy
	LIU Runjing

Cite this article:

LI Yunlong,LIU Yixian,LIU Miao, et al. Efficiently Remove Tannic Acid from Aqueous Solution by MIL-101(Cr)-NH₂ Based on the Synergistic Effect of Electrostatic and Complexation Interaction[J]. Materials Reports, 2024, 38(14): 22100069-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22100069 OR http://www.mater-rep.com/EN/Y2024/V38/I14/22100069

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