Please wait a minute...
材料导报  2025, Vol. 39 Issue (22): 24100225-7    https://doi.org/10.11896/cldb.24100225
  金属与金属基复合材料 |
硬钎剂的技术及应用研究进展
董宏伟, 钟素娟, 董媛媛, 尤明珠, 王东亮, 张冠星*
中国机械总院集团郑州机械研究所有限公司,高性能新型焊接材料全国重点实验室,郑州 450001
Research Progress on Technology and Application of Brazing Flux
DONG Hongwei, ZHONG Sujuan, DONG Yuanyuan, YOU Mingzhu, WANG Dongliang, ZHANG Guanxing*
State Key Laboratory of High Performance & Advanced Welding Materials, China Academy of Machinery Zhengzhou Research Institute of Mechanical Engineering Co.,Ltd., Zhengzhou 450001, China
下载:  全 文 ( PDF ) ( 11242KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 钎剂是钎焊过程的核心辅料,其性能与选择直接关系到钎焊接头的质量与可靠性。本文全面梳理和总结近年来硬钎料用钎剂的作用机制、去膜原理及类型、成分优化与制备、选择使用及后处理、标准规范等方面的技术研究进展,通过归纳研究思路、创新方法和存在的问题,提出了加强对硬钎剂-母材界面耦合反应机理、钎剂元素动力学迁移过程的技术研究,注重钎剂的绿色高效制备与应用,推进钎剂相关标准制定等方面的建议,以期为相关领域的研究人员和技术人员提供参考和借鉴,共同推动钎剂的持续创新与发展。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
董宏伟
钟素娟
董媛媛
尤明珠
王东亮
张冠星
关键词:  硬钎剂  反应机制  钎剂成分    
Abstract: As the core auxiliary material of brazing process, the properties and selection of flux are directly related to the quality and reliability of brazing joints. This paper comprehensivIely reviews and summarizes the technical research progress in recent years in the mechanism of action of brazing agent, the principle and type of film removal, composition optimization and preparation, selection and use, post-treatment, standards and other aspects of brazing agent for brazing filler metal, and summarizes the research ideas, innovative methods and existing problems. In order to provide reference for researchers and technicians in related fields and promote the continuous innovation and development of flux, some suggestions are put forward to strengthen the interface coupling reaction mechanism of the base material of hard flux, pay attention to the green and efficient preparation and application of flux, and promote the development of flux related standards.
Key words:  brazing flux    reaction mechanism    flux composition
出版日期:  2025-11-25      发布日期:  2025-11-14
ZTFLH:  TG454  
基金资助: 河南省科技研发计划联合基金(225200810013);河南省中央引导地方科技发展资金(Z20231811002)
通讯作者:  *张冠星,博士,正高级工程师,主要围绕国家重点发展的先进金属材料,开展关于先进加工工艺以及组织性能控制的基础理论和应用研究。zgx_1983102@163.com   
作者简介:  董宏伟,硕士,工程师,主要从事新型钎焊材料、钎焊工艺开发等工作。
引用本文:    
董宏伟, 钟素娟, 董媛媛, 尤明珠, 王东亮, 张冠星. 硬钎剂的技术及应用研究进展[J]. 材料导报, 2025, 39(22): 24100225-7.
DONG Hongwei, ZHONG Sujuan, DONG Yuanyuan, YOU Mingzhu, WANG Dongliang, ZHANG Guanxing. Research Progress on Technology and Application of Brazing Flux. Materials Reports, 2025, 39(22): 24100225-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24100225  或          https://www.mater-rep.com/CN/Y2025/V39/I22/24100225
1 Xue S B, Wang B, Zhang L, et al. Materials Reports, 2019, 33(17), 2813 (in Chinese).
薛松柏, 王博, 张亮, 等. 材料导报, 2019, 33(17), 2813.
2 Li Y B, Ma Y W, Lou M, et al. Journal of Mechanical Engineering, 2016, 52(24), 1 (in Chinese).
李永兵, 马运五, 楼铭, 等. 机械工程学报, 2016, 52(24), 1.
3 He Y M, Zhao X Q, Lang H Z, et al. Transactions of Nonferrous Metals Society of China, 2023, 33(11), 3662 (in Chinese).
贺艳明, 赵小强, 郎红专, 等. 中国有色金属学报, 2023, 33(11), 3662.
4 Li X Y, Wu C S, Li W S. Journal of Mechanical Engineering, 2012, 48(6), 19 (in Chinese).
李晓延, 武传松, 李午申. 机械工程学报, 2012, 48(6), 19.
5 Shi J W, Wen Y H. Modern electronic assembly soldering technology, Publishing House of Electronics Industry, China, 2015, pp.265 (in Chinese).
史建卫, 温粤晖. 现代电子装联软钎焊接技术, 电子工业出版社, 2015, pp.265.
6 Chang Q, Zhang L X. Transactions of the China Welding Institution, 2022, 43(12), 1 (in Chinese).
常青, 张丽霞. 焊接学报, 2022, 43(12), 1.
7 Wang X X, Wu G, He P, et al. Rare Metal Materials and Engineering, 2022, 51(7), 2689 (in Chinese).
王星星, 吴港, 何鹏, 等. 稀有金属材料与工程, 2022, 51(7), 2689.
8 Xiong H P, Li H, Mao W, et al. Transactions of the China Welding Institution, 2011, 32(5), 108 (in Chinese).
熊华平, 李红, 毛唯, 等. 焊接学报, 2011, 32(5), 108.
9 Long W M, Zhang Q K, Zhu K, et al. Welding, 2014(1), 3 (in Chinese).
龙伟民, 张青科, 朱坤, 等. 焊接, 2014(1), 3.
10 GB/T 15829-2021软钎剂 分类与性能要求.
11 Chen H Y, Lai Z M, Chen Z L, et al. Hot Working Technology, 2018, 47(19), 213 (in Chinese).
陈海燕, 赖振民, 陈子良, 等. 热加工工艺, 2018, 47(19), 213.
12 Cheng F J, Yang J X, Zhao H W, et al. Transactions of the China Wel-ding Institution, 2013, 34(6), 5 (in Chinese).
程方杰, 杨俊香, 赵海微, 等. 焊接学报, 2013, 34(6), 5.
13 Jin X, Yang C J, Liu B X. Electronic Process Technology, 2008(2), 112 (in Chinese).
金霞, 杨倡进, 刘保祥. 电子工艺技术, 2008(2), 112.
14 Guan Y X, Xue S B, Han R N, et al. Transactions of the China Welding Institution, 2013, 34(2), 101.
管永星, 薛松柏, 韩若男, 等. 焊接学报, 2013, 34(2), 101.
15 Zhang M, Zhang S, Li Y, et al. Materials Letters, 2020, 260, 126977.
16 Li X, Sun W, Ning G. Journal of Materials Research and Technology, 2024, 29, 4547.
17 Zhang G X, Zhong S J, Dong Y Y, et al. Welding, 2022(11), 47 (in Chinese).
张冠星, 钟素娟, 董媛媛, 等. 焊接, 2022(11), 47.
18 Woods W G. Environmental Health Perspectives, 1994, 102, 5.
19 Aghili S, Panjepour M, Meratian M. Reaction Kinetics, Mechanisms and Catalysis, 2022, 135(1), 349.
20 Zhao Y, Long W M, Huang S, et al. Rare Metal Materials and Engineering, 2022, 51(12), 4502.
21 Zhou F M, Xu D H, Shi M X, et al. High Temperature Materials and Processes, 2020, 39, 88.
22 Zhao Yue, Long Weimin, Huang Sen, et al. Rare Metal Materials and Engineering, 2021, 50(11), 3857.
23 Roberts P M. Introduction to brazing technology, CRC Press, USA, 2016, pp.131
24 Zhang Q Y, Zhuang H S. Handbooks of brazing and soldering, 3rd Edition, China Machine Press, China, 2017, pp.141 (in Chinese).
张启运, 庄鸿寿. 钎焊手册3版. 机械工业出版社, 2017, pp.141.
25 Zhang Yingli, Zhou Yuhua. Handbooks of welding materials, Chemical Industry Press, China, 2019, pp.379 (in Chinese)
张应立, 周玉华. 焊接材料手册, 化学工业出版社, 2019, pp.379.
26 Wei G Q, He Y B. Welding Technology, 2005, 34(6), 56 (in Chinese).
卫国强, 何艳兵. 焊接技术, 2005, 34(6), 56.
27 Cole S S, Taylor N W. Journal of the American Ceramic Society, 1935, 18, 82.
28 Wu C G, Zhang L J, Chai Y Q. Welding, 2003(12), 29 (in Chinese).
伍成根, 张露菁, 柴艳倩. 焊接, 2003(12), 29.
29 Zhang L Q, Zhu Q H, Gu R N. Journal of China Textile University, 1999(1), 98 (in Chinese).
张露菁, 朱庆华, 顾润南. 中国纺织大学学报, 1999(1), 98.
30 Wu C G, Zhang L G. Welding, 2002(10), 29 (in Chinese).
伍成根, 张露菁. 焊接, 2002(10), 29.
31 Gao N Z. Machine Worker (Hot Processing), 1995(1), 13 (in Chinese).
高念宗. 机械工人(热加工), 1995(1), 13.
32 Shan J G, Jiang G Q, Ren J L. Welding, 1998(3), 5 (in Chinese).
单际国, 姜光强, 任家烈. 焊接, 1998(3), 5.
33 Li G Z. Metallurgy Series, 1995(5), 36 (in Chinese).
黎光照. 冶金丛刊, 1995(5), 36.
34 Cui M D. Electronic Technology, 1985(9), 10 (in Chinese).
崔明道. 电子工艺技术, 1985(9), 10.
35 Winiowski A, Majewski D. Archives of Metallurgy and Materials, 2012, 57(2), 545.
36 Xu J F, Wang B F, Shan L Y, et al. Welding Technology, 1995(6), 24 (in Chinese).
徐金富, 王秉芳, 单丽云, 等. 焊接技术, 1995(6), 24.
37 Cheng G Y, Gao X Z, Fu C X. Welding Communication, 1984(4), 10 (in Chinese).
程光玉, 高湘芝, 付承信. 焊接通讯, 1984(4), 10.
38 Xie G S, Wu Y, Qi Y, et al. Hot Working Technology, 2023, 52(9), 148 (in Chinese).
谢贵生, 武媛, 齐影, 等. 热加工工艺, 2023, 52(9), 148.
39 Sheng C X. Fine Chemical Information, 1987(5), 37 (in Chinese).
盛承祥. 精细化工信息, 1987(5), 37.
40 Liu X X. Welding Technology, 1989(4), 46 (in Chinese).
刘希贤. 焊接技术, 1989(4), 46.
41 He H, Yang C, Lin S, et al. Science and Technology of Welding and Joining, 2014, 19(6), 527.
42 Xue S B. Welding, 1995(9), 7 (in Chinese).
薛松柏. 焊接, 1995(9), 7.
43 Chen H Y, Yi J, Zhang H Y, et al. Electronic Components and Materials, 2010, 29(8), 51 (in Chinese).
陈海燕, 易骏, 张海燕, 等. 电子元件与材料, 2010, 29(8), 51.
44 Chen H Y, Li W M, Li F, et al. Transactions of the China Welding Institution, 2005, 26(7), 75 (in Chinese).
陈海燕, 李卫民, 李风, 等. 焊接学报, 2005, 26(7), 75.
45 Zhang N, Ge J G, Qiang Y H, et al. Hot Working Technology, 2013, 42(21), 194 (in Chinese).
张宁, 葛进国, 强颖怀, 等. 热加工工艺, 2013, 42(21), 194.
46 张冠星, 龙伟民, 钟素娟, 等. 中国专利, CN201910993164. 1, 2021.
47 Long W M, Li S N, Du D, et al. Rare Metal Materials and Engineering, 2019, 48(12), 3781.
48 Daniel H. Welding Journal, 2007, 86(3), 53.
49 Shin Y S, Lee Y S, Lee C H. In:3rd International Brazing and Soldering Conference. San Antonio, Texas, USA, 2006, pp.136.
50 Zhu H X, Yu W Y. Hot Working Technology, 2018, 47(7), 204 (in Chinese).
朱海旭, 俞伟元. 热加工工艺, 2018, 47(7), 204.
51 Du Q B, Long W M, Lu Q B, et al. Materials Engineering, 2017, 45(11), 96 (in Chinese).
杜全斌, 龙伟民, 路全彬, 等. 材料工程, 2017, 45(11), 96.
52 Zhao L, Pang W H, Cao X K. Water Supply and Drainage, 2017, 53(5), 73 (in Chinese).
赵利, 庞维海, 曹兴坤. 给水排水, 2017, 53(5), 73.
53 Li X P, Long W M, Chen X, et al. Transactions of the China Welding Institution, 2015, 36(3), 97 (in Chinese).
李秀朋, 龙伟民, 陈曦, 等. 焊接学报, 2015, 36(3), 97.
54 Huang H P, Jie X H, Liang X H, et al. Hot Working Technology, 2008(9), 1 (in Chinese).
黄惠平, 揭晓华, 梁兴华, 等. 热加工工艺, 2008(9), 1.
55 Song B, Yang H K, Jiang S Q, et al. Machine Manufacturing Abstracting (Welding Sub-Volume), 2019(4), 45 (in Chinese).
宋北, 杨宏坤, 蒋士芹, 等. 机械制造文摘(焊接分册), 2019(4), 45.
[1] 朱万利, 包建勋, 张舸, 崔聪聪. 金刚石/碳化硅复合材料的研究进展[J]. 材料导报, 2023, 37(10): 22100263-8.
[1] JIN Qinglin, WANG Yang, CAO Lei, SONG Qunling. Effect of Nitriding in Mushy Zone on the Nitrogen Content and Solidification Transformation of Cr10Mn9Ni0.7 Alloy[J]. Materials Reports, 2018, 32(4): 579 -583 .
[2] WANG Shengmin, ZHAO Xiaojun, HE Mingyi. Research Status and Development of Mechanical Plating[J]. Materials Reports, 2017, 31(5): 117 -122 .
[3] HE Yuandong, SUN Changzhen, MAO Weiguo, MAO Yiqi, ZHANG Honglong, CHEN Yanfei, PEI Yongmao, FANG Daining. Measurement of Transverse Piezoelectric Coefficients of Pb(Zr0.52Ti0.48)O3 Thin Films by a Mechano-electrical Multiphysics Coupling, Bulge Test Method[J]. Materials Reports, 2017, 31(15): 139 -144 .
[4] TAO Lei, ZHENG Yunwu,DI Mingwei, ZHANG Yanhua, ZHENG Zhifeng. Preparation of Porous Carbon Nanofiber from Liquid Phenolic Resin and Its Characterization[J]. Materials Reports, 2017, 31(10): 101 -106 .
[5] SU Lan, ZHANG Chubo, WANG Zhen, MI Zhenli. Finite Element Simulation of Electromagnetic Induction Heating in Hot Metal Gas Forming[J]. Materials Reports, 2017, 31(24): 182 -177 .
[6] QI Yaping, LUO Faliang, WANG Kezhi, SHEN Zhiyuan, WU Xuejian, WANG Diran. Effect of TMC-300 on the Performance of PLLA/PPC Alloy[J]. Materials Reports, 2018, 32(10): 1672 -1677 .
[7] DU Min, SONG Dian, XIE Ling, ZHOU Yuxiang, LI Desheng, ZHU Jixin. Electrospinning in Rechargeable Ion Batteries for High Efficient Energy Storage[J]. Materials Reports, 2018, 32(19): 3281 -3294 .
[8] LIU Xiao, XU Qian, LAI Guanghong, GUAN Jianan, XIA Chunlei, WANG Ziming, CUI Suping. Application Performances and Mechanism of Polycarboxylic Acid in Different Comb-bonded Structures in High-performance Concrete[J]. Materials Reports, 2018, 32(22): 4011 -4015 .
[9] ZHANG Di, YANG Di, XU Cui, ZHOU Riyu, LI Hao, LI Jing, WANG Peng. Study on Mechanism of Highly Effective Adsorption of Bisphenol F by Reduced Graphene Oxide[J]. Materials Reports, 2019, 33(6): 954 -959 .
[10] LIU Hongyin, YANG Hongyu, CHEN Mingfeng. Impact of Isocyanate Index on Flame Retardancy, Thermal Stability andCombustion Behaviors of Rigid Polyurethane Foam[J]. Materials Reports, 2019, 33(12): 2071 -2075 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed