Research Status and Development of Tungsten Alloy for Throat Lining
GUO Tianyao1, DOU Caihong1,*, WANG Changji1, ZHANG Lingfeng1, YU Hua1, PAN Kunming1, CUI Hailin2, DONG Di3
1 School of Materials Science and Engineering, Henan University of Science and Technology , Luoyang 471000, Henan, China 2 The Key Laboratory of Transient Impact Technology, Beijing 102200, China 3 ATTL Advanced Materials Co.,Ltd., Tianjin 301817, China
Abstract: Throat lining materials are closely related not only to engine safety, but also to indicators such as thrust and reliability. With the continuous improvement of engine performance, the service conditions of throat lining are becoming more and more harsh, and the commonly used throat lining materials have been difficult to meet the performance requirements due to insufficient thermal shock resistance, low mechanical properties at high temperatures, and weak ablation resistance. In this paper, the research progress of tungsten alloy throat lining materials at home and abroad is systematically summarized, and the shortcomings of the preparation technology, sintering process, and molding technology of the existing tungsten alloy precursor powder are identified. Taking into account the progress and achievements of the project team in the powder preparation process and forming technology of tungsten alloy throat lining materials for throat lining. The development trend of new tungsten alloy throat lining materials is proposed. This may provide a solid technical support for the performance improvement of a new generation of high-thrust solid engines from the aspect of throat lining materials.
郭天瑶, 窦彩虹, 王长记, 张凌峰, 于华, 潘昆明, 崔海林, 董帝. 喉衬用钨合金的研究现状及发展[J]. 材料导报, 2025, 39(18): 24060138-9.
GUO Tianyao, DOU Caihong, WANG Changji, ZHANG Lingfeng, YU Hua, PAN Kunming, CUI Hailin, DONG Di. Research Status and Development of Tungsten Alloy for Throat Lining. Materials Reports, 2025, 39(18): 24060138-9.
1 Liu J J, Li T H, Hao Z B. Aerospace Materials and Technology, 2005(1), 42(in Chinese). 刘建军, 李铁虎, 郝志彪. 航宇材料工艺, 2005(1), 42. 2 Song G M, Zhou Y, Wang Y J, et al. Journal of Solid Rocket Technology, 1998, 21(2), 51(in Chinese). 宋桂明, 周玉, 王玉金, 等. 固体火箭技术, 1998, 21(2), 51. 3 Chen B, Zhang L T, Cheng L F, et al. Journal of Inorganic Materials, 2008, 23(5), 938(in Chinese). 陈博, 张立同, 成来飞, 等. 无机材料学报, 2008, 23(5), 938. 4 Chen J, Wei X G, Li J, et al. Journal of Solid Rocket Technology, 2010, 33(1), 34(in Chinese). 陈剑, 魏祥庚, 李江, 等. 固体火箭技术, 2010, 33(1), 34. 5 Zheng X, Bai R, Wang D H, et al. Rare Metal Materials and Engineering, 2011, 40(10), 1871(in Chinese). 郑欣, 白润, 王东辉 等. 稀有金属材料与工程, 2011, 40(10), 1871. 6 Tao G Y, Zheng Z Q, Liu S H, et al. Acta Materiae Compositae Sinica, 2006, 23(4), 72(in Chinese). 陶光勇, 郑子樵, 刘孙和, 等. 复合材料学报, 2006, 23(4), 72. 7 Zhu Y, Sun J T, Yan L S, et al. Journal of Functional Materials, 2019, 50(6), 6206(in Chinese). 朱阳, 孙建涛, 闫联生, 等. 功能材料, 2019, 50(6), 6206. 8 Xiao J, Yang X G, Lin X S, et al. Aero Weaponry, 2009(6), 61(in Chinese). 肖军, 杨晓光, 林学书, 等. 航空兵器, 2009(6), 61. 9 Wang Y, Liang S S, Luo N, et al. Rare Metal Materials and Engineering, 2016, 45(2), 329. 10 Chen W, Zhou W P, Kuang Y G, et al. Powder Metallurgy Industry, 2004, 14(2), 17(in Chinese). 陈伟, 周武平, 邝用庚, 等. 粉末冶金工程, 2004, 14(2), 17. 11 Chen W, Zhou W P, Kuang Y G, et al. Aerospace Materials & Technology, 2005(1), 56(in Chinese). 陈伟, 周武平, 邝用庚, 等. 宇航材料工艺, 2005(1), 56. 12 Xu T Q. Aerospace China, 1985(9), 42(in Chinese). 徐涛清. 中国航天, 1985(9), 42. 13 Lin B T, Yu X B, Zhang B H, et al. Journal of Ordnance Equipment Engineering, 2020, 41(12), 214(in Chinese). 林冰涛, 余小波, 张保红, 等. 兵器装备工程学报, 2020, 41(12), 214. 14 Senthilnathan Natarajan, Venkatachalam Gopalan, Raja Annamalai Arunjunai Rajan, et al. Materials, 2021, 14(7), 1660. 15 Qin M L, Chen Z, Chen P Q, et al. International Journal of Refractory Metals and Hard Materials, 2021, 68, 145. 16 Deng S H, Yuan T C, Li R D, et al. International Powder Technology, 2017, 68, 264. 17 Ren J P, Wang Y, Zhao J, et al. Rare Metals and Cemented Carbides, 2020, 48(4), 17(in Chinese). 任俊鹏, 王毓, 赵君, 等. 稀有金属与硬质合金, 2020, 48(4), 17. 18 Borji S, Ahangarkani M, Zangeneh-mader K, et al. International Journal of Refractory Metals and Hard Materials, 2017, 68, 150. 19 Tang L L, Zhang B H, Lin B T, et al. China Molybdenum Industry, 2019, 43(5), 35(in Chinese). 唐亮亮, 张保红, 林冰涛, 等. 中国钼业, 2019, 43(5), 35. 20 Yu J X, Wang X P. Physics Examination and Testing, 2021, 39(5), 20(in Chinese). 余建新, 王晓鹏. 物理测试, 2021, 39(5), 20. 21 Li Y C. High temperature mechanical behavior and ablative propertise of W-3Re-xHfC Alloys. Ph. D. Thesis, Xi'an University of Technology, China, 2022(in Chinese). 李延超. W-3Re-xHfC合金的高温力学行为与抗烧蚀性能研究. 博士学位论文, 西安理工大学, 2022. 22 Li Y C, Zhang W, Li J F, et al. Materials Science and Engineering:A, 2021, 818, 141198. 23 Li Y C, Zhang W, Lin X H, et al. International Journal of Refractory Metals and Hard Materials, 2023, 113, 106186. 24 Kwang S. Shin, Anhua Luo, Bor-Liang Chen. et al. JOM, 1990, 42(8), 12. 25 John J Park. Materials Science and Engineering:A, 1999, 265(1), 174. 26 Wang L W, Tian W P, Guo Y Q, et al. Journal of Solid Rocket Technology, 2019, 42(2), 135(in Chinese). 王立武, 田维平, 郭运强, 等. 固体火箭技术, 2019, 42(2), 135. 27 Gao Y, Cha B L, Wang J J. Hi-Tech Fiber and Application, 2020, 45(4), 1(in Chinese). 高勇, 查柏林, 王金金. 高科技纤维与应用, 2020, 45(4), 1. 28 Xue N J, Zhao Z X, Zhao D M, et al. Materials Reports, 2023, 37(1), 112(in Chinese). 薛宁娟, 赵枝香, 赵大明, 等. 材料导报, 2023, 37(1), 112. 29 Su J M, Zhou S J, Xue N J, et al. New Carbon Materials, 2018, 33(5), 442(in Chinese). 苏君明, 周绍建, 薛宁娟, 等. 新型碳材料, 2018, 33(5), 442. 30 Qu J H, Wei Y J, Lu F S, et al. Chinese Journal of Rare Metals, 2014, 38(4), 622(in Chinese). 曲家惠, 魏岩峻, 卢风生, 等. 稀有金属, 2014, 38(4), 622. 31 Chen W, Kuang Y G, Zhou W P. Rare Metal Materials and Engineering, 2004, 33(1), 11(in Chinese). 陈伟, 邝用庚, 周武平. 稀有金属材料与工程, 2004, 33(1), 11. 32 Kuang Y G, Mou K Q, Xu G L, et al. Rare Metal Materials and Engineering, 1997, 26(5), 30(in Chinese). 邝用庚, 牟科强, 徐桂兰, 等. 稀有金属材料与工程, 1997, 26(5), 30. 33 Zhang N N, Yi C. China Ceramics, 2014, 50(4), 47(in Chinese). 张宁宁, 伊超. 中国陶瓷, 2014, 50(4), 47. 34 Li D Y, Li W G, Zhang W B, et al. Materials & Design, 2012, 37, 211. 35 Xu X, Chen P Q, Tai Y X, et al. Materiae Compositae Sinica, 2021, 38(23), 4025(in Chinese). 徐仙, 陈鹏起, 台云霄, 等. 复合材料学报, 2021, 38(23), 4025. 36 Lee D, Umer M A, Ryu H J, et al. Journal of Refractory Metals and Hard Materials, 2014, 43, 89. 37 Yi J, Xiong X, Zhang H B, et al. Materials Reports, 2004, 18(4), 46(in Chinese). 尹健, 熊翔, 张红波, 等. 材料导报, 2004, 18(4), 46. 38 Liang H R, Liu Y M, Zhao K Y, et al. Materials Protection, 2024, 57(3), 1(in Chinese). 梁浩然, 刘艳明, 赵科遥, 等. 材料保护, 2024, 57(3), 1. 39 Mao S B, Yang Y, Li H Q, et al. Chinese Journal of Process Engineering, 2019, 19(4), 826(in Chinese). 毛绍宝, 杨英, 李海庆, 等. 过程工程学报, 2019, 19(4), 826. 40 Mou K Q, Xu K D, Wei A B, et al. Journal of Iron and Steel Research, 1995, 7(5), 89(in Chinese). 牟科强, 徐克玷, 韦昂邦, 等. 钢铁研究学报, 1995, 7(5), 89. 41 Mou K Q, Xu K D, Wei A B, et al. In:7th Conference of Refractory Metals of China. Hawaii, 1991, pp. 98. 42 Liu Y L. Study of microscopic defects and helium behavior in tungsten and tungsten-rhenium alloys in plasma environment. Master's Thesis, Chengdu University of Technology, China, 2019(in Chinese). 刘永利. 面向等离子体材料钨及钨铼合金中微观缺陷与氦行为研究. 硕士学位论文, 成都理工大学, 2019. 43 Luo L M, Xu W Z. China Tungsten Industry, 2022, 37(1), 1(in Chinese). 罗来马, 徐旺之. 中国钨业, 2022, 37(1), 1. 44 Shi J B, Song J P, Liang M X, et al. Nuclear Materials and Energy, 2024, 38, 101609. 45 Shuhei Nogami, Akira Hasegawa, Makoto Fukuda, et al. Fusion Engineering and Design, 2020, 152, 111445. 46 Daniel Caillard. Acta Materialia, 2020, 194, 249. 47 Zhang Y H, En M, Sun J, et al. Acta Materialia, 2024, 264, 119586. 48 Zhang L, Nie R X, Wang J, et al. Cemented Carbides, 2023, 40(6), 413(in Chinese). 张立, 聂仁鑫, 王喆, 等. 硬质合金, 2023, 40(6), 413. 49 Shotaro Watanabe, Shuhei Nogami, Jens Reiser, et al. Fusion Engineering and Design, 2019, 148, 111323. 50 Yao H L, Wang C Y, Liu J, et al. China Tungsten Industry, 2022, 37(1), 60(in Chinese). 姚惠龙, 王承阳, 刘洁, 等. 中国钨业, 2022, 37(1), 60. 51 Klopp W D, Witzke W R. Fusion Engineering and Design, 1971, 24(4), 427. 52 Zhao B L, Xie Z M, Liu R, et al. Fusion Engineering and Design, 2021, 164, 112208. 53 Kurishita H, Matsuo S, Arakawa H, et al. Physica Scripta, 2014, 2014, T150. 54 Wang Z F, Ai D W, Wang K J, et al. Materials Reports, 2024, 38(S1), 130(in Chinese). 王卓凡, 艾德文, 王坤杰, 等. 材料导报, 2024, 38(S1), 130. 55 O'Dell J S, Mckechnie T N. International Thermal Spray Conference, 2008, 83683, 288. 56 Witzke W R. Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 1974, 5(2), 449. 57 Zheng Z H, Lai C, Zhou W Y, et al. Materials, 2024, 17(1), 102. 58 Eckley C C, Kemnitz R A, Fassio C P, et al. JOM, 2021, 73(11), 3439. 59 Skotnicova K, Kirillova V M, Ermishkin V A, et al. Materials Science and Engineering:A, 2015, 636, 536. 60 Stephenson R L. Journal of the Less Common Metals, 1971, 24(2), 173. 61 Xiong N, Dong D, Wang C Y, et al. Materials Research Express, 2022, 9(3), 036509. 62 Ma L P, Liu W C. Rare Metal Materials and Engineering, 2008, 37(6), 28(in Chinese). 马立蒲, 刘为超. 有色金属加工, 2008, 37(6), 28. 63 Xiong N, Dong D, Wang C Y, et al. Materials Research Express, 2022, 9(3), 036509. 64 Li Z. Microstructure and properties of zirconia doped tungsten alloy prepared by liquid phase method. Ph. D. Thesis, China Academy of Mechanical Science & Technology, China, 2022(in Chinese). 李洲. 液相法制备氧化锆掺杂钨合金的组织和性能. 博士学位论文, 机械科学研究总院, 2022. 65 Wang C J. Preparation, microstructure and mechanical properties of Al2O3 particle reinforecd tungsten alloys. Ph. D. Thesis, University of Science and Technology Beijing, China, 2021(in Chinese). 王长记. Al2O3颗粒增强W合金的制备、组织结构与力学性能. 博士学位论文, 北京科技大学, 2021. 66 Sun D F, Sun Z C, Gu Z, et al. Heat Treatment of Metals, 2023, 48(3), 1(in Chinese). 孙德福, 孙智程, 谷臻, 等. 金属热处理, 2023, 48(3), 1. 67 Liu N, Dong Z, Ma Z Q, et al. Journal of Alloys and Compounds, 2019, 744, 122. 68 Wang J S, Lai C, Liu W, et al. Materials Research Bulletin, 2013, 48(9), 3594. 69 Wahlberg S, Yar M A, Abuelnaga M O, et al. Journal of Materials Chemistry, 2012, 22(25), 12622. 70 Huang S M, Xu W Z, Luo L M, et al. The Chinese Journal of Nonferrous Metals, 2023, 33(2), 540(in Chinese). 黄胜猛, 徐旺之, 罗来马, 等. 中国有色金属学报, 2023, 33(2), 540. 71 Liu G, Zhang G J, Jiang F, et al. Nature Materials, 2013, 12(4), 344. 72 Wang K, Wang X P, Liu R, et al. Journal of Nuclear Materials, 2012, 431(1), 206. 73 Wang J. Nonferrous Metal Materials and Engineering, 2019, 40(4), 53(in Chinese). 王军. 有色金属材料与工程, 2019, 40(4), 53. 74 Shi H G, Qi Z W, Shang F J, et al. Ordnance Material Science and Engineering, 2006, 29(1), 29(in Chinese). 史洪刚, 齐志望, 尚福军, 等. 兵器材料科学与工程, 2006, 29(1), 29. 75 He C Y, Feng F, Wang J B, et al. International Journal of Refractory Metals and Hard Materials, 2022, 107, 105883. 76 Liu G R, Wang L, Wang G D, et al. Ordnance Material Science and Engineering, 2010, 33(5), 39(in Chinese). 刘桂荣, 王玲, 王广达, 等. 兵器材料科学与工程, 2010, 33(5), 39. 77 Wang F, Zheng X, Li L P, et al. China Tungsten Industry, 2014, 29(2), 37(in Chinese). 王峰, 郑欣, 李来平, 等. 中国钨业, 2014, 29(2), 37. 78 Zhang B H, Lin B T, Tang L L. China Molybdenum Industry, 2017, 41(5), 49(in Chinese). 张保红, 林冰涛, 唐亮亮. 中国钼业, 2017, 41(5), 49. 79 Su J M, Chen L Q, Wang S X, et al. Journal of Solid Rocket Technology, 2003, 26(3), 58(in Chinese). 苏君明, 陈林泉, 王书贤, 等. 固体火箭技术, 2003, 26(3), 58. 80 Shi K S. Carbon Techniques, 1987(3), 15(in Chinese). 史可顺. 碳素技术, 1987(3), 15. 81 Zhou L F, Li Y H. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms, 2023, 535, 247. 82 Huang X Y, Huang J, Cao Z Q, et al. Journal of Nuclear Materials, 2022, 570, 153981. 83 Zhang J P, Qu J L, Fu Q G, et al. Corrosion Science, 2019, 151, 87.