MXene对锌-空气电池双金属催化剂催化性能的影响

doi:10.11896/cldb.24020010

材料导报

2025, Vol. 39

Issue (2): 24020010-8 https://doi.org/10.11896/cldb.24020010

无机非金属及其复合材料

MXene对锌-空气电池双金属催化剂催化性能的影响

马润山¹, 王海燕², 张琦², 杨建新², 汤彬², 李睿², 李双寿², 林万明¹, 范晋平^1,*

1 太原理工大学材料科学与工程学院,太原 030024
2 清华大学基础工业训练中心,北京 100084

Effect of MXene on the Catalytic Performance of Bimetallic Catalysts for Zinc-Air Batteries

MA Runshan¹, WANG Haiyan², ZHANG Qi², YANG Jianxin², TANG Bin², LI Rui², LI Shuangshou², LIN Wanming¹, FAN Jinping^1,*

1 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2 Fundamental Industry Training Center, Tsinghua University, Beijing 100084, China

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摘要开发高氧还原和氧析出性能、稳定和低成本阴极催化剂是实现锌-空气电池产业化的关键。本工作以FeCl₃、NiCl₂、ZnCl₂和甲酰胺为原材料,采用水热合成-高温碳化-低温硫化的制备方法引入层状MXene材料,制备了FeNiSNC7∶3@MXene双金属复合材料作为锌-空气电池阴极催化剂,并分析了其物相组成、微观形貌、元素组成、电化学性能和电池性能。结果表明,使用这种催化材料制备的电池在电池测试中具有0.74 V的窄电压间隙,峰值功率密度达到179 mW/cm²,为二维材料与非贵金属催化剂结合提升锌-空气电池催化剂性能方面提供了新思路。

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	马润山
	王海燕
	张琦
	杨建新
	汤彬
	李睿
	李双寿
	林万明
	范晋平

关键词: MXene材料双金属复合材料催化剂水热合成高温碳化低温硫化

Abstract: The development of cathode catalysts with high oxygen reduction and oxygen evolution performance, stable and low-cost is the key to the industrialization of zinc-air batteries. In this work, FeNiSNC7∶3@MXene bimetallic composites were prepared as cathode catalysts for zinc-air batteries using FeCl₃, NiCl₂, ZnCl₂ and formamide as raw materials, and the phase composition, microscopic morphology, elemental composition, electrochemical properties and battery properties were analyzed by hydrothermal-synthesis, high-temperature, carbonization, low-temperature vulcanization. The battery prepared by this catalytic material has a narrow voltage gap of 0.74 V and a peak power density of 179 mW/cm² in the battery test, which provides a new idea for the combination of two-dimensional materials and non-noble metal catalysts to improve the performance of zinc-air battery catalysts.

Key words: MXene materials bimetallic composite catalysts hydrothermal synthesis high-temperature carbonization low-temperature vulcanization

出版日期: 2025-01-25 发布日期: 2025-01-21

ZTFLH:

TQ152

基金资助: 横向课题项目(20232001144);清华大学本科教育教学改革项目(ZY01_02);清华大学实验室创新基金

通讯作者: ^*范晋平,太原理工大学材料科学与工程学院讲师、硕士研究生导师。目前主要从事轻合金冶炼、耐热镁合金改性、非氰化浸金、电池等方面的研究工作。fanjinping@tyut.edu.cn

作者简介: 马润山,太原理工大学材料科学与工程学院硕士研究生,在范晋平讲师的指导下进行研究。目前主要研究领域为锌-空气电池。

引用本文:

马润山, 王海燕, 张琦, 杨建新, 汤彬, 李睿, 李双寿, 林万明, 范晋平. MXene对锌-空气电池双金属催化剂催化性能的影响[J]. 材料导报, 2025, 39(2): 24020010-8.
MA Runshan, WANG Haiyan, ZHANG Qi, YANG Jianxin, TANG Bin, LI Rui, LI Shuangshou, LIN Wanming, FAN Jinping. Effect of MXene on the Catalytic Performance of Bimetallic Catalysts for Zinc-Air Batteries. Materials Reports, 2025, 39(2): 24020010-8.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24020010 或 https://www.mater-rep.com/CN/Y2025/V39/I2/24020010

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