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材料导报  2026, Vol. 40 Issue (15): 25100172-12    https://doi.org/10.11896/cldb.25100172
  无机非金属及其复合材料 |
高效稳定全钒液流电池电解液研究进展
王熙俊1,†, 刘子阳2,3,†, 李林3, 李晨磊1, 韩爱娟2, 杨淼森3,*, 刘军枫2,*
1 国网冀北电力有限公司电力科学研究院(华北电力科学研究院有限责任公司),北京 100049
2 北京化工大学化学学院,北京 100029
3 东北电力大学化学工程学院,吉林 吉林 132001
Research Progress on Highly Efficient and Stable Vanadium Redox Flow Battery Electrolytes
WANG Xijun1,†, LIU Ziyang2,3,†, LI Lin3, LI Chenlei1, HAN Aijuan2, YANG Miaosen3,*, LIU Junfeng2,*
1 State Grid Jibei Electric Power Research Institute (North China Electric Power Research Institute Co., Ltd.), Beijing 100049, China
2 College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
3 School of Chemical Engineering, Northeast Electric Power University, Jilin 132001, Jilin, China
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摘要 全钒液流电池是一种兼具高安全性、长循环寿命和长时储能能力的大规模储能技术。本文聚焦全钒液流电池核心组件——电解液的关键技术指标,系统综述了其支撑电解质和两类常见添加剂(稳定剂、动力学增强剂)的研究进展。同时结合成本控制需求,对电解液的制备方法进行了介绍。本综述旨在为开发具有高钒离子浓度、宽工作温度范围、优异电化学活性且低成本的电解液提供理论支持与技术参考。
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王熙俊
刘子阳
李林
李晨磊
韩爱娟
杨淼森
刘军枫
关键词:  全钒液流电池  支撑电解质  稳定剂  动力学增强剂  电解液制备    
Abstract: The vanadium redox flow battery (VRFB) is a large-scale energy storage technology that boasts high safety, an extended cycle life, and robust long-duration energy storage capabilities. This review centers on the key technical indicators of the electrolyte— the core component of the VRFB — and delivers a systematic overview of research advances in its supporting electrolyte, as well as two common categories of additives:stabilizers and kinetic enhancers. Meanwhile, combined with the demand for cost control, the preparation methods of the electrolyte are introduced. The paper′s primary objective is to furnish theoretical support and technical references for the development of electrolytes that exhibit high vanadium ion concentration, a broad operating temperature range, superior electrochemical activity, and cost-effectiveness.
Key words:  vanadium redox flow battery    supporting electrolyte    stabilizer    kinetic enhancer    electrolyte preparation
出版日期:  2026-08-10      发布日期:  2026-08-31
ZTFLH:  TQ152  
基金资助: 国网冀北电力有限公司科技项目(52018K25000Q);国网冀北电科院2024—2025年科研项目(SGJBDK00HHJS2400197)
通讯作者:  * 杨淼森,博士,东北电力大学化学工程学院教授。长期从事无机功能材料的设计、制备及在电化学、环境保护、金属防腐等领域的应用研究。ymiaosen@163.com;刘军枫,博士,北京化工大学化学学院教授。长期从事无机功能纳米材料设计合成及其在能源催化领域的应用研究。ljf@mail.buct.edu.cn   
作者简介:  †共同第一作者.
王熙俊,硕士,国网冀北电力有限公司电力科学研究院(华北电力科学研究院有限责任公司)高级工程师,从事电化学储能及电网腐蚀与防护研究工作。
刘子阳,北京化工大学化学学院硕士研究生,在刘军枫教授指导下研究液流电池电极材料及电解质。
引用本文:    
王熙俊, 刘子阳, 李林, 李晨磊, 韩爱娟, 杨淼森, 刘军枫. 高效稳定全钒液流电池电解液研究进展[J]. 材料导报, 2026, 40(15): 25100172-12.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25100172  或          https://www.mater-rep.com/CN/Y2026/V40/I15/25100172
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