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材料导报  2026, Vol. 40 Issue (17): 25080139-7    https://doi.org/10.11896/cldb.25080139
  无机非金属及其复合材料 |
CaO激发剂对镍渣提铁尾渣-水泥胶凝体系活性的影响
冯琼1,2,*, 孙晓霞1,2, 乔宏霞1,2, 宋彦宁1,2, 魏超1,2
1 兰州理工大学土木与水利工程学院,兰州 730050
2 甘肃省先进土木工程材料工程研究中心,兰州 730050
Effect of CaO Activator on the Activity of Ferrous Extraction Tailing of Nickel
Slag-Cementitious System
FENG Qiong1,2,*, SUN Xiaoxia1,2, QIAO Hongxia1,2, SONG Yanning1,2, WEI Chao1,2
1 School of Civil and Hydraulic Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2 Gansu Province Engineering Research Center for Advanced Civil Engineering Materials, Lanzhou 730050, China
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摘要 针对镍渣提铁尾渣胶凝活性低制约资源化利用的瓶颈问题,通过掺入CaO激发剂调控镍渣提铁尾渣-水泥复合胶凝体系的水化进程,借助微观与宏观测试相结合的方法,系统揭示激发剂CaO对复合胶凝体系反应活性的激发机理,旨在提升镍渣提铁尾渣在水泥基材料中的利用率。试验结果表明:CaO的掺入对镍渣提铁尾渣-水泥复合体系的水化过程具有显著促进作用。在微观层面,CaO有效激发了C-S-H凝胶和钙矾石的形成,这些水化产物填充了材料的孔隙结构,使微观结构更加致密;在宏观上,CaO加速了早期水化反应,使得复合胶凝体系的力学性能显著提升,3 d和28 d抗压强度分别平均提高16.46%和15.41%。本工作可为镍渣提铁尾渣在水泥基材料中的高效利用提供理论依据和技术支撑。
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冯琼
孙晓霞
乔宏霞
宋彦宁
魏超
关键词:  镍渣提铁尾渣  水泥胶凝体系  CaO激发剂  反应活性    
Abstract: To address the bottleneck issue of low cementitious activity in ferrous extraction tailing of nickel slag that restricts their resource utilization, this work incorporates CaO as an activator to regulate the hydration process of a ferrous extraction tailing of nickel slag-cement composite cementitious system. By using a combination of micro- and macro-scale testing methods, the activation mechanism of CaO in enhancing the system’s reactivity was systematically investigated, with the aim of enhancing the utilization efficiency of ferrous extraction tailing of nickel slag in cement-based materials. The experimental results demonstrate that the addition of CaO significantly promotes the hydration process of the ferrous extraction tailing of nickel slag-cement composite system. At the micro-level, CaO effectively stimulates the formation of C-S-H gel and ettringite;these hydration products fill the pore structure of the material, resulting in a denser microstructure. In terms of macroscopic properties, CaO accelerates the early-age hydration, resulting in a remarkable improvement in the mechanical performance of the composite cementitious system, with the 3-day and 28-day compressive strength increasing by an average of 16.46% and 15.41%, respectively. This research provides a theoretical basis and technical support for the efficient utilization of iron-extracted nickel slag tailings in cement-based materials.
Key words:  ferrous extraction tailing of nickel slag    cementitious system    CaO activator    reactivity
出版日期:  2026-09-10      发布日期:  2026-09-22
ZTFLH:  TU521  
基金资助: 国家自然科学基金(52468036;U21A20150;52408277);甘肃省科技计划(25CXGA070;24JRRA213)
通讯作者:  *冯琼,博士,兰州理工大学土木与水利工程学院副教授、硕士研究生导师。目前主要从事特殊环境下混凝土材料耐久性、工业废弃物资源化利用、机制砂特种砂浆制备与性能方面的研究。fengqiong.1985@163.com   
引用本文:    
冯琼, 孙晓霞, 乔宏霞, 宋彦宁, 魏超. CaO激发剂对镍渣提铁尾渣-水泥胶凝体系活性的影响[J]. 材料导报, 2026, 40(17): 25080139-7.
FENG Qiong, SUN Xiaoxia, QIAO Hongxia, SONG Yanning, WEI Chao. Effect of CaO Activator on the Activity of Ferrous Extraction Tailing of Nickel
Slag-Cementitious System. Materials Reports, 2026, 40(17): 25080139-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25080139  或          https://www.mater-rep.com/CN/Y2026/V40/I17/25080139
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