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材料导报  2026, Vol. 40 Issue (13): 25080105-13    https://doi.org/10.11896/cldb.25080105
  金属与金属基复合材料 |
含能高熵合金能量释放特性的研究进展与展望
李治倩1, 黄佳豪2, 徐立志1, 杜成鑫1, 庞兆君1,*, 程春2,*, 杜忠华1
1 南京理工大学机械工程学院,南京 210094
2 宁波大学冲击与安全工程教育部重点实验室,浙江 宁波 315211
Research Progress and Prospects of Energy Release Characteristics of Energetic High-entropy Alloys
LI Zhiqian1, HUANG Jiahao2, XU Lizhi1, DU Chengxin1, PANG Zhaojun1,*, CHENG Chun2,*, DU Zhonghua1
1 School of Mechanical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
2 MOE Key Laboratory of Impact and Safety Engineering, Ningbo University, Ningbo 315211, Zhejiang, China
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摘要 含能高熵合金以其高强度和高能量密度在冲击诱导能量释放研究中引起了广泛关注,为武器装备毁伤能力的提高打开了一个全新的局面。现代武器的战斗部主要为惰性金属材料(如钢、钨、铜等),仅依靠动能侵彻对目标实施毁伤,毁伤效果单一且存在局限性。采用含能高熵合金来代替当前使用的战斗部材料,可通过化学能释放增强动能毁伤,从而显著提升综合毁伤效能。本文系统综述了含能高熵合金在断裂-点火-反应-释能过程中的点火诱发因素与能量释放规律,涵盖不同加载条件下的裂纹形成与碎裂行为、碎片燃烧反应机理以及试验与数值模拟方法的研究进展。最后,基于现有研究成果,指出了该领域亟待解决的重要问题与未来发展方向,为含能高熵合金在工程应用与武器系统设计中的深入研究提供参考。
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李治倩
黄佳豪
徐立志
杜成鑫
庞兆君
程春
杜忠华
关键词:  含能高熵合金  点火机理  能量释放  反应性结构材料    
Abstract: Energetic high-entropy alloys (EHEAs), distinguished by their high strength and elevated energy density, have attracted significant attention in studies of impact-induced energy release and are opening new possibilities for enhancing the destructive performance of modern weapon systems. Conventional warheads are predominantly composed of inert metallic materials such as steel, tungsten, or copper, whose lethality relies solely on kinetic penetration and is therefore inherently limited. Replacing these conventional materials with EHEAs enables the integration of chemical energy release with kinetic impact, markedly improving the overall damage efficiency. This review provides a systematic examination of the ignition-triggering mechanisms and energy-release characteristics of EHEAs throughout the fracture-ignition-reaction-release sequence. It summarizes current understanding of crack initiation and fragmentation under various loading conditions, the combustion and reaction behavior of fragments, and recent advances in experimental techniques and numerical simulation approaches. Finally, based on existing research progress, the review identifies key scientific challenges and future research directions, offering guidance for the further development of EHEAs in engineering applications and weapon-system design.
Key words:  energetic high-entropy alloy    ignition mechanism    energy release    reactive structural material
出版日期:  2026-07-10      发布日期:  2026-07-24
ZTFLH:  TB31  
基金资助: 微小型航天器快速设计与智能集群全国重点实验室(MS01240113); 国家自然科学基金(12102201)
通讯作者:  *庞兆君,博士,南京理工大学机械工程学院副研究员、博士研究生导师。目前主要从事先进毁伤与防护技术、航天器动力学与控制等方面的研究 pangzj@njust.edu.cn; 程春,宁波大学新域新质毁伤能力研究院院长,从事弹药与战斗部设计、空天特种功能载荷研制、爆炸与冲击动力学等相关研究 chengchun@nbu.edu.cn   
作者简介:  李治倩,南京理工大学机械工程学院博士研究生,在杜忠华研究员和庞兆君副研究员的指导下进行研究。目前主要研究方向为高熵合金动力学行为。
引用本文:    
李治倩, 黄佳豪, 徐立志, 杜成鑫, 庞兆君, 程春, 杜忠华. 含能高熵合金能量释放特性的研究进展与展望[J]. 材料导报, 2026, 40(13): 25080105-13.
LI Zhiqian, HUANG Jiahao, XU Lizhi, DU Chengxin, PANG Zhaojun, CHENG Chun, DU Zhonghua. Research Progress and Prospects of Energy Release Characteristics of Energetic High-entropy Alloys. Materials Reports, 2026, 40(13): 25080105-13.
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https://www.mater-rep.com/CN/10.11896/cldb.25080105  或          https://www.mater-rep.com/CN/Y2026/V40/I13/25080105
1 Cantor B, Chang I T H, Knight P, et al. Materials Science and Enginee-ring A, 2004, 375-377, 213.
2 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299.
3 Zhang T W, Jiao Z M, Wang Z H, et al. Scripta Materialia, 2017, 136, 15.
4 Hu M L, Song W D, Duan D B, et al. International Journal of Mechanical Sciences, 2020, 182, 105738.
5 Cui J, Chen S, Zhang Y, et al. Journal of Alloys and Compounds, 2024, 1002, 175311.
6 Yang Y F, Yang Y J, Dong Y, et al. Materials Research and Application, 2024,18(5), 736(in Chinese).
杨煜锋, 杨玉婧, 董勇, 等. 材料研究与应用, 2024, 18(5), 736.
7 Zhang B, Tang Y, Li S, et al. Entropy, 2021, 23(12), 1632.
8 Dirras G, Couque H, Lilensten L, et al. Materials Characterization, 2016, 111, 106.
9 Gludovatz B, Hohenwarter A, Catoor D, et al. Science, 2014, 345(6201), 1153.
10 Qiao J W, Ma S G, Huang E W, et al. Materials Science Forum, 2011, 688, 419.
11 Yang F, Guo Y F, Hu Y J, et al. Materials Research and Application, 2025, 19(6), 1053(in Chinese).
杨帆, 郭一帆, 胡永俊, 等. 材料研究与应用, 2025, 19(6), 1053.
12 Tsai C W, Tsai M H, Yeh J W, et al. Journal of Alloys and Compounds, 2010, 490(1-2), 160.
13 Senkov O N, Woodward C F. Materials Science and Engineering A, 2011, 529, 311.
14 Zhang Z, Zhang H, Tang Y, et al. Materials & Design, 2017, 133, 435.
15 Miracle D B, Senkov O N. Acta Materialia, 2017, 122, 448.
16 Ren H, Liu X, Ning J. Materials Science and Engineering A, 2016, 660, 205.
17 Luo P, Wang Z, Jiang C, et al. Materials & Design, 2015, 84, 72.
18 Aydelotte B, Braithwaite C H, Thadhani N N. Journal of Physics: Conference Series, 2014, 500(13), 132001.
19 Wang B, Wang C, Liu B, et al. Entropy, 2019, 21(12), 1154.
20 Gwalani B, Wang T, Jagetia A, et al. Entropy, 2020, 22(4), 431.
21 Cao C M, Tong W, Bukhari S H, et al. Materials Science and Enginee-ring A, 2019, 759, 648.
22 Wang X, Wang L, Li T, et al. Materials Science and Engineering A, 2022, 856, 143964.
23 Xia S, Zhang Y. Materials Science and Engineering A, 2018, 733, 408.
24 Li Z, Zhao S, Diao H, et al. Scientific Reports, 2017, 7(1), 42742.
25 Ding Q, Fu X, Chen D, et al. Materials Today, 2019, 25, 21.
26 Xu L, Jia Y, Ma Y, et al. Journal of Materials Science & Technology, 2025, 209, 240.
27 Zhou S, Xiao Y, Zhang J, et al. Heliyon, 2025, 11(4), e42513.
28 Choi W M, Jo Y H, Sohn S S, et al. npj Computational Materials, 2018, 4(1), 1.
29 Wang L Y, Jiang J W, Li M, et al. Defence Technology, 2021, 17(2), 467.
30 Shang C, Ren T, Zhang Q, et al. Materials & Design, 2022, 216, 110564.
31 Zatsarna O, Kotrechko S, Filatov O, et al. Fracture and Structural Integrity, 2024, 18(68), 410.
32 Chen J, Chen C, Guo K, et al. Journal of Alloys and Compounds, 2023, 933, 167798.
33 Freund F T, Takeuchi A, Lau B W S. Physics and Chemistry of the Earth Parts A/B/C, 2006, 31(4-9), 389.
34 Enomoto Y, Hashimoto H. Nature, 1990, 346(6285), 641.
35 Chen C, Guo Y Y, Gao R K, et al. Materials Science and Technology, 2022, 38(15), 1230.
36 Guo K, Zhang Y, Chen C, et al. Intermetallics, 2024, 170, 108312.
37 Chen H H, Zhang X F, Xiong W, et al. Chinese Journal of Theoretical and Applied Mechanics, 2020, 52(5), 1443 (in Chinese).
陈海华, 张先锋, 熊玮, 等. 力学学报, 2020, 52(5), 1443.
38 Guo Y, Liu R, Ran C, et al. Journal of Materials Research and Technology, 2024, 28, 2819.
39 Hou X W, Xiong W, Chen H H, et al. Chinese Journal of Theoretical and Applied Mechanics, 2021, 53(9), 2528 (in Chinese).
侯先苇, 熊玮, 陈海华, 等. 力学学报, 2021, 53(9), 2528.
40 Richard G A, Samuel S W. In: Energetic Materials: Performance and Safety. Karlsruhe(DE), 2005, pp. 180.
41 Ames R. In: 43rd AIAA Aerospace Sciences Meeting and Exhibit. Reno, Nevada, 2005, pp.
42 Ames R. MRS Proceedings, 2005, 896, 0896.
43 Chen X, Du C X, Cheng C, et al. Ordnance Material Science and Engineering, 2018, 41(6), 44 (in Chinese).
陈曦, 杜成鑫, 程春, 等. 兵器材料科学与工程, 2018, 41(6), 44.
44 Wang C T, He Y, Ji C, et al. Intermetallics, 2018, 93, 383.
45 Ren K, Liu H, Chen R, et al. Materials Science and Engineering A, 2021, 827, 142074.
46 Ji W, Zou Q, Yin X, et al. Journal of Alloys and Compounds, 2024, 984, 173881.
47 Vyazovkin S, Burnham A K, Criado J M, et al. Thermochimica Acta, 2011, 520(1-2), 1.
48 Jing F Q. Introduction to experimental equation of state, Science Press, China, 1986, pp. 25 (in Chinese).
经福谦. 实验物态方程导引, 科学出版社, 1986, pp. 25.
49 Tan H. Experimental shock wave physics, Defence Industry Press, China, 2007(in Chinese).
谭华. 实验冲击波物理导引, 国防工业出版社, 2007.
50 Si S, He C, Liu S, et al. Materials & Design, 2022, 220, 110846.
51 Sheng D, Li T, Zhang W, et al. Journal of Applied Physics, 2025, 137(8), 085904.
52 Lan J, Liu J, Zhang S, et al. Materials & Design, 2020, 186, 108325.
53 Wainwright E R, Schmauss T A, Vummidi Lakshman S, et al. Combustion and Flame, 2018, 196, 487.
54 Wang H, Chao Q, Cui X Y, et al. Materials Today, 2022, 61, 11.
55 Lloyd R. Conventional warhead systems physics and engineering design, America Institute of Aeronautics and Astronautics, Reston, VA 20191-4333, USA, 1998, pp.
56 Sui M, Wang B, Guo X, et al. Journal of Alloys and Compounds, 2024, 1001, 175137.
57 Mott N F. A theory of the fragmentation of shells and bombs, Springer Berlin Heidelberg, Berlin, Heidelberg, 2006, pp. 243.
58 Mott N F. Proceedings of the Royal Society of London Series A: Mathema-tical and Physical Sciences, 1947, 189(1018), 300.
59 Grady D E, Kipp M E. Journal of Applied Physics, 1985, 58(3), 1210.
60 Grady D E, Winfree N A. International Journal of Impact Engineering, 2001, 26(1-10), 249.
61 Grady D E. International Journal of Fracture, 2010, 163(1-2), 85.
62 Grady D E. International Journal of Impact Engineering, 2008, 35(12), 1557.
63 Meng J, Shen B, Wang J, et al. Intermetallics, 2023, 162, 108036.
64 Ma Y, Zhou L, Zhang K, et al. Materials, 2022, 15(20), 7332.
65 Liu S, Liu X, Xie R, et al. Journal of Alloys and Compounds, 2023, 935, 168022.
66 Meng J Y, He J Z, Zhang B, et al. Defence Technology, 2024, 31, 343.
67 Chen C, Gao R, Guo K, et al. International Communications in Heat and Mass Transfer, 2022, 133, 105958.
68 Tang E, Sun Z, Han Y, et al. Results in Physics, 2021, 31, 105019.
69 He Z, Tang E, Ou X, et al. Journal of Materials Research and Technology, 2020, 9(6), 14528.
70 Chen C, Tang E, Zhu W, et al. Experimental Thermal and Fluid Science, 2020, 116, 110132.
71 Tang E L, Xu M Y, Zhang Q M, et al. Chinese Journal of Solid Mechanics, 2016, 37(2), 152 (in Chinese).
唐恩凌, 徐名扬, 张庆明, 等. 固体力学学报, 2016, 37(2), 152.
72 Duan C Z, Qin S W. Heat Treat Metals, 2017, 42(2), 34 (in Chinese).
段春争, 秦泗伟. 金属热处理, 2017, 42(2), 34.
73 Wang D W, Ren K R, Jiang Z R, et al. Explosion and Shock Waves, 2021, 41(3), 031408(in Chinese).
汪德武, 任柯融, 江增荣, 等. 爆炸与冲击, 2021, 41(3), 031408.
74 Wang Y, Wang J, Lei M, et al. Acta Mechanica Sinica, 2022, 38(11), 122116.
75 Yuan K, Yao X, Yu Y, et al. International Journal of Mechanical Sciences, 2023, 246, 108148.
76 Choi W M, Jo Y H, Sohn S S, et al. npj Computational Materials, 2018, 4(1), 1.
77 Lu G, Li P, Liu Z, et al. Materials, 2022, 15(15), 5356.
78 Xiong W, Zhang X, Zheng L, et al. Journal of Materials Science, 2019, 54(8), 6651.
79 Zhao D, Fang H, Jin T, et al. Materials Research Express, 2019, 6(10), 1065h3.
80 Cao J, Chen C L, Ma K, et al. Chinese Journal of Energetic Materials(Hanneng Cailiao), 2023, 31(8), 786 (in Chinese).
曹进, 陈春林, 马坤, 等. 含能材料, 2023, 31(8), 786.
81 Wang H F, Xie J W, Ge C, et al. Defence Technology, 2021, 17(2), 599.
82 Ren S, Zhang Q, Wu Q, et al. International Journal of Impact Engineering, 2019, 130, 124.
83 Geng H, Wang J, Xiong W, et al. Journal of Materials Research and Technology, 2025, 35, 7393.
84 Zhang X F, Shi A S, Qiao L, et al. Journal of Applied Physics, 2013, 113(8), 083508.
85 Majeed M, Chen J, Jin J F, et al. International Journal of Mechanical Sciences, 2025, 301, 110408.
86 Morrison K R, Cherukara M J, Guda V K, et al. Acta Materialia, 2014, 69, 30.
87 Pyzer E O, Pitera J W, Staar P W J, et al. npj Computational Materials, 2022, 8(1), 84.
88 Liu S, Feng G, Xiao L, et al. International Journal of Mechanical Sciences, 2023, 239, 107859.
89 Dai F Z, Sun Y, Wen B, et al. Journal of Materials Science & Technology, 2021, 72, 8.
90 Dai F Z, Wen B, Sun Y, et al. Journal of Materials Science & Technology, 2020, 43, 168.
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