Study on Microstructure Evolution of TC18 Titanium Alloy During Continuous Cooling Process
ZHAI Jiangbo1,2, TU Junzhe1, QIN Weidong2, JI Shengli2, XU Jianwei1, ZENG Weidong1,*
1 School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China 2 Shandong Hongshan Aviation Forging Co., Ltd., Yantai 265713, Shandong, China
Abstract: Controlling the morphological characteristics of α-phase precipitation following β annealing is the pivotal factor governing the attainment of superior damage tolerance performance. This work presents a systematic investigation of the precipitation behavior and associated microstructural evolution of α-phase in TC18 titanium alloy during continuous cooling processes. Comprehensive experimental characterization demonstrates that reduced cooling rates facilitate both enhanced α-phase precipitation and pronounced coarsening of α platelets. Notably, grain boundary α (αGB) exhibits preferential precipitation, followed by Widmansttten α laths (αW), which manifest through two distinct formation pathways:extension from αGB into adjacent grain interiors (αWGB) and autonomous nucleation within β grains (αWI). Crystallographic orientation analysis reveals that αGB preferentially maintains the Burgers orientation relationship (BOR) with a single adjacent β grain, while unique variants simultaneously satisfying the BOR with both neighboring grains emerge when adjacent β grains share (110) crystallographic planes. Subsequent growth behavior shows that αGB extends exclusively into BOR-compliant β grains to form αWGB, preserving orientation continuity with the parent αGB. In addition, intra-granular αWI rigorously adheres to BOR principles, exhibiting the complete spectrum of 12 orientation variants. Therefore, this work statistically analyzes the influence of cooling rate on the variant types of intragranular αWI. At a cooling rate of 0.3 ℃·s-1, the (011)β//(0001)α, [111]β//[1120]α variant dominates precipitation, whereas below 0.1 ℃·s-1, preferential growth occurs for both (101)β//(0001)α, [111]β//[1120]α and (110)β//(0001)α, [111]β//[1120]α variants. These findings provide a parameter basis for optimizing the TC18 alloy heat treatment processes to regulate α-phase distribution.
1 Sun Z C,Yin L J. Journal of Alloys and Compounds,2022,901,163622. 2 Sun Y X,Liu Y Y,Zhang J Y,et al. Chinese Journal of Rare Metals,2019,43(7),699 (in Chinese). 孙宇幸, 刘莹莹, 张君彦, 等. 稀有金属, 2019, 43(7), 699. 3 Wei Q C, Lan Z Q, Li M J, et al. Chinese Journal of Rare Metals, 2025, 49(4), 457 (in Chinese). 魏启超, 拦宗强, 李明佳, 等. 稀有金属, 2025, 49(4), 457. 4 Byres N E, Fonseca J Q, Daniel C S, et al. Acta Materialia, 2021, 221, 117362. 5 Xu J W, Ji X Y, Tian S L, et al. Chinese Journal of Rare Metals, 2022, 48(3), 317 (in Chinese). 徐建伟, 纪晓宇, 田胜利, 等. 稀有金属, 2022, 48(3), 317. 6 Shi X H, Zeng W D, Xue S K, et al. Journal of Alloys and Compounds, 2015, 631, 340. 7 Gao P, Zhu Y X, Zhu J C, et al. International Journal of Fatigue, 2024, 179, 108074. 8 Sun Z C, Guo S S, Yang H. Acta Materialia, 2013, 61, 2057. 9 Stanford N, Bate P S. Acta Materialia, 2004, 52(17), 5215. 10 Zhang Y, Xin R L, Huang X X, et al. Journal of Chinese Electron Microscopy Society, 2025, 44(3), 271 (in Chinese). 张宇, 辛仁龙, 黄晓旭, 等. 电子显微学报, 2025, 44(3), 271. 11 Zhang Y, Xin, R L, Guo B Q, et al. Materials Characterization, 2021, 177, 111162. 12 Dang W, Xue X Y, Kou H C, et al. Journal of Aeronautical Materials, 2010, 30(3), 19 (in Chinese). 党薇, 薛祥义, 寇宏超, 等. 航空材料学报, 2010, 30(3), 19. 13 Salib M, Teixeira J, Germain L, et al. Acta Materialia, 2013, 61, 3758. 14 Tang B, Kou H C, Zhang X, et al. Progress in Natural Science:Materials International, 2016, 26, 385. 15 Wu C, Zhao Y Q, Huang S X, et al. Journal of Alloys and Compounds, 2020, 841, 155728. 16 Wan M P, Wen X, Ma R, et al. Rare Metal Materials and Engineering, 2019, 48(1), 0097. 17 Cai X, Lei M, Wan M P, et al. Chinese Journal of Rare Metals, 2019, 43(12), 1291 (in Chinese). 蔡馨, 雷旻, 万明攀, 等. 稀有金属, 2019, 43(12), 1291. 18 Qi M, Wang Q, Ma Y J, et al. Acta Metallurgica Sinica, 2025, 61(2), 265 (in Chinese). 齐敏, 王倩, 马英杰, 等. 金属学报, 2025, 61(2), 265. 19 Ji X Y, Xu J W, Zhang Y, et al. Rare Metal Materials and Engineering, 2025, 54(3), 665 (in Chinese). 纪晓宇, 徐建伟, 张宇, 等. 稀有金属材料与工程, 2025, 54(3), 665. 20 Hao M Y, Wang D, Wang Y L, et al. Acta Materialia, 2024, 269, 119810. 21 Ou M G, Xia Q F, Song H C, et al. Rare Metal Materials and Engineering, 2019, 48(2), 638 (in Chinese). 欧梅桂, 夏麒帆, 宋洪超, 等. 稀有金属材料与工程, 2019, 48(2), 638. 22 Zhao Z B, Wang Q J, Hu Q M, et al. Acta Materialia, 2017, 126, 372.