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材料导报  2026, Vol. 40 Issue (15): 25080005-14    https://doi.org/10.11896/cldb.25080005
  无机非金属及其复合材料 |
BiFeO3-SrTiO3陶瓷材料的研究进展
柳豪, 张剑, 杨晨, 杨鑫*
云南师范大学,能源与环境科学学院,可再生能源材料先进技术与制备教育部重点实验室,云南省教育厅新型光伏材料与薄膜太阳电池重点实验室,昆明 650500
Research Progress of BiFeO3-SrTiO3 Ceramic Materials
LIU Hao, ZHANG Jian, YANG Chen, YANG Xin*
Key Laboratory of New Photovoltaic Materials and Thin Film Solar Cells, Yunnan Provincial Department of Education, MOE Key Laboratory of Advanced Technology and Preparation of Renewable Energy Materials, College of Energy and Environmental Sciences, Yunnan Normal University, Kunming 650500, China
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摘要 BiFeO3-SrTiO3(BFO-STO)陶瓷因其无铅特性、高温稳定性和多铁耦合效应,有望在高温压电、能量储能等领域取代铅基陶瓷材料。本文系统综述其研究进展:通过调控准同型相界(MPB)提升陶瓷极化强度与储能性能;探讨不同陶瓷制备方法的优化,包括固相反应法、溶胶-凝胶、放电等离子烧结(SPS)及两步烧结等工艺调控陶瓷的相结构、晶粒尺寸及性能;进行A/B位离子掺杂和三元氧化物掺杂实现微观结构、晶体结构和缺陷调控,提高陶瓷的压电性能、介电性能、多铁性能及储能稳定性;揭示晶体结构、微观结构和陶瓷性能的相互作用关系;探索其在能量储存器、高温传感器及磁电耦合器件等实际应用中的可能性。
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柳豪
张剑
杨晨
杨鑫
关键词:  BiFeO3-SrTiO3(BFO-STO)陶瓷  无铅陶瓷  固相反应法  准同型相界调控  掺杂改性    
Abstract: BiFeO3-SrTiO3(BFO-STO) ceramics have attracted considerable attention as lead-free functional materials due to their high-temperature stability and intrinsic multiferroic coupling. These characteristics make them promising candidates for high-temperature piezoelectric devices and energy-storage applications. This review systematically summarizes recent advances in BFO-STO ceramics:modulating the morphotropic phase boundary (MPB) to improve polarization and energy storage performance;optimizing ceramic preparation methods, including the solid-state reaction method, sol-gel, spark plasma sintering (SPS), and two-step sintering process strategies to regulate the phase structure, grain size, and performance of ceramics;employing A/B site and ternary oxide doping to adjust the microstructure, crystal structure, and defects, thereby improving piezoelectric, dielectric, multiferroic performance, and energy-storage stability;elucidating the interplay between crystal structure, microstructure, and macroscopic functional responses;and exploring potential applications in energy storage, high-temperature sensors, and magnetoelectric devices.
Key words:  BiFeO3-SrTiO3(BFO-STO) ceramics    lead-free ceramics    solid-state reaction method    morphotropic phase boundary regulation    doping modification
出版日期:  2026-08-10      发布日期:  2026-08-31
ZTFLH:  TQ129  
基金资助: 云南省“兴滇英才支持计划”青年人才专项(20225132);云南省基础研究计划面上项目(202001AT070086);云南师范大学博士科研启动项目(2021ZB019)
通讯作者:  * 杨鑫,博士,云南师范大学副教授、硕士研究生导师。目前主要从事多元氧化物纳米材料、光催化材料等方面的研究。yangxin@ynnu.edu.cn   
作者简介:  柳豪,云南师范大学能源与环境科学学院硕士研究生,在杨鑫副教授的指导下研究铁酸铋-钛酸锶复合材料。
引用本文:    
柳豪, 张剑, 杨晨, 杨鑫. BiFeO3-SrTiO3陶瓷材料的研究进展[J]. 材料导报, 2026, 40(15): 25080005-14.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25080005  或          https://www.mater-rep.com/CN/Y2026/V40/I15/25080005
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