Please wait a minute...
材料导报  2026, Vol. 40 Issue (17): 25070233-10    https://doi.org/10.11896/cldb.25070233
  无机非金属及其复合材料 |
玄武岩纤维改性沥青与集料界面黏附性评价及微观机理研究
谢祥兵1,*, 张永坤1, 侯博研1, 邵景干2,3, 王乾4, 邢芳5, 李广慧5,6
1 郑州航空工业管理学院土木与环境学院,郑州 450046
2 河南交通职业技术学院公路学院,郑州 451460
3 绿色高性能材料交通运输行业研发中心,郑州 450000
4 西安建筑科技大学土木工程学院, 西安 710055
5 河南水利与环境职业学院水利工程学院,郑州 450008
6 新乡学院土木工程与建筑学院,河南 新乡 453003
Evaluation of Basalt Fiber Modified Asphalt-Aggregate Interfacial Adhesion and
Microscopic Mechanism Study
XIE Xiangbing1,*, ZHANG Yongkun1, HOU Boyan1, SHAO Jinggan2,3, WANG Qian4, XING Fang5, LI Guanghui5,6
1 School of Civil Engineering and Environment, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
2 School of Highway Engineering, Henan College of Transportation, Zhengzhou 451460, China
3 R & D Center for Green High-performance Material in the Transportation Industry, Zhengzhou 450000, China
4 College of Civil Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
5 School of Hydraulic Engineering, Henan Vocational College of Water Conservancy and Environment, Zhengzhou 450008, China
6 School of Civil Engineering and Architecture, Xinxiang University, Xinxiang 453003, Henan, China
下载:  全 文 ( PDF ) ( 41233KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 玄武岩纤维(BF)改性沥青的黏聚性及其与集料之间的黏附性是影响沥青混合料耐久性的关键因素。本工作采用分子动力学(MD)模拟方法,构建了SBS改性沥青、BF-SBS改性沥青、BFKH550(硅烷偶联剂改性纤维)-SBS改性沥青与氧化物集料的界面模型,计算了沥青与集料之间的径向分布函数(RDF)和黏附功,并通过接触角试验计算纤维与沥青之间的黏附力,从分子尺度探究了不同温度下BF-SBS改性沥青和BFKH550-SBS改性沥青与氧化物集料层之间的聚集特性和黏附性能。研究结果表明:在沥青体系中,SBS与BFKH550缠绕,形成韧性界面层,有效抑制了纤维剥离现象;BFKH550凭借更高的表面能,实现了与沥青更牢固、更有效的界面结合。三种改性沥青与不同氧化物集料界面之间的黏附强度排序为CaO>Al2O3>SiO2;常温下BFKH550-SBS改性沥青与CaO集料层之间的黏附功最高为221.67 mJ/m2,相比SBS改性沥青和BF-SBS改性沥青分别提高了31%和18%,表明碱性氧化物与沥青之间有更强的黏附作用。研发的高性能玄武岩纤维改性技术为提升沥青路面耐久性提供了理论依据,为公路工程绿色建设提供技术支持。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
谢祥兵
张永坤
侯博研
邵景干
王乾
邢芳
李广慧
关键词:  SBS改性沥青  硅烷偶联剂  玄武岩纤维  集料氧化物  黏附性能    
Abstract: The cohesion of basalt fiber (BF) modified asphalt and its adhesion to aggregates are critical factors determining the durability of asphalt mixtures. This work employed molecular dynamics (MD) simulations to construct interfacial models between oxide aggregates and three asphalt systems:SBS-modified, BF-SBS-modified, and BFKH550(silane coupling agent modified fiber)-SBS-modified asphalts. Radial distribution functions (RDF) and adhesion work were calculated to evaluate molecular interactions, while contact angle tests were calculated to validate fiber-asphalt adhesion force. The aggregation characteristics and adhesion properties between BF-SBS and BFKH550-SBS modified asphalts, along with their adhesion to oxide aggregate layers and oxide aggregate layers were investigated at the molecular scale under different temperature conditions. The test results demonstrate that SBS and BFKH550 molecules intertwine within the asphalt matrix, forming a ductile interfacial layer that effectively suppresses fiber debonding. Due to its higher surface energy, BFKH550 demonstrates stronger and more stable interfacial bonding with asphalt. The adhesion strength between the three modified asphalts and oxide aggregates follows the order:CaO>Al2O3>SiO2. At notrmal temperature, BFKH550-SBS-modified asphalt exhibits the highest adhesion work with CaO aggregate (221.67 mJ/m2), representing improvements of 31% and 18% compared to SBS-modified and BF-SBS-modified asphalts, respectively. This indicates that alkaline oxides demonstrate superior adhesion with modified asphalt. The high-performance basalt fiber modification technology developed in this work provides both theoretical foundation for enhancing asphalt pavement durability and technical support for sustainable highway construction.
Key words:  SBS modified asphalt    silane coupling agent    basalt fiber    aggregate oxide    adhesive property
出版日期:  2026-09-10      发布日期:  2026-09-22
ZTFLH:  TU535  
基金资助: 河南省自然科学基金面上项目(242300421257);河南省交通运输科技计划(2016-2-3);郑州航空工业管理学院研究生创新计划基金(2025CX171;2025CX184);河南省科技攻关项目(262102230169;262102240027;252102240026)
通讯作者:  *谢祥兵,郑州航空工业管理学院土木与环境学院副教授、硕士研究生导师。目前主要围绕特殊环境下路面长期性能演化与健康服役开展研究,具体包括新型路面材料与结构、路域环境感知与智能检测。xiexiangbing.good@163.com   
引用本文:    
谢祥兵, 张永坤, 侯博研, 邵景干, 王乾, 邢芳, 李广慧. 玄武岩纤维改性沥青与集料界面黏附性评价及微观机理研究[J]. 材料导报, 2026, 40(17): 25070233-10.
XIE Xiangbing, ZHANG Yongkun, HOU Boyan, SHAO Jinggan, WANG Qian, XING Fang, LI Guanghui. Evaluation of Basalt Fiber Modified Asphalt-Aggregate Interfacial Adhesion and
Microscopic Mechanism Study. Materials Reports, 2026, 40(17): 25070233-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25070233  或          https://www.mater-rep.com/CN/Y2026/V40/I17/25070233
1 Sultan S A, Guo Z Y. International Journal of Transportation Science and Technology, 2016, 5(3), 200.
2 Guo Y, Hou K, Jia Y S, et al. Automation in Construction, 2021, 128, 103742.
3 Guo Y F, Piergiorgio T, Cesare S. Construction and Building Materials, 2023, 390, 131754.
4 Wang Z H, Zhang Y, Zhang C, et al. Journal of Army Engineering University of PLA, 2026, 5(1), 47(in Chinese).
王志航, 张悦, 张超, 等. 陆军工程大学学报, 2026, 5(1), 47.
5 Wang X, Xie J Z, Zhou J Y, et al. Journal of Army Engineering University of PLA, 2026, 5(2), 14(in Chinese).
汪昕, 解佳展, 周竞洋, 等. 陆军工程大学学报, 2026, 5(2), 14.
6 Zhang H M, Chen L. Journal of Army Engineering University of PLA, 2026, 5(2), 31(in Chinese).
张恒铭, 陈璐. 陆军工程大学学报, 2026, 5(2), 31.
7 Chen L L, Li W, Chen M H, et al. Case Studies in Construction Materials, 2023, 19, e02442.
8 Sun S F, Li P L, Su J F, et al. Construction and Building Materials, 2021, 294, 123581.
9 Cui S, BlackmanR B, Kinloch J A, et al. International Journal of Adhesion & Adhesives, 2014, 54, 100.
10 Wang H, Chen G, Kang H Y, et al. Construction and Building Materials, 2024, 457, 139317.
11 Xu G, Wang H. Computational Materials Science, 2016, 112, 161.
12 Jagadeesh P, Rangappa M S, Siengchin S. Construction and Building Materials, 2024, 436, 136834.
13 Pradeep V, Kumar P, Reddy I R. Results in Engineering, 2024, 23, 102722.
14 Wang W S, Cheng Y C, Tan G J. Materials, 2018, 11(8), 1311.
15 Xu J, Liu M H, Kang A H, et al. Construction and Building Materials, 2024, 438, 137234.
16 Ni S W, Luo W B, Wang Z C. Construction and Building Materials, 2024, 448, 138290.
17 Xiong C F, Gao M, Huang H, et al. Applied Surface Science Advances, 2024, 21, 100594.
18 Zheng H P, Wang Z Y, Wang Y Y, et al. Surface & Coatings Technology, 2024, 487, 131023.
19 Zhang S C, Zhong T H, Xu Q B, et al. Construction and Building Materials, 2022, 323, 126563.
20 Cheng X, Liu J X, Han C, et al. Construction and Building Materials, 2023, 366, 130182.
21 Yang C C, Liu L, Liu Z H, et al. Case Studies in Construction Materials, 2023, 19, e02493.
22 Ge M C, Li X D, Han F, et al. Polymers, 2025, 17(1), 61.
23 Cheng X, Liu J X, Han C, et al. Construction and Building Materials, 2023, 366, 130182.
24 Wang F Y, Zou G Y, Xu L, et al. Construction and Building Materials, 2024, 421, 135643.
25 Zhang S C, Zhong T H Y, Xu Q B, et al. Polymer Materials Science and Engineering, 2022, 38(2), 88(in Chinese).
张圣昌, 钟天皓月, 许启彬, 等. 高分子材料科学与工程, 2022, 38(2), 88.
26 Qu X, Liu Q, Guo M, et al. Construction and Building Materials, 2018, 187, 718.
27 Zhu X Y, Du Z, Ling H W, et al. International Journal of Pavement Engineering, 2018, 25(6), 1029.
28 Wang P, Dong Z J, Tan Y Q, et al. Energy & Fuels, 2015, 29, 112.
29 Tang Y J, Fu Z, Raos G, et al. Surfaces and Interfaces, 2024, 44, 103706.
30 Amorosi A, ROampello S. Géotechniquee, 2007, 57(2), 153.
31 Yao H, Liu J F, Xu M, et al. Advances in Colloid and Interface Science, 2022, 229, 102565.
32 Rosenholm B J. Advances in Colloid and Interface Science, 2016, 234, 89.
33 Ren S S, Poot M, Liu X Y, et al. Materials & Design, 2025, 252, 113791.
[1] 刘春岳, 张启帆, 张建伟, 张蕾, 刘嘉麒, 王淇芃. 玄武岩熔融出丝漏嘴长度对纤维成型的影响[J]. 材料导报, 2026, 40(8): 25040180-7.
[2] 张泽明, 黄存盛, 党东营, 张德伟, 汪传生. 羧甲基纤维素钠改性的BF/EPDM复合材料的性能研究[J]. 材料导报, 2026, 40(7): 24120160-6.
[3] 李克亮, 段龙航, 杜建, 李伟华, 卢洪波, 鲁幼勤, 赵军. 地下污水管道有机改性地质聚合物耐腐蚀涂层研究[J]. 材料导报, 2026, 40(6): 25030250-8.
[4] 李亚莎, 董恒, 周朝威, 吴雕, 王福达, 王桂斌. 不同硅烷偶联剂修饰CNTs改性硅橡胶的分子动力学模拟[J]. 材料导报, 2026, 40(6): 25020105-7.
[5] 高英力, 黄国泰, 李昀博, 朱俊材. 偶联表面处理咖啡渣粉改性沥青的高温流变特性及储存稳定性[J]. 材料导报, 2026, 40(5): 25020128-8.
[6] 高源, 樊恒辉, 刘国冲, 倪闻博, 任冠洲, 孟敏强, 庞帅. 废弃禽畜骨提取物协同纤维固砂的力学特性试验研究[J]. 材料导报, 2026, 40(17): 25070101-7.
[7] 张蓉蓉, 李岩, 蔡凤杰, 赵云峰, 冯振刚. 基于结构重组的老化SBS改性沥青再生行为研究进展[J]. 材料导报, 2026, 40(16): 25090045-13.
[8] 郭向柯, 李乐臣, 李克亮, 周新显, 宋灿, 吴庆亮, 李伟华. 海洋环境下裸露和嵌入海水海砂混凝土中BFRP筋的耐久性[J]. 材料导报, 2026, 40(16): 25060089-6.
[9] 黄敦文, 刘源, 夏立鹏, 肖羚彰, 彭晖. 碱激发材料的液相碱度对玄武岩纤维性能的影响[J]. 材料导报, 2026, 40(15): 25070057-7.
[10] 李亚莎, 田泽, 王璐敏, 庞梦昊, 曾跃凯, 赵光辉. 表面接枝KH550 的石墨烯改性聚二甲基硅氧烷热力学性能的分子动力学模拟[J]. 材料导报, 2025, 39(2): 24010155-6.
[11] 田小革, 李光耀, 高凯, 吴清浩, 黄思丹, 谢振. 硅烷偶联剂接枝活化废胶粉与沥青相容性及微观机理研究[J]. 材料导报, 2025, 39(18): 24070126-10.
[12] 涂义亮, 任思雨, 赵林, 凌玲, 柴贺军. 玄武岩纤维-粉煤灰提升水泥土抗剪性能试验研究[J]. 材料导报, 2025, 39(16): 24050216-8.
[13] 郭寅川, 樊鹏龙, 申爱琴, 戴晓倩, 姚超, 杨雪瑞, 李震南. 轮载-动水耦合作用下玄武岩纤维路面混凝土性能衰减及机理研究[J]. 材料导报, 2025, 39(13): 24010002-8.
[14] 杨程程, 柳力, 刘朝晖, 黄优, 刘磊鑫. 基于分子动力学的偶联剂接枝改性玄武岩纤维与沥青粘附特性研究[J]. 材料导报, 2024, 38(6): 22110027-7.
[15] 苗世坦, 刘嘉麒, 郭玲, 刘忠, 丁宝明, 张蕾. 高温处理对玄武岩纤维抗拉强度和结构的影响[J]. 材料导报, 2024, 38(11): 22090168-6.
[1] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4] Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5] Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6] Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7] Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8] Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9] Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10] Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed