Please wait a minute...
材料导报  2026, Vol. 40 Issue (12): 25070137-11    https://doi.org/10.11896/cldb.25070137
  光热调控超材料的应用与创新 |
电致变红外发射率器件研究进展
张虎林1, 王兰喜1, 陈明俊2, 陈曦3, 张翔2, 王晓毅1, 何延春1, 倪壮1, 李坤1, 杨淼1, 王虎1,*, 李垚2,*
1 兰州空间技术物理研究所真空技术与物理国防科技重点实验室,兰州 730000
2 哈尔滨工业大学复合材料与结构研究所,哈尔滨 150006
3 电子科技大学长三角研究院,江苏 湖州 313000
Research Progress of Electrically Tunable Infrared Emissivity Devices
ZHANG Hulin1, WANG Lanxi1, CHEN Mingjun2, CHEN Xi3, ZHANG Xiang2, WANG Xiaoyi1, HE Yanchun1, NI Zhuang1, LI Kun1, YANG Miao1, WANG Hu1,*, LI Yao2,*
1 Science and Technology on Vacuum Technology and Physics Laboratory, Lanzhou Institute of Physics, Lanzhou 730000, China
2 Center for Composite Materials and Structure, Harbin Institute of Technology, Harbin 150006, China
3 Yangtze River Delta Research Institute, University of Electronic Science and Technology of China, Huzhou 313000, Jiangsu, China
下载:  全 文 ( PDF ) ( 52892KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 电致变红外发射率器件(e-TIED)通过电场/电流动态调控红外辐射特性,在智能热管理、隐身伪装及建筑节能等领域展现出重要的应用价值。本文从材料本征特性调控与光学结构设计双维度系统评述了电致红外发射率调控的核心策略与研究进展。一方面,基于无机电致变色材料(如氧化钨)、有机导电聚合物(如聚苯胺)、金属(如银)、二维材料(如石墨烯)等变色体系,揭示了离子插层效应、载流子浓度调控及相变协同作用对发射率的调控机制;另一方面,综述了Fabry-Perot谐振腔、超表面、光子晶体及局域表面等离子体共振等光学谐振结构,分析了电磁模式耦合、共振峰动态调谐对红外辐射特性的增强效应。然而,现有e-TIED研究多受限于单一维度策略的优化:或过度聚焦材料本征优化(如开发新型电致变色材料),或片面专注于结构设计(如构建多层膜体系),导致红外发射率调控陷入性能瓶颈。针对此挑战,本文阐明了材料本征特性与光学结构的协同作用是实现红外发射率调控性能突破的关键,以期为新一代e-TIED的开发提供理论指导与技术参考。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
张虎林
王兰喜
陈明俊
陈曦
张翔
王晓毅
何延春
倪壮
李坤
杨淼
王虎
李垚
关键词:  电致变色  红外发射率  Fabry-Perot谐振腔  智能热控    
Abstract: The electrically tunable infrared emissivity device (e-TIED) features dynamically controllable infrared radiation properties, achieved through the application of an electric field or current. It is extensively utilized in various fields, including intelligent thermal management, stealth ca-mouflage, and building energy conservation. This paper systematically reviews the core strategies and research progress of e-TIED, focusing on material intrinsic characteristics control and optical structure design. On the one hand, the mechanism for regulating emissivity through ion intercalation effect, carrier concentration modulation, and phase transition synergy is elucidated using inorganic electrochromic materials (tungsten oxide), organic conductive polymers (polyaniline), metals (silver), and two-dimensional materials (graphene). On the other hand, the review covers optical resonant structures such as Fabry-Perot resonators, meta-surfaces, photonic crystals, and local surface plasmon resonance. It analyzes the enhancement effect of electromagnetic mode coupling and dynamic tuning of resonance peaks on the characteristics of infrared ra-diation. However, the current e-TIED research is primarily limited to optimizing a one-dimensional strategy:either placing excessive emphasis on enhancing materials (such as developing new electrochromic materials) or solely on structural design (such as constructing multilayer film systems), resulting in performance bottlenecks due to infrared emissivity regulation. This paper highlights the importance of synergy between mate-rial properties and optical structure to achieve breakthroughs in controlling infrared emissivity. Future research should prioritize interdisciplinary approaches, incorporating artificial intelligence, nanotechnology, materials science, and other relevant fields to devise more efficient solutions. This provides theoretical insights and practical references to propel the progress of a new era of e-TIED.
Key words:  electrochromic    infrared emissivity    Fabry-Perot resonator    intelligent thermal control
出版日期:  2026-06-25      发布日期:  2026-07-08
ZTFLH:  TQ174  
基金资助: 国家重点研发计划(2022YFB3806300);湖州市科技计划专项(2022GZ17)
通讯作者:  *王虎,兰州空间技术物理研究所高级工程师,甘肃省陇原青年英才,主要研究方向为空间热控防护薄膜与涂层技术。wanghu19841@163.com
李垚,哈尔滨工业大学航天学院教授、博士研究生导师、国家级高层次人才。主要从事光热功能复合材料的研究。yaoli@hit.edu.cn   
作者简介:  张虎林,博士,兰州空间技术物理研究所真空技术与物理国防科技重点实验室设计师。目前主要从事电致变发射率、功能薄膜及器件等方面的研究。
引用本文:    
张虎林, 王兰喜, 陈明俊, 陈曦, 张翔, 王晓毅, 何延春, 倪壮, 李坤, 杨淼, 王虎, 李垚. 电致变红外发射率器件研究进展[J]. 材料导报, 2026, 40(12): 25070137-11.
ZHANG Hulin, WANG Lanxi, CHEN Mingjun, CHEN Xi, ZHANG Xiang, WANG Xiaoyi, HE Yanchun, NI Zhuang, LI Kun, YANG Miao, WANG Hu, LI Yao. Research Progress of Electrically Tunable Infrared Emissivity Devices. Materials Reports, 2026, 40(12): 25070137-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25070137  或          https://www.mater-rep.com/CN/Y2026/V40/I12/25070137
1 Zhao X P, Mofid S A, Gao T, et al. Materials Today Physics, 2020, 13, 100205.
2 Wang S, Jiang T, Meng Y, et al. Science, 2021, 374(6574), 1501.
3 Zhu H, Li Q, Tao C, et al. Nature Communications, 2021, 12(1), 1805.
4 Demiryont H, Moorehead D. Solar Energy Materials and Solar Cells, 2009, 93(12), 2075.
5 Leung E M, Colorado E M, Stiubianu G T, et al. Nature Communications, 2019, 10(1), 1947.
6 Zhang X A, Yu S, Xu B, et al. Science, 2019, 363(6427), 619.
7 Xu C, Stiubianu G T, Gorodetsky A A. Science, 2018, 359(6383), 1495.
8 Salihoglu O, Uzlu H B, Yakar O, et al. Nano Letters, 2018, 18(7), 4541.
9 Barnes R B. Science, 1963, 140(3569), 870.
10 Niklasson G A, Granqvist C G. Journal of Materials Chemistry, 2007, 17(2), 127.
11 Chein S L K, Zhang H, Liu X, et al. Journal of the American Ceramic Society, 2021, 104(5), 2143.
12 Zhang X, Tian Y, Li W, et al. Solar Energy Materials and Solar Cells, 2019, 200, 109916.
13 Larsson A L, Niklasson G A. Materials Letters, 2004, 58(20), 2517.
14 Hale J S, Woollam J A. Thin Solid Films, 1999, 339(1-2), 174.
15 Demiryont H. In:23rd Annual AIAA/USU Conference on Small Satellites. Utah, 2009, pp. 1.
16 Franke E B, Trimble C L, Schubert M, et al. Applied Physics Letters, 2000, 77(7) 930.
17 Franke E B, Trimble C L, Hale J S, et al. Journal of Applied Physics, 2000, 88(10), 5777.
18 Franke E B, Neumann H, Schubert M, et al. Surface and Coatings Technology, 2002, 151-152, 285.
19 Bessiere A, Beluze L, Morcrette M, et al. Journal of Applied Physics, 2004, 95(12), 7701.
20 Kislov N. In:AIP Conference Proceedings. New Mexico, 2003, pp. 172.
21 Kislov N. In:AIP Conference Proceedings. New Mexico, 2004, pp. 112.
22 Demiryont H, Shannon III K. In:Proceedings of the SPIE Conference. Florida, 2012, pp. 84360B.
23 Mandal J, Du S, Dontigny M, et al. Advanced Functional Materials, 2018, 28(36), 1802180.
24 Chandrasekhar P, Zay B J, Birur G C, et al. Advanced Functional Materials, 2002, 12(2), 95.
25 Zhang L, Xu G, Wang L, et al. Dyes and Pigments, 2021, 187, 109084.
26 Wang B, Xu G, Song S, et al. Electrochimica Acta, 2021, 390, 138891.
27 Yilmaz P, Magni M, Martinez S, et al. ACS Applied Energy Materials, 2020, 3(4), 3779.
28 Li H, Xie K, Pan Y, et al. Synthetic Metals, 2009, 159(13), 1386.
29 Chandrasekhar P, Zay B J, Barbolt S, et al. In:AIP Conference Proceedings. Alabama, 2013, pp. 1208.
30 Tian Y, Zhang X, Dou S, et al. Solar Energy Materials and Solar Cells, 2017, 170, 120.
31 Zhang L, Li D, Li X, et al. Dyes and Pigments, 2019, 170, 107570.
32 Zhang L, Wang B, Li X, et al. Journal of Materials Chemistry C, 2019, 7(32), 9878.
33 Xu G, Zhang L, Wang B, et al. Solar Energy Materials and Solar Cells, 2020, 208, 110356.
34 Xu G, Zhang L, Wang B, et al. Journal of Materials Chemistry C, 2020, 8(38), 13336.
35 Li M, Liu D, Cheng H, et al. Science Advances, 2020, 6, eaba3494.
36 Brar V W, Sherrott M C, Jang M S, et al. Nature Communications, 2015, 6(1), 7032.
37 Lim M, Kim H D, Shim H C, et al. Nano Energy, 2024, 131, 110189.
38 Ergoktas M S, Bakan G, Steiner P, et al. Nano Letters, 2020, 20(7), 5346.
39 Inoue T, Zoysa M D, Asano T, et al. Nature Materials, 2014, 13(10), 928.
40 Xiao L, Ma H, Liu J, et al. Nano Letters, 2015, 15(12), 8365.
41 Gu J. Study on the fabrication and performance of VO2/HfO2/Al smart thermal control coating. Ph. D. Thesis, Harbin Institute of Technology, China, 2023 (in Chinese).
谷金鑫. VO2/HfO2/Al智能热控涂层的制备及性能研究. 博士学位论文, 哈尔滨工业大学, 2023.
42 Chen J, Wang Z, Liu C, et al. Advanced Materials, 2021, 33(14), 2007314.
43 Zhang H, Zhang X, Sun W, et al. Advanced Functional Materials, 2024, 34(16), 2307356.
44 Wang P, Wang H, Sun Y, et al. Physical Chemistry Chemical Physics, 2024, 26(22), 16253.
45 Wang X, Cao Y, Zhang Y, et al. Applied Surface Science, 2015, 344, 230.
46 Ji C, Lee K, Xu T, et al. Advanced Optical Materials, 2017, 5(20), 1700368.
47 Beaini R, Baloukas B, Loqual S, et al. Solar Energy Materials and Solar Cells, 2020, 205, 110260.
48 Wang S, Jiang T, Meng Y, et al. Science, 2021, 374(6574), 1501.
49 Long L, Taylor S, Wang L. ACS Photonics, 2020, 7(8), 2219.
50 Tang K, Dong K, Li J, et al. Science, 2021, 374(6574), 1504.
51 Lounis S D, Runnerstrom E L, Llordes A, et al. The Journal of Physical Chemistry Letters, 2014, 5(9), 1564.
52 Pattathil P, Giannuzzi R, Manca M. Nano Energy, 2016, 30, 242.
53 Llordes A, Garcia G, Gazquez J, et al. Nature, 2013, 500(7462), 323.
54 Heo S, Kim J, Ong G K, et al. Nano Letters, 2017, 17(9), 5756.
55 Kim J, Ong G K, Wang Y, et al. Nano Letters, 2015, 15(8), 5574.
56 Barile C J, Slotcavage D J, Mcgehee M D. Chemistry of Materials, 2016, 28(5), 1439.
57 Liu D, Jia Y, Jin Y, et al. Nature Communications, 2023, 14(1), 5087.
58 Ono M, Chen K, Li W, et al. Optics Express, 2018, 26(18), A777.
59 Sun W, Zhang X, Chen M, et al. ACS Applied Nano Materials, 2023, 6(24), 23506.
60 Redel E, Mlynarski J, Moir J, et al. Advanced Materials, 2012, 24(35), 265.
61 Haddad E, Kruzelecky R V, Hendaoui A, et al. In:43rd International Conference on Environmental Systems. Colorado, 2013, pp. 3436.
62 Sun K, Xiao W, Ye S, et al. Advanced Materials, 2020, 32(25), 2001534.
63 Morsy A M, Barako M T, Jankovic V, et al. Scientific Reports, 2020, 10(1), 13964.
64 Tang K, Wang X, Dong K, et al. Advanced Materials, 2020, 32(36), 1907071.
[1] 栾俨丁, 王艳, 王磊, 罗凯, 吴洁, 赖蔓崎. 多尺度孔隙结构及其在辐射制冷中的应用进展[J]. 材料导报, 2026, 40(8): 25040199-10.
[2] 王申, 严闪闪, 梁文城, 毛阳俊, 许青青, 潘梦瑶, 赵俊华, 徐洪波. 电致变色MOF材料的研究进展[J]. 材料导报, 2026, 40(12): 25090138-13.
[3] 赵思名, 郭震宇, 黄娅, 蓝帆, 赵卓菁, 李润, 张如范. 面向建筑节能的新型光热调控技术:主动电致变色与被动辐射制冷[J]. 材料导报, 2025, 39(1): 24100008-18.
[4] 范浩博, 豆书亮, 李垚. 二氧化钒智能热控涂层光学结构原理及研究进展[J]. 材料导报, 2025, 39(1): 24100229-10.
[5] 张文霞, 贾岩, 程海峰, 刘东青. 全固态电致变色器件研究进展[J]. 材料导报, 2025, 39(1): 24100119-11.
[6] 解伟荣, 周涵. 柔性电响应动态热辐射调控材料研究进展[J]. 材料导报, 2025, 39(1): 24110064-8.
[7] 王海萍, 陈必华, 陶益杰, 黄凯兵, 张世国. 聚醚接枝丙烯酸树脂基凝胶聚合物电解质的制备及在电致变色器件中的应用[J]. 材料导报, 2024, 38(7): 22090034-5.
[8] 陈渊泽, 牛春晖, 王雷, 杨明庆, 张世玉, 吕勇. 聚苯胺红外电致变色器件研究进展[J]. 材料导报, 2024, 38(5): 22090259-10.
[9] 蔡轩皓, 娄兴, 覃继宁, 周涵. 电致变色材料微纳结构设计及多波段调控应用研究进展[J]. 材料导报, 2024, 38(21): 23100087-7.
[10] 俞朱敏, 李琳, 赵凯, 吴梦悦, 叶常青. 具有光子晶体结构的电致变色器件的研究进展[J]. 材料导报, 2024, 38(21): 23070230-13.
[11] 张伟钢, 李娇, 吕丹丹. 涂料助剂对PDMS改性环氧树脂/Al复合涂层性能的影响[J]. 材料导报, 2024, 38(10): 23010030-5.
[12] 吕丹丹, 李慕荣, 张伟钢. 超疏水PDMS改性聚氨酯/黄铜复合涂层的制备及性能表征[J]. 材料导报, 2023, 37(4): 21060116-6.
[13] 杜益嘉, 王盼, 肖诚禹, 唐道远, 徐建明, 周涵. 基于外场调控的智能热控超材料[J]. 材料导报, 2022, 36(2): 20110075-6.
[14] 李晓丹, 胡心雨, 刘小平, 刘小清, 申渝, 唐莹, 冯佳成. 苯并噁嗪树脂的研究新进展:智能化应用及能源、环境领域应用[J]. 材料导报, 2021, 35(3): 3209-3218.
[15] 汪心坤, 赵芳, 王建江. Zn1-xCexO纳米纤维的电纺制备及其红外雷达兼容隐身性能[J]. 材料导报, 2019, 33(Z2): 83-88.
[1] XU Yangtao, LOU Dechao, CHEN Baolin. Effects of Nickel Content on High Temperature Coarsening of γ' Phase in Co-8.8Al-9.8W Alloys[J]. Materials Reports, 2018, 32(6): 943 -946 .
[2] LI Yan, CAO Rui, CHE Hongyan, ZHAI Yazhong. Impact-Abrasive Wear Behavior of Cutting Tool Cemented Carbide YG8[J]. Materials Reports, 2026, 40(4): 25010200 -6 .
[3] WANG Lisha, CAO Rui, ZHANG Yawei, ZHANG Ji. Effects of Isothermal Oxidation on the Tensile and Fatigue Properties of GH3230 Alloy[J]. Materials Reports, 2026, 40(3): 25010188 -9 .
[4] TONG Fujia, ZHANG Guan, XIE Lei, ZHAO Dongmei, REN Tiezhen. Effect of Adding Ta on Corrosion Resistance of Fe-based Amorphous Alloy Coatings[J]. Materials Reports, 2026, 40(6): 25020082 -8 .
[5] CAO Jianghai, FANG Weiping, LUO Bingbing, ZENG Yangming, ZHANG Yupeng, WANG Gang. Effect of Hot Isostatic Pressing Heating Temperature on Microstructure and Properties of Ti6Al4V Titanium Alloy by Additive Manufacturing[J]. Materials Reports, 2026, 40(6): 25020112 -6 .
[6] ZHANG Yating, ZHOU Xiangyang, YANG Juan, CHEN Song, ZHOU Jinhui, TANG Jingjing. Progress in Graphite Anode Materials for Fast-charging Lithium-ion Batteries[J]. Materials Reports, 2026, 40(11): 25050048 -12 .
[7] WANG Kun, WANG Lixin, AN Pan, LI Guojie, CHEN Lin, ZHANG Shaoyan. Synthesis of C3N4/MnSnO3/C Hierarchical Heterostructure Composite and Its Lithium Storage Performance[J]. Materials Reports, 2026, 40(11): 25070179 -6 .
[8] MA Li, LI Shuang, HUANG Xiao, FAN Jing, LIU Shangming. Research Progress on Performance Testing Technology of Building Fireproof Materials[J]. Materials Reports, 2026, 40(11): 25040294 -11 .
[9] JI Chenyuan, ZHAO Zengfeng, YAO Lei, LIN Can, XIAO Jianzhuang. Hydration Kinetics Analysis and Life Cycle Assessment of Cement Blended Binder Incorporating Sand Washing Residual Mud[J]. Materials Reports, 2026, 40(11): 25050182 -6 .
[10] XIA Weitong, WANG Yujie, ZHANG Yichao, LI Xinghua, WU Fengyuan. Research Progress on Genesis-distribution and Amelioration-treatment of Coastal Saline Soils[J]. Materials Reports, 2026, 40(11): 25080026 -8 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed