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材料导报  2026, Vol. 40 Issue (12): 25070095-10    https://doi.org/10.11896/cldb.25070095
  无机非金属及其复合材料 |
正极富锂添加剂在锂离子电容器中的应用进展
徐建伟1,2, 刘贺强3, 刘洋1,2, 安亚斌3,4, 王浩1,2, 张熊3,4,*
1 北京绿发中科锂电容科技有限公司,北京 101111
2 中国绿发投资集团有限公司,北京 100020
3 中国科学院电工研究所高密度电磁动力与系统全国重点实验室,北京 100190
4 齐鲁中科电工先进电磁驱动技术研究院山东省先进电磁变换技术重点实验室,济南 250013
Progress in the Application of Lithium-rich Cathode Additives in Lithium-ion Capacitors
XU Jianwei1,2, LIU Heqiang3, LIU Yang1,2, AN Yabin3,4, WANG Hao1,2, ZHANG Xiong3,4,*
1 Beijing Green Development Lithium-ion Capacitors Technology Co., Ltd., Beijing 101111, China
2 China Green Development Investment Group Co., Ltd., Beijing 100020, China
3 State Key Laboratory of High Density Electromagnetic Power and Systems, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
4 Shandong Key Laboratory of Advanced Electromagnetic Conversion Technology, Institute of Electrical Engineering and Advanced Electromagnetic Drive Technology, Qilu Zhongke, Jinan 250013, China
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摘要 锂离子电容器因其高功率密度、高能量密度和长循环寿命等优异特性,已成为储能领域的研究热点。然而,其电化学性能受限于负极首次充放电过程中的库仑效率。为突破这一技术瓶颈,正极预锂化技术通过引入牺牲型锂源材料,在器件活化阶段定向补偿负极固态电解质界面形成所消耗的不可逆锂离子,成为提升锂离子电容器电化学性能的核心策略。本文系统综述了正极预锂化材料的设计原则与技术进展,重点剖析了二元锂化合物、富锂过渡金属氧化物及有机锂盐在锂离子电容器体系中的应用实例与性能优势,并深入探讨了正极牺牲锂盐预锂化在实际应用中面临的关键挑战与发展路径。本综述旨在为开发低工作电位、高不可逆容量的新型预锂化材料提供理论指导,并为建立预锂化工艺与器件性能的构效关系奠定技术基础。
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徐建伟
刘贺强
刘洋
安亚斌
王浩
张熊
关键词:  锂离子电容器  正极  活性炭  富锂化合物  预锂化    
Abstract: Lithium-ion capacitors have emerged as a research hotspot in the energy storage field due to their advantages of high power density, high energy density, and long cycle life. However, their electrochemical performance is significantly constrained by the initial coulombic efficiency of the anode during the first charge-discharge cycle. To overcome this bottleneck, cathode prelithiation technology, which introduces sacrificial lithium-containing materials, has become a key strategy. During the device activation stage, this approach compensates for the irreversible lithium ion loss caused by the formation of the solid electrolyte interphase on the anode. This review systematically summarizes the design principles and recent advancements in cathode prelithiation materials. Particular emphasis is placed on the application examples and performance advantages of binary lithium compounds, lithium-rich transition metal oxides, and organic lithium salts in lithium-ion capacitors. In addition, this review provides an in-depth analysis of the key challenges and potential development pathways associated with sacrificial lithium salt-based cathode prelithiation in practical applications. The aim is to provide theoretical guidance for the development of novel prelithiation materials with low working potentials and high irreversible capacities, and to lay a technical foundation for establishing structure-performance relationships between prelithiation processes and device-level electrochemical performance.
Key words:  lithium-ion capacitors    cathode    activated carbon    lithium-rich compound    prelithiation
出版日期:  2026-06-25      发布日期:  2026-07-08
ZTFLH:  G304  
基金资助: 国家自然科学基金(52377218)
通讯作者:  *张熊,博士,中国科学院电工研究所研究员、博士研究生导师。目前主要从事锂离子电容器的研究。zhangxiong@mail.iee.ac.cn   
作者简介:  徐建伟,北京中绿中科锂电容科技有限公司总经理助理,电力工程技术中级工程师,目前主要从事锂离子电容器生产研发管理工作。
引用本文:    
徐建伟, 刘贺强, 刘洋, 安亚斌, 王浩, 张熊. 正极富锂添加剂在锂离子电容器中的应用进展[J]. 材料导报, 2026, 40(12): 25070095-10.
XU Jianwei, LIU Heqiang, LIU Yang, AN Yabin, WANG Hao, ZHANG Xiong. Progress in the Application of Lithium-rich Cathode Additives in Lithium-ion Capacitors. Materials Reports, 2026, 40(12): 25070095-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25070095  或          https://www.mater-rep.com/CN/Y2026/V40/I12/25070095
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