糖基三聚氰胺甲醛树脂木材胶黏剂的研究进展

doi:10.11896/cldb.21120170

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Abstract Melamine formaldehyde resin (MF), commonly synthesized by the polycondensation of melamine and formaldehyde under alkaline catalyst conditions, belongs to one of the three major aldehyde-based thermosetting adhesives and ranks No.3 of the adhesives with most consumption in global wood industry. MF has many excellent performances, such as strong bonding strength, high hardness, good boiling water resis-tance, excellent thermal stability, wonderful low-temperature curing ability, and outstanding wear resistance. Meanwhile, MF also has some shortcomings which have been for a long time limiting its industrial applications to some extent, e.g., brittleness, short shelf life, high price, etc. Therefore, it is of vital practical significance to seek low-cost, high-performance and eco-friendly methods of modifying MF. Sugars are a kind of natural renewable substances with low cost and wide source, and more importantly, capability of being decomposed into active monomers with hydroxyl and aldehyde groups under suitable conditions. These monomers can react with formaldehyde or amino-group, which results in reduced condensation time. The addition of sugar can also improve the toughness and thermal stability of the products, and hence is a potential method to overcome the inherent brittleness of MF. This article reviews recent research on sugar including sucrose, maltose and glucose, used as the raw materials to synthesize sugar-based melamine formaldehyde resins. It also gives detailed description about the authors’ understanding of the synthetic mechanism, and summary of bonding strength, thermal stability and free formaldehyde content of sugar-based melamine formaldehyde resins. This work is expected to provide theoretical support for the high-value utilization of sugar and the development of sugar-based melamine formaldehyde copolymer adhesives.

Key words： sucrose maltose glucose melamine formaldehyde resin wood adhesive

Published: 10 September 2023 Online: 2023-09-05

CLC number:	TQ433.439
	TQ323

Fund:Major Science Technology Project of Guangxi Province (AA18118044, AA17204067), the National Natural Science Foundation of China (31360158), the National Science and Technology Support Program of China (2015BAD14B03).

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	Articles by authors
	LIU Jinming
	ZHANG Yifu
	GAN Weixing
	MO Hailin

Cite this article:

LIU Jinming,ZHANG Yifu,GAN Weixing, et al. Research Progress on Sugar-based Melamine Formaldehyde Resin as Wood Adhesives[J]. Materials Reports, 2023, 37(17): 21120170-7.

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http://www.mater-rep.com/EN/10.11896/cldb.21120170 OR http://www.mater-rep.com/EN/Y2023/V37/I17/21120170

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