INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Research Progress on Fabrication and Application in Photocatalytic Degradation of Organic Pollutants of Spinel Ferrite Heterojunction |
CHEN Dandan, LI Yan*, WANG Aiguo
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Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230601, China |
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Abstract Discharge of organic wastewater into the environment following the rapid development of industrial production has led to serious pollution. Photocatalytic technology using solar energy to degrade organic pollutants is considered one of the most valuable strategies for water treatment. However, traditional photocatalysts (e.g., TiO2, ZnO, and ZnS) suffer from the inefficient use of visible light, high recombination rate of photon-generated carriers, and poor recycling performance, which hinder their widespread application. Researchers have proposed the preparation of the spinel ferrite heterojunction photocatalyst by combining a traditional semiconductor and spinel ferrite. Photocarrier recombination is inhibited by the interface of the heterojunction, and the excellent magnetic properties of the ferrite guarantee the recovery and reuse of the photocatalyst in wastewater treatment. At present, a large number of spinel ferrites such as Fe3O4, CoFe2O4, CuFe2O4, ZnFe2O4 and NiFe2O4 have led to remarkable research results in the field of heterojunction photocatalysts. In this paper, the spinel ferrite heterojunctions are divided into type-Ⅱ, Schottky, Z-scheme (traditional, all-solid-state, and direct), and step-scheme heterojunctions. The separation strategies of the photogenerated charges, defects in various spinel ferrite heterojunction materials, as well as their applications in the field of water treatment are discussed, providing a theoretical reference for the construction of spinel ferrite heterojunction photocatalysts with high carrier separation rates.
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Published: 25 August 2023
Online: 2023-08-14
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Fund:Key Projects of Natural Science Foundation of Colleges and Universities in Anhui Province (KJ2020A0476), and Key Research and Development Projects of Anhui Province (202004b11020033). |
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