镁合金负差数效应的研究进展

doi:10.11896/cldb.21070256

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Abstract With the continuous progress in industrialization, the demand for lightweight components in engineering applications is becoming increasingly urgent, which has significantly promoted the rapid development of Mg alloys. However, the poor corrosion resistance of Mg alloys seriously hinders their practical engineering applications. To effectively solve this issue, it is essential to comprehensively study the corrosion mechanism of Mg alloys. Mg alloys exhibit a typical negative difference effect (NDE) in their electrochemical corrosion process, i.e., the hydrogen evolution rate increases with the increase in potential under an anodic polarization process, which is different from the traditional electrochemical theory.
In recent years, researchers from different countries have conducted several investigations on the NDE of Mg alloys and successively established eight theoretical models including the local protective film model, monovalent Mg ion model, dissolution and abscission model, MgH₂ solution promotion theory, comprehensive theory, partial external electronic circuit consumption mechanism, hydrogen evolution through an exchange current density i₀ increase mechanism, and electrocatalysis mechanism. Based on the above models, a deeper understanding of the hydrogen evolution process of Mg alloys is obtained and the depth of research on the corrosion mechanism of Mg alloys is improved.
This paper overviews the basic principle and research status of NDE in the electrochemical corrosion of Mg alloys, summarizes the eight theoretical models of NDE and the development process of each model, highlights their shortcomings, and anticipates the research direction of NDE in the future.

Key words： magnesium alloy negative difference effect corrosion monovalent magnesium ion theoretical model anodic polarization

Published: 25 June 2023 Online: 2023-06-20

CLC number:

TG178

Fund:National Natural Science Foundation of China (52071220, 51871211, U21A2049), and High Level Achievement Construction Project of Shenyang Ligong University(SYLUXM202105).

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	HOU Jiyu
	WANG Baojie
	XU Kai
	XU Daokui
	SUN Jie

Cite this article:

HOU Jiyu,WANG Baojie,XU Kai, et al. Research Progress on the Negative Difference Effect of Magnesium Alloys[J]. Materials Reports, 2023, 37(12): 21070256-7.

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http://www.mater-rep.com/EN/10.11896/cldb.21070256 OR http://www.mater-rep.com/EN/Y2023/V37/I12/21070256

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