| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress on Adsorption of Heavy Metal Ions and Radionuclides by Metal-Organic Framework Materials |
| LI Zifan1,2, ZHANG Zhibin1,2,*, DONG Zhimin1,2, LIU Yunhai1,2,*
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1 Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang 330013, China
2 State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang 330013, China |
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Abstract Metal-organic frameworks (MOFs)are a kind of porous materials by combining metal nodes with organic ligands by strong bonds. Compared with the traditional adsorption materials, MOFs have various advantages, such as adjustable structural, functional diversity, large specific surface area and high porosity. Another unique advantage is that the pores size can be adjusted, and the specific functional groups and active sites can be modified by in situ synthesis or post-modification to obtain the efficient and selective adsorption of different heavy metals and radionuclides from wastewater, which is of great significance to resource recycling and environmental remediation. In this paper, the latest research progresses and corresponding adsorption mechanisms for the adsorption of heavy metals (As, Cr, Hg, etc.)and radionuclides (U, Tc, etc.)are described in detail. And the methods of improving the adsorption of MOFs are summarized. Furthermore, the challenges and problems of MOFs as the adsorbents of heavy metals and radionuclides are proposed.
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Published: 25 June 2023
Online: 2023-06-20
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| Fund:National Natural Science Foundation of China (U2167223, 21866004, 21866003, 22066003), the Defense Industrial Technology Development Program (JCKY2019401C004), and the Open Fund of Jiangxi Province Key Laboratory of Synthetic Chemistry (JXSC202012). |
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2023, Vol. 37 
