多孔富缺陷半导体应用于光催化降解废水有机污染物

doi:10.11896/cldb.21110143

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Abstract Porous semiconductor materials with high specific surface area, preferential selectivity and microchannels for electrons/photons can improve the rate and efficiency of photocatalytic reactions and have shown important applications in adsorption and photocatalysis of the organic pollutants in wastewater. Porous semiconductors show some structural advantages in photochemistry, dynamics, and electronics: large pores can be used as guided channels for light propagation to increase the photon absorption efficiency, mesopores have specific selectivity for differential reactants and products in complex reaction systems, and micropores can provide microscopic paths for photogenerated carriers conduction and migration. Structural defects have previously been considered as disadvantages in photocatalytic reactions, resulting in the recombination of electron-hole pairs and decrease in lifetime of photogenerated carriers and photocatalytic efficiency. In recent years, some researchers explore that the introduction of defective sites can further optimize the microstructure and properties of porous materials and the structural defects can supply more spaces for reactions and more reactive sites for photocatalysis. The porous structure and defective sites of semiconductor materials promote coordinated photocatalytic processes, and the porosities and defects play important roles in photocatalytic decontamination. In this review, synthesis of porous semiconductor micro/nanostructures, design for defective sites,effects on oxygen storage and electron migration by porous defect structures and photodegradation mechanism of organic pollutants are briefly summarized. It is possible to predict that porous materials assisted in defect structures will be competitive candidates for semiconductor photocatalysts. The negative effect of structural defects as recombination centers of photoinduced carriers is an urgent problem to be solved. It can be predicted the prospects of photocatalytic materials with porous and defective structures are promising, and some novel ideas have been provided to design highly reactive photocatalysts for excellent photodegradation of organic pollutants in wastewater.

Key words： porous semiconductor defective sites guided connection oxygen storage electron transmission sewage organics photocatalytic mechanism

Published: 25 June 2023 Online: 2023-06-20

CLC number:	O643
	TQ426

Fund:Youth Innovation Project, Natural Science Foundation of Fujian Province, China (2019J05142), and Start-up Fund for Doctoral Scientific Research of Fujian Academy of Agricultural Sciences (DC2018-6).

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LI Jie. Porous Defective Semiconductor for Photocatalytic Degradation of Organic Pollution in Wastewater[J]. Materials Reports, 2023, 37(12): 21110143-9.

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http://www.mater-rep.com/EN/10.11896/cldb.21110143 OR http://www.mater-rep.com/EN/Y2023/V37/I12/21110143

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