POLYMERS AND POLYMER MATRIX COMPOSITES |
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Preparation and Properties of Water-borne Zinc Coating |
LI Qingpeng1,2, LIU Liran1, ZHANG Liang3, WANG Li2, GUAN Yong4, WANG Na1,2
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1 Liaoning Provincial Key Laboratory for Synthesis and Preparation of Special Functional Materials, Shenyang University of Chemical Technology, Shenyang 110142, China 2 Shenyang Research Institute of Industrial Technology for Advanced Coating Materials, Shenyang 110330, China 3 Shenyang Hangda Technology Co., Ltd., Shenyang 110043, China 4 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China |
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Abstract Ahigh performance waterborne zinc coating was prepared by modifying acrylic resin using silane (A-187) and high modulus potassium silicate.The storage stability of the coatings and the surface morphology, composition and corrosion resistance of the coatings were characterized and analyzed by Fourier infrared spectroscopy, SEM, EDS energy spectroscopy, X-ray diffraction (XRD), neutral salt spray and electrochemical tests. The results showed that: A187, potassium silicate and aqueous acrylic resin were successfully cross-linked and modified to form an aqueous resin shell structure on the surface of zinc powder to protect the active zinc powder; SEM showed that the zinc powder was uniformly distributed and the surface of the coating was smooth and flat without obvious defects; after 1 000 hours of neutral salt spray test, the surface of the coating was free of red rust; compared with the solvent-based Zn coating, the coating resistance of the water-based Zn coating prepared in this paper is increased by nearly two orders of magnitude, and the coating has better protective properties.
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Published: 10 June 2023
Online: 2023-06-19
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Fund:“Jie Bang Gua Shuai” of Science and Technology Projects of Liaoning Province in 2021(2021JH1/10400091), Liao-ning Provincial Education Department's 2021 Research Grant Project (LJK Z0470), Scientific Research Funding Project of the Educational Department of Liao-ning Province in 2020(LZ2020002), and Liaoning BaiQianWan Talents Program([2020]78). |
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