稀土倍半氧化物晶体材料研究进展

doi:10.11896/cldb.22110093

Abstract
Figure/Table
References
Related Citation (1)

Download:

Full Text ( PDF ) (5108KB)
Export: BibTeX | EndNote (RIS)

Abstract Rare earth sesquioxide crystals are very suitable for ultrafast laser gain and magneto-optical medium. Its research began in the 1920s. Because of high thermal conductivity, wide fluorescence spectrum, low phonon energy and other advantages, they're still a research highlight in the field of advanced materials. Ranking first in the top 10 cutting-edge scientific issues issued by the China Association for Science and Technology in 2021, is ‘how to break through the preparation theory and technology of large size crystal materials’. It is clear that improving the preparation technology of large size crystal materials is the key to the commercial application of crystals. The crystalline intrinsic properties and crystal quality of materials are the result of the coupling of multiple degrees of freedom at the multi-scale level. Therefore, it is needed to study the multi-level and multi factor problems of rare earth such as ion bonding, melt structure evolution, crystal growth, etc., in the system at the multi-scale level, for the development of high-quality rare earth sesquioxide materials. In this paper, we focus on the influence of the electronegativity of rare earth ions on the coordination number of cations in the melt at the micro scale, the melt structure researched by the experiment and computational simulation, and the latest progress in crystal growth. The high melting point of rare earth sesquioxide (≥2 400 ℃) are the limits to the use of iridium crucibles and most growth technologies, and it is accordingly slow to develop the rare earth sesquioxide crystals at the inch grade. It is the key point for the preparation of large size and high-quality rare-earth sesquioxide crystals to adopt cosolvent method, heat exchange method and design low melting point components. In order to promote the commercial application of rare earth sesquioxide, revealing the coordination structure of rare earth ions, the evolution of melt structure, the formation mechanism of defects in the growth process, and developing the large-scale crystal growth technology are the key scientific challenges and technical bottlenecks that need to be solved urgently.

Key words： rare earth sesquioxide crystal computer simulation crystal growth and preparation

Published: 10 February 2023 Online: 2023-02-23

CLC number:

O469

Fund:The National Natural Science Foundation of China for Youth (52202012), Key Projects of National Natural Science Foundation of China (51832007), International (regional) Cooperation and Exchange Projects (52220105010), 2021 Sino-German Cooperation and Exchange Program of the Sino-German Science Center of the National Natural Science Foundation (M-0755), Major Basic Research Project of Shandong Natural Science Foundation (ZR2020ZD35), and Research and Development Project of Shandong Institute of Industrial Technology (Z1250020005).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LIU Feng
	CHEN Kunfeng
	XUE Dongfeng

Cite this article:

LIU Feng,CHEN Kunfeng,XUE Dongfeng. Research Progress of the Rare Earth Sesquioxide Crystal Materials[J]. Materials Reports, 2023, 37(3): 22110093-7.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.22110093 OR http://www.mater-rep.com/EN/Y2023/V37/I3/22110093

1 Xu L L, Sun C T, Xue D F. Journal of the Chinese Society of Rare Earths, 2018, 1(1),1 (in Chinese).
徐兰兰,孙丛婷,薛冬峰.中国稀土学报, 2018, 1 (1), 1.
2 Chen K F, Hu J L, Zhang Y B, et al. Inorganic Chemicals Industry, 2020,52(3), 11(in Chinese).
陈昆峰,胡家乐,张一波, 等. 无机盐工业, 2020, 52 (3), 11.
3 Chen K F, Ma T Y, Wang A L, et al. Inorganic Chemicals Industry, 2021, 53 (12), 1(in Chinese).
陈昆峰,马天宇,王安良, 等. 无机盐工业, 2021, 53 (12), 1.
4 China Association for Science and Technology. Focusing on the Future of Science and Technology: 2021 major scientific problems, engineering and technical problems, China Science and Technology Press, China, 2021(in Chinese).
中国科学技术协会. 面向未来的科技:2021重大科学问题、工程技术难题, 中国科学技术出版社, 2021.
5 Liu F, Chen K F, Peng C, et al. Journal of Synthetic Crystals, 2022, 51(Z1), 1732(in Chinese).
刘锋,陈昆峰,彭超, 等. 人工晶体学报, 2022, 51 (Z1), 1732.
6 Liu F, Chen K F, Peng C, et al. Journal of the Chinese Ceramic Society, 2023, 51(2), 1(in Chinese).
刘锋,陈昆峰,彭超, 等. 硅酸盐学报, 2023, 51(2), 1.
7 Zachariasen W. Zeitschrift fur Physikalische Chemie, 1926, 123U(1), 134.
8 Pauling L. Zeitschrift fur Kristallographie-Crystalline Materials, 1929, 69 (1-6), 415.
9 Gasson D B,Cockayne B. Journal of Materials Science, 1970, 5 (2), 100.
10 Fornasiero L,Mix E,Peters V,et al. Crystal Research and Technology, 1999, 34 (2), 255.
11 Fornasiero L,Mix E,Peters V,et al. Ceramics International, 2000, 26 (6), 589.
12 Petermann K,Fagundes-Peters D,Johannsen J,et al. Journal of Crystal Growth, 2005, 275 (1), 135.
13 Fukabori A,Chani V,Kamada K,et al. Journal of Crystal Growth, 2011, 318 (1), 823.
14 Shi G Q, Xue D F. Chemical Research, 2022, 33 (5), 387(in Chinese).
史国强,薛冬峰.化学研究, 2022, 33 (5), 387.
15 Panling L. The nature of the chemical bond (3rd Ed), Cornell University Press, USA, 1960.
16 Li K Y, Xue D F. Chinese Science Bulletin, 2008, 53(20), 2442(in Chinese).
李克艳,薛冬峰.科学通报, 2008, 53(20), 2442.
17 Parr R G, Donnellly R A, Levy M, et al. Journal of Chemical Physics, 1978, 68(8), 3801.
18 Li K,Xue D. The Journal of Physical Chemistry A, 2006, 110 (39), 11332.
19 Li K,Wang X,Xue D. The Journal of Physical Chemistry A, 2008, 112 (34), 7894.
20 Xue D F, Li K Y, Zhang F F. Progress in Materials Chemistry, East China University of Science and Technology Press, China, 2011, pp.7(in Chinese).
薛冬峰,李克艳,张方方. 材料化学进展, 华东理工大学出版社, 2011, pp.7.
21 Guzik M,Pejchal J,Yoshikawa A,et al. Crystal Growth & Design, 2014, 14 (7), 3327.
22 Hanic F,Hartmanova M,Knab G G,et al. Acta Crystallographica Section B, 1984, 40 (2), 76.
23 Pauling L,Shappell M D. Zeitschriftfür Kristallographie-Crystalline Mate-rials, 1930, 75 (1), 128.
24 Sheldrick G. Acta Crystallographica Section A, 2008, 64 (1), 112.
25 Shankar K,David L P. Journal of Physics: Condensed Matter, 2000, 12 (12), R145.
26 Cristiglio V,Hennet L,Cuello G J,et al. Journal of Non-Crystalline Solids, 2007, 353 (8), 993.
27 Krishnan S,Ansell S,Price D L. Journal of the American Ceramic Society, 1998, 81 (7), 1967.
28 Tosi M P. Annual Review of Physical Chemistry, 1993, 44 (1), 173.
29 Du J C. Journal of the American Ceramic Society, 2009, 92 (1), 87.
30 Belonoshko A B. Geochimica et Cosmochimica Acta, 1994, 58 (19), 4039.
31 Belonoshko A B,Dubrovinsky L S. American Mineralogist,1996, 81 (3-4), 303.
32 Maija M K. Journal of Physics: Condensed Matter, 2000, 12 (13), 2953.
33 Skinner L B,Benmore C J,Weber J K R,et al. Physical Review Letters, 2014, 112 (15), 157801.
34 Pedone A,Malavasi G,Menziani M C,et al. The Journal of Physical Che-mistry B, 2006, 110 (24), 11780.
35 Kramer G J,Farragher N P,van Beest B W H,et al. Physical Review B, 1991, 43 (6), 5068.
36 Belonoshko A B,Gutierrez G,Ahuja R,et al. Physical Review B, 2001, 64 (18), 184103.
37 Allen M P,Tildesley D J. Computer simulation of liquids, Oxford University Press, UK, 2017.
38 Liu F, Peng C, Xue D F,et al. In: 2022 Academic Annual Meeting of China Rare Earth Society, Baotou, Inner Mongolia, China, 2022(in Chinese).
刘锋,彭超,薛冬峰,等. 中国稀土学会2022学术年会, 中国内蒙古包头, 2022.
39 Hennet L,Thiaudière D,Landron C,et al. Nuclear Instruments and Met-hods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2003, 207 (4), 447.
40 Yang Y,Olmsted D L,Asta M,et al. Acta Materialia, 2012, 60 (12), 4960.
41 Kränkel C. IEEE Journal of Selected Topics in Quantum Electronics, 2015, 21 (1), 250.
42 Yoshikawa A,Chani V. MRS Bulletin, 2009, 34 (4), 266.
43 Chen G,Li S,Zhang L,et al. Infrared Physics & Technology, 2020, 109, 103431.
44 Veber P,Velázquez M,Jubera V,et al. CrystEngComm, 2011, 13 (16), 5220.
45 Velázquez M,Veber P,Buşe G,et al. Optical Materials, 2015, 39, 258.
46 Veber P,Velázquez M,Gadret G,et al. CrystEngComm, 2015, 17 (3), 492.
47 Heuer A M,von Brunn P,Huber G,et al. Optical Materials Express, 2018, 8 (11), 3447.
48 Yin Y,Wang G,Jia Z,et al. CrystEngComm, 2020, 22 (39), 6569.
49 Zhao H Y, Hou W T, Xue Y Y,et al. Journal of Synthetic Crystals, 2021, 50(4), 732(in Chinese).
赵衡煜,侯文涛,薛艳艳,等. 人工晶体学报, 2021,50 (4), 732.
50 Si X Y, Huang H T, Qian L J, et al. Laser & Optoelectronics Progress,2019, 56 (9), 9(in Chinese).
司晓云,黄海涛,钱丽娟,等. 激光与光电子学进展, 2019, 56 (9), 9.
51 Peters R,Kränkel C,Petermann K,et al. Journal of Crystal Growth, 2008, 310 (7), 1934.
52 Krankel C,Uvarova A,Haurat E,et al. Acta Crystallographica Section B, 2021, 77 (4), 550.