涂布正极表面丝网印刷氧化锌颗粒对锂离子电池性能的影响

doi:10.11896/cldb.21050056

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (4362KB)
Export: BibTeX | EndNote (RIS)

Abstract Previous studies have shown that modifying the doctor-bladed electrodes is beneficial to improve the electrochemical performance of lithium-ion batteries. In this study, the ternary cathode material LiNi_1/3Co_1/3Mn_1/3O₂, conductive additives, polyvinylidene fluoride and N-methylpyrrolidone were mixed into a homogeneous slurry, spread on aluminum foil and dried sufficiently to prepare NCM electrodes. The zinc oxide (ZnO) particles of around 100 nm in diameter were prepared by chemical precipitation method. Screen-printed ZnO particles were well dispersed on the surface of the electrode. The crystal structure of LiNi_1/3Co_1/3Mn_1/3O₂ did not change after the modification. The batteries assembled with the modified electrodes had higher rate capability and better cycling performance. The increasing rate of electrochemical polarization of the modified electrode slow down with the charge-discharge test. The results show that modifying the electrode with ZnO particles by facile screen-printing method can effectively improve the cycling performance and rate performance of the batteries.

Key words： LiNi_1/3Co_1/3Mn_1/3O₂ (NCM) electrode screen printing zinc oxide surface modification

Published: 10 November 2022 Online: 2022-11-03

CLC number:

TM912.9

Fund:National Natural Science Foundation of China (51575335,51876113), Program for New Century Excellent Talents in University(NCET-10-0296), the Project Science and Technology Commission of Shanghai Municipality (16030501300), the Project Open Found of Jiangsu Laboratory of Lake Environment Remote Sensing Technologies (JSLERS-2019-003), and the Project Open Project of Shanghai Key Laboratory of Digital Manufacture for Thin-walled Structures(2019-002).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LU Chunchi
	WANG Ying
	WANG Dongzheng

Cite this article:

LU Chunchi,WANG Ying,WANG Dongzheng. Effect of Screen-printed Zinc Oxide Particles Coated on the Cathode Surface on the Performance of Lithium-ion Batteries[J]. Materials Reports, 2022, 36(21): 21050056-5.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.21050056 OR http://www.mater-rep.com/EN/Y2022/V36/I21/21050056

1 Armand M, Tarascon J M. Nature, 2008, 451(7179), 652.
2 Bruce P G, Freunberger S A, Hardwick L J, et al. Nature Materials, 2011, 11(1), 19.
3 Cheng B X, Zhang R, Zhao C Z,et al. Chemical Reviews, 2017, 117(15), 10403.
4 Nitta N, Wu F, Lee J T, et al. Materials Today, 2015, 18(5), 252.
5 Zhao R, Yng Z, Chen J C, et al. Journal of Alloy & Compounds, 2015, 627, 206.
6 Gallus D R, Schmitz R, Wagner R, et al. Electrochimica Acta, 2014, 134, 393.
7 Han X, Ouyang M, Lu L,et al. Journal of Power Sources, 2014, 268(5),658.
8 Hu S K, Cheng G H, Cheng M Y, et al. Journal of Power Sources, 2009, 188(2), 564.
9 Kim H S, Kim Y, Kim S L, et al. Journal of Power Sources, 2006, 161(1), 623.
10 Johannes K,Marco E, Benjamin S, et al. The Journal of Physical Chemistry C, 2017, 121(3), 1521.
11 Jung S K, Gwon H, Hong J Y, et al. Advanced Energy Materials, 2014, 4(1), 1300787.
12 Tsai Y W, Hwang B J, Ceder G, et al. Chemistry of Materials, 2005, 17(12), 3191.
13 Liu S, Xiong L, He C. Journal of Power Sources, 2014, 261, 285.
14 Fujimoto T, Kitada K, Yamaura K, et al. ECS Meeting Abstracts, 2015, MA2015-02, 405.
15 Wang Z X, Sun Y C, Chen L Q, et al. Electrochemistry, 2004, 151(6), A914.
16 Lee G, Wu J, Kim D, et al. Angewandte Chemie Internatinal Edition, 2020, 59(22), 8681.
17 Zhu L, Xie L, Bao C, et al. International Journal of Energy Research, 2020, 44(1), 298.
18 Sun Q, Cheng H, Zhao K, et al. Chemistryselect, 2020, 5(4), 1275.
19 Li J, Liu Z, Wang Y, et al. Journal of Alloys Compounds, 2020, 834, 155150.
20 Zhang Z, Yu M, Yang B, et al. Materials Research Bulletin, 2020, 126, 110855.
21 Gao A, Sun Y, Zhang Q, et al. Journal of Materials Chemistry A, 2020, 8(13), 6337.
22 Kim Y, Kim H S, Martin S W. Electrochimica Acta, 2006, 52(3), 1316.
23 Wang J, He X, Kloepsch R, et al. Energy Technology, 2014, 2(2), 188.
24 Zhu J P, Xu Q B, Jun J Z, et al. Journal of Nanoscience & Nanotechnology, 2012, 12(3), 2534.
25 Babu G, Kalaiselvi N, Bhuvaneswari D. Journal of Electronic Materials, 2014, 43(4), 1062.
26 Bhuvaneswari D, Babu G, Kalaiselvi N. Electrochimica Acta, 2013, 109, 684.
27 Sun X L, Gong Q J, Liang Y X, et al. Materials Reports B:Research Papers, 2021, 35(4), 8001 (in Chinese).
孙晓玲, 弓巧娟, 梁云霞, 等. 材料导报:研究篇, 2021, 35(4), 8001.
28 Yang T, Hu X Y, Wang W L. Materials Reports B:Research Papers, 2021, 35(4), 8007 (in Chinese).
杨婷, 胡新宇, 王文磊. 材料导报:研究篇, 2021, 35(4), 8007.
29 Ren Y, Wang Y, Wang D Z, et al. Energy Story Science and Technology, 2019, 8(5), 935(in Chinese).
任雅, 王影, 王东征, 等. 储能科学与技术, 2019, 8(5), 935.
30 Zhuang Q C, Xu S D, Qiu X Y, et al. Progress in Chemistry, 2010, 22(6),1044(in Chinese).
庄全超, 徐守冬, 邱祥云, 等. 化学进展, 2010, 22(6), 1044.