Ti<sub>3</sub>AlC<sub>2</sub>陶瓷粉末的研究现状及进展

doi:10.11896/cldb.20090196

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Abstract Ternary layered Ti₃AlC₂, an important member of the MAX phases, attracted extensive attention due to its advantages of both metal and ceramic concurrently. As a potential functional and structural material, Ti₃AlC₂ has wide application prospects as high temperature structural materials, heat exchanger materials, corrosion-resistant components, low-friction-coefficient materials, electrical contact materials, nuclear fuel cladding materials, damage-sensitive parts and so on.
However, the synthesis window for Ti₃AlC₂ is quite narrow. At present, the in-situ reaction method is mostly used to prepare high-purity Ti₃AlC₂ bulk materials. The purity of the product prepared by this method is difficult to control, the appearance is simple, the size is small, and it is difficult to industrialize. In general, to manufacture the conventional ceramic materials, the corresponding high-purity ceramic powder is synthesized first, and then to prepare the required ceramic materials through different designs of the powder. So, the synthesis of high-purity Ti₃AlC₂ powder is vital for the manufacture of Ti₃AlC₂ ceramic materials.
In-depth and systematic research has been carried out on the synthesis of high-purity Ti₃AlC₂ ceramic powder. Currently, the main preparation methods include self-propagation high-temperature synthesis, pressureless sintering, mechanical alloying, mechanical alloying-heat treatment, molten salt, microwave sintering, etc., all of which can prepare micron or nano high-purity Ti₃AlC₂ powder. Among them, the pressureless sintering method has a simple process and a wide range of applications. Numerous studies have shown that adding additives such as Sn, Si, Ni and B₂O₃ can significantly reduce the synthesis temperature and increase the purity of the Ti₃AlC₂ phase in the product. Nano Ti₃AlC₂ powder with good dispersibility and high purity can be synthesized by molten salt method at a lower temperature, and its morphology and size are controllable. These two preparation methods are superior to others.
This paper reviewed the latest research progress of high-purity Ti₃AlC₂ powder. The preparation technology, synthesis mechanism, property comparison and future application of the Ti₃AlC₂ powder were summarized. Finally, the urgent problems in the Ti₃AlC₂ powder research were analyzed and discussed.

Key words： MAX phase Ti₃AlC₂ powder preparation technology synthesis mechanism

Published: Online: 2022-10-26

CLC number:

TF12

Fund:National Natural Science Foundation of China (51871180), National Key R & D Program of China (2021YFB3701203), Zhejiang Provincial Natural Science Foundation of China (LGG20E010004) and Taizhou Science and Technology Project (1902gy16).

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	GAO Lina
	CHEN Wenge
	LI Shufeng

Cite this article:

GAO Lina,CHEN Wenge,LI Shufeng. Research Status and Progress of Ti₃AlC₂ Ceramic Powder[J]. Materials Reports, 2022, 36(20): 20090196-11.

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http://www.mater-rep.com/EN/10.11896/cldb.20090196 OR http://www.mater-rep.com/EN/Y2022/V36/I20/20090196

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