稀土配合物-无机杂化发光材料研究进展

doi:10.11896/cldb.21050037

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Abstract The rare earth metal elements show excellent magnetic, optical and electrical properties due to their unique 4f sublayer electrons, which have rich energy level transitions under certain excitation conditions, but the 4f configuration transition of rare earth trivalent ions is parity forbidden. The luminescence intensity can be improved by introducing the rare earth ions into some crystal lattices or combining with organic ligands to form rare earth complex. Rare earth complexes are susceptible to the external environment and have relatively poor stability. It has great application potential to prepare high-performance rare earth hybrid luminescent materials through connecting organic ligands with inorganic matrix. In this paper, the research status of the hybridization processes of various inorganic substrates and rare earth complexes, including mesoporous silicon dioxide, zeolite, lithium saponite, graphene and its derivatives, and titanium dioxide, is reviewed in detail from the perspectives of structure composition, luminescence mechanism and synthesis methods. Then, the application progress of rare earth inorganic hybrid materials in silicon solar cells, LED luminescent materials, information security encryption, luminescent sensors and biological applications are introduced. Finally, the research direction prospect of rare earth inorganic hybrid technology are discussed. In the fucture, the microstructure composition and action mechanism of rare earth ion organic ligands and inorganic matrix should be further explored. Moreover, the design and assembly of organic ligands with good sensitization performance were studied, so as to realize the efficient utilization and functional development of rare earth inorganic hybrid materials, and realize industrial production as well.

Key words： rare earth complexes inorganic substrate hybrid luminescent materials graphene

Published: 10 October 2022 Online: 2022-10-12

CLC number:

TQ133.1

Fund:Shaanxi Provincial Science and Technology Innovation Project (2011KTDZ01-04-01), Innovation and Entrepreneurship Training Program for College Students of Shaanxi Province(S202113679009), and the 2020 Annual Special Scientific Research Project of Huaqing College of Xi'an University of Architecture and Technology (20KY02)

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	TANG Yangyang
	LI Linbo
	WANG Chao
	YANG Liu
	YANG Pan

Cite this article:

TANG Yangyang,LI Linbo,WANG Chao, et al. Research Progress of Rare Earth Complex-Inorganic Hybrid Luminescent Materials[J]. Materials Reports, 2022, 36(19): 21050037-9.

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http://www.mater-rep.com/EN/10.11896/cldb.21050037 OR http://www.mater-rep.com/EN/Y2022/V36/I19/21050037

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