利用碳纳米纤维/Pt纳米片构建柔性电极用于葡萄糖检测

doi:10.11896/cldb.21010143

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (4658KB)
Export: BibTeX | EndNote (RIS)

Abstract Diabetes is a metabolic disease characterized by hyperglycemia, which seriously threatens human health. Blood glucose monitoring plays an important role in the prevention, diagnosis and treatment of diabetes. The flexible carbon nanofibers were prepared by combination of electrospinning and heat treatment using polyacrylonitrile as the carbon source. Subsequently, the nonenzyme glucose sensor was constructed by loading Pt nanosheets directly on the surface of self-supporting carbon nanofibers by potentiostatic electrodeposition method. The results indicated that the surface of the nanofibers was smooth, and the Pt nanosheets gradually grew to fill the gap of carbon nanofibers. The length of single nanosheet was 100—200 nm, and the width was about 100 nm. The electrochemical results indicated that the linear detection range of the nonenzyme glucose biosensor electrode was 7.5—87.5 mmol/L with a low detection limit of 14.04 μmol/L and a sensitivity of 6.41 μA·(mmol/L)^-1·cm^-2. In addition, the sensor showed the excellent anti-interference ability, high repeatability and excellent storage stability. The fabricated sensor can combine the advantages of flexible electrode and nonenzyme sensor, and provides the possibility for the construction of flexible glucose sensor.

Key words： flexible nonenzymatic sensor carbon nanofibers electrospinning glucose platinum nanosheets

Published: 10 May 2022 Online: 2022-05-09

CLC number:

O657

Fund:Key Research and Development Project of Shanxi Province(201703D421019) and Applied Basic Research Project of Shanxi Province(201801D121281).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Jiaojiao
	WANG Xiaojun
	ZHANG Zhuoya

Cite this article:

ZHANG Jiaojiao,WANG Xiaojun,ZHANG Zhuoya. Construction of Flexible Electrode Using Carbon Nanofibers/Pt Nanosheets for Glucose Detection[J]. Materials Reports, 2022, 36(9): 21010143-6.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.21010143 OR http://www.mater-rep.com/EN/Y2022/V36/I9/21010143

1 Yu M, Zhao K, Zhu X, et al. Biosensors and Bioelectronics,2017,95,41.
2 Zhang Y, Yuan T, Li L, et al. Journal of Agricultural and Food Chemistry,2014, 62(28), 6687.
3 Wu W, Mitra N, Yan E C Y, et al. ACS Nano, 2010, 4(8), 4831.
4 Qiao F, Qi Q, Wang Z, et al. Sensors and Actuators B: Chemical, 2016, 229, 379.
5 Wang N, Han Z, Fan H, et al. RSC Advances,2015, 5(111), 91302.
6 Clark J L C, Lyons C. Annals of the New York Academy of Sciences,1962, 102(1), 29.
7 Updike S J, Hicks G P. Science, 1967, 158(3798), 270.
8 Keerthi M, Mutharani B, Chen S M, et al. Microchimica Acta, 2019, 186(12), 1.
9 Guo M Q. Fabrication and study of performance of nonenzymatic glucose sensor based on Pt-based micro-nano structure. Ph.D. Thesis, Tianjin University, China, 2012(in Chinese).
郭美卿. Pt基微纳结构无酶葡萄糖传感器的构建和性能研究. 博士学位论文, 天津大学, 2012.
10 Chen C, Ran R, Yang Z, et al. Sensors and Actuators B: Chemical, 2018, 256, 63.
11 Zhao H, Zhou C, Teng Y, et al. Applied Surface Science,2011, 257(8), 3793.
12 Chen H, Yuan R, Chai Y, et al. Biotechnology Letters,2010, 32(10), 1401.
13 Zhai D, Liu B, Shi Y, et al. ACS Nano, 2013, 7(4), 3540.
14 Liang J, Xi X, Ji W, et al. Material Sciences, 2019, 9(11), 984(in Chinese).
梁晶, 奚馨, 纪伟,等. 材料科学, 2019, 9(11), 984.
15 Bae C W, Toi P T, Kim B Y, et al. ACS Applied Materials & Interfaces,2019, 11(16), 14567.
16 Lee H, Song C, Hong Y S, et al. Science Advances,2017,3(3),e1601314.
17 Gao W, Emaminejad S, Nyein H Y Y, et al. Nature,2016,529(7587),509.
18 Rafatmah E, Hemmateenejad B. Sensors and Actuators B: Chemical, 2020, 304, 127335.
19 Xu W N. Study on flexible non-enzymatic biosensor based on oxide nanostructures directly grown on carbon fiber fabric. Master's Thesis, Chongqing University, China, 2016(in Chinese).
许伟娜. 基于碳布上生长氧化物纳米结构的柔性无酶生物传感器研究. 硕士学位论文,重庆大学, 2016.
20 Xu W, Dai S, Wang X, et al. Journal of Materials Chemistry B,2015, 3(28), 5777.
21 Cheng S, DelaCruz S, Chen C, et al. Sensors and Actuators B: Chemical, 2019, 298, 126860.
22 Cheng S, Gao X, DelaCruz S, et al. Journal of Materials Chemistry B, 2019, 7(32), 4990.
23 Liu F, Wang P, Zhang Q, et al. Analytical and Bioanalytical Chemistry,2018, 410(29), 7663.
24 Sun S, Shi N, Liao X, et al. Applied Surface Science,2020,529,147067.
25 Guzsvány V, Anojčić J, Radulović E, et al. Microchimica Acta, 2017, 184(7), 1987.
26 Ekabutr P, Chailapakul O, Supaphol P. Journal of Applied Polymer Science, 2013, 130(6), 3885.
27 Lee K B, Kim J R, Park G C, et al. Sensors, 2017, 17(1), 42.
28 Liu Z Y. Research and preparation of flexible micro-electrode with a dimensional nano-pillar arrays and its glucose sensor. Master's Thesis, Wuyi University, China, 2016(in Chinese).
刘忠银. 纳米柱阵列柔性微电极及其葡萄糖传感器的研究与制备. 硕士学位论文, 五邑大学, 2016.
29 Chen K, Chou W, Liu L, et al. Sensors, 2019, 19(17), 3676.
30 Zhang X, Liu D, Yu B, et al. Sensors and Actuators B: Chemical, 2016, 224, 103.
31 Li Y, Zhang M, Zhang X, et al. Nanomaterials, 2015, 5(4), 1891.
32 Guo J, Liu J, Dai H, et al. Journal of Colloid and Interface Science, 2017, 507, 154.
33 Liu Y, Jiang G, Sun S, et al. Journal of Electroanalytical Chemistry, 2017, 804, 212.
34 Joh H I, Song H K, Lee C H, et al. Carbon, 2014, 70, 308.
35 Zhao X, Nie G, Luan Y, et al. Journal of Alloys and Compounds, 2019, 808, 151737.
36 Zhang J, Su L, Ma L, et al. Journal of Electroanalytical Chemistry,2017, 790, 40.
37 Ju Y W, Choi G R, Jung H R, et al. Electrochimica Acta, 2008, 53(19), 5796.
38 Shim W G, Kim C, Lee J W, et al. Journal of Applied Polymer Science,2006, 102(3), 2454.
39 Friedlander H N, Peebles Jr L H, Brandrup J, et al. Macromolecules, 1968, 1(1), 79.
40 Yusof N, Ismail A F. Journal of Analytical and Applied Pyrolysis, 2012, 93, 1.
41 He W, Sun Y, Xi J, et al. Analytica Chimica Acta, 2016, 903, 61.
42 Sreekumar A, Navaneeth P, Suneesh P V, et al. Microchimica Acta, 2020, 187(2), 1.
43 Shu H, Cao L, Chang G, et al. Electrochimica Acta, 2014, 132, 524.
44 Zhao Y, Chu J, Li S H, et al. Electroanalysis, 2014, 26(3), 656.
45 Ridhuan N S, Nor N M, Razak K A, et al. Journal of Solid State Electrochemistry, 2021, 25(3), 1065.
46 Ming Z, Shang L, Li B, et al. Biosensors & Bioelectronics,2009,24,442.