不同类型锌卟啉自组装染料敏化太阳能电池

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Abstract Dye plays a key role in dye-sensitized solar cells. Designing a new photosensitizer is an effective strategy to improve the efficiency of self-assembled dye-sensitized solar cells. The most fundamental problem is the relationship between the structure of photosensitizer, the photoelectric properties of the assembled body and the photovoltaic performance. In this paper, two kinds of zinc porphyrin (ZnPx) with carboxyl group are introduced, and their coordination self-assembly double-layer dye-sensitized solar cells are studied. The results show that zinc porphyrin, a structure of ZnP1 (2+2), has better current and voltage, and shows a high efficiency of photoelectric conversion (η=1.68%). The self-assembly structure is also verified in this paper.

Key words： dye-sensitized solar cells coordination self-assembly electron donor zinc porphyrin photosensitizer

Published: 09 December 2021

CLC number:

O614.24⁺1

Fund:This work was financially supported by Science and Technology Fund Project of Guizhou Provincial Science and Technology Department (QianKeHe-ZK〔2021〕064), Natural Science Foundation of Guizhou Education Department, (QianJiaoHe KY Zi 〔2020〕200,〔2020〕203), Major Projects of Research and Innovation Fund of Qiannan Normal University for Nationalities (QNSY2018BS020) and School Level Project of Qiannan Normal University for Nationalities (qnsy201503).

About author:: Yu Wu received his Ph.D. degree of science from the Northwest Normal University in Jun.2017 and joined Qiannan Normal University for Nationalities as a teacher after graduation. He is currently an associate professor and master supervisor. He has published more than 20 journal papers as the first author, applied 3 national invention patents and 1 of them was authorized. His research interests focus on porphyrin coordination self-assembled dye sensitized solar cells, and carries out research on functional complexes and basic chemistry education and teaching.

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Cite this article:

WU Yu,LIU Jiacheng. Novel Self-assembly Dye-sensitized Solar Cells: Using Different Types of Electron Donor Zinc Porphyrin[J]. Materials Reports, 2021, 35(z2): 479-482.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/Iz2/479

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