钙钛矿量子点与金属有机框架复合材料的研究进展

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Abstract Perovskite quantum dots (PVK QDs) have the advantages of high visible light response intensity, luminescence purity and quantum efficiency, which have broad application prospects in the field of optoelectronics. But its crystal structure is vulnerable under the existence of light, heat, water, and oxygen. Metal organic frameworks (MOFs) are porous material with large specific surface area and adjustable pore structure, which have high environmental stability. By embedding perovskite quantum dots into the channels of the metal organic frameworks, the stability of perovskite quantum dots and the optical properties of MOFs can be improved at the same time. In this paper, four main synthesis methods of pe-rovskite quantum dots and metal organic framework composites in recent years have been reviewed, including the template method, in-situ growth method, post synthesis method, and mechanochemical method. And the advantages and disadvantages of these preparation methods are compared. In addition, the working mechanism of composite materials in the fields of solar cells, LEDs, carbon dioxide reduction (CO₂RR), sewage treatment, and information encryption are discussed from the perspective of application. Finally, the industrialization prospect of perovskite quantum dots and metal organic framework composites prepared by green mechanochemical method and the problems to be solved in the practical application of the composites are analyzed and prospected.

Key words： perovskite quantum dots metal organic framework composite material green mechanochemical method application

Published: 09 December 2021

CLC number:

TB331

Fund:This work was financially supported by the Research Fund Program of Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology (2020B1212060022), Natural Science Foundation of Guangdong Province(2019A1515011344).

About author:: Sitong Feng received her B.S. degree from Guangdong University of Technology in June 2020. She is currently pursuing her master's degree in the School of Chemical Engineering and Light Industry, Guangdong University of Technology, under the supervision of professor Chuande Wu. Her research is currently focusing on preparation of the composite of perovskite quantum dot and metal organic frameworks and their application in photothermal catalysis.
Shaojuan Luo is an associate professor and postgra-duate supervisor in the School of Chemical Engineering and Light Industry, Guangdong University of Technology. In August 2014, she received her Ph.D. degree in Chemical and Biomolecular Engineering from Hong Kong University of Science and Technology. From 2014 to 2018, she was appointed as a visiting scholar to Hong Kong University of Science and Technology, Nanyang Technological University and Shenzhen University. She has mainly been engaged in research on modification and applications of two-dimensional nanomaterials, development of self-healing substrates and device preparation, development, mechanism and application of hierarchical porous silicon-based molecular sieves and MOFs. She has been responsible for the National Natural Science Foundation of China, the Natural Science Foundation of Guangdong Province, and the Hong Kong Science and Technology Innovation Fund and published more than 30 SCI in peerreviewed journals.
Chuande Wu is a full professor and doctoral supervisor in the Department of Chemistry,Zhejiang University. In July 2003, he received his Ph.D. degree in Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. In September 2003, he went to the University of North Carolina at Chapel Hill to do postdoctoral research, mainly engaged in the synthesis of chiral porous MOFs and the application of asymmetric catalysis. In 2005, he worked as an introduced professor in the Department of Chemistry of Zhejiang University, engaged in the design, synthesis and application of porous MOFs. He has mainly been engaged in hybrid materials in which organic ligands and polyacid ligands bridge transition metal ions or rare earth ions, and synthesis, structure and properties of porous MOFs with mixed organic ligands bridging transition metal ions or rare earth ions. He has published more than 160 papers in Acc. Chem. Res.、J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater, and other journals, and has been cited more than 4,000 times. He was selected in the Elsevier 2014, 2015, 2016, and 2017 "China's Highly Cited Scholars List", and received funding from Zhejiang Outstanding Youth Fund, National Outstanding Youth Fund, etc.

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	FENG Sitong
	WANG Linjie
	OU Jinfa
	LUO Shaojuan
	YAN Kai
	WU Chuande

Cite this article:

FENG Sitong,WANG Linjie,OU Jinfa, et al. Recent Advances in the Composites of Perovskite and Metal Organic Framework[J]. Materials Reports, 2021, 35(z2): 298-305.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/Iz2/298

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