POLYMERS AND POLYMER MATRIX COMPOSITES |
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Mechanical Properties and Corrosion Mechanism of the FN04Mo on 7 Kinds of Typical Atmospheric Environment |
SUN Youmei1,2,3, ZHAO Quancheng1,4, LI Qian1,2, WANG Ling1,3, SHE Zuxin1,3, WANG Changpeng1,4
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1 Southwest Institute of Technology and Engineering, Chongqing 400039, China 2 Hainan Wanning Atmospheric Material Corrision Field National Observation and Research Station, Wanning 571522, China 3 Chongqing Key Laboratory of Environmental Effect and Protection, Chongqing 400039, China 4 CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China |
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Abstract In this paper, FN04Mo was prepared by metal injection molding. The mechanical properties and corrosion mechanisms of FN04Mo under se-ven typical atmospheric conditions at Wanning Station, Mohe Station, Dunhuang Station, Lasa Station, Jiangjin Station, Xishuangbanna Station, and Yongxing Station were investigated using electro-hydraulic servo tester, X-ray diffraction analysis, scanning electron microscopy, and energy spectrum analyzer. The results showed that mechanical properties of FN04Mo at the initial stage of corrosion (1—3 months) appeared a significant decreasing trend and remained stable after 3—18 months. After 1 year exposure test in the seven typical atmospheres, the surface of FN04Mo was covered with corrosion products and the surface corrosion pattern is pitting. The SO2-rich industrial atmosphere (Jiangjin) is the most corrosive. The corrosion products of the samples exposed for 1 year in Jiangjin are α-FeOOH、γ-FeOOH and Fe3O4, while the corrosion products of the samples exposed for 9 months in Yongxing are β-FeOOH、γ-FeOOH、Fe3O4 and FeOCl. The two atmospheric pollutants, the aggressive Cl- and polar SO2, aggravated the corrosion of the FN04Mo matrix in the atmospheric environment. The formation of corrosion pro-ducts and delamination of the FN04Mo sample after atmospheric exposure reduced its effective bearing area and led to significant changes in its mechanical properties.
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Published: 30 September 2021
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Fund:This work was financially supported by the Technical Basic Scientific Research Project(JSHS2017209B001). |
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