石墨烯/硅肖特基结太阳能电池的研究进展

doi:10.11896/cldb.19120150

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Abstract Solar cells directly convert light energy into electricity by photovoltaic effect, which can effectively solve future energy crisis and environmental pollution, and conform to the concept of sustainable development. Traditional silicon-based solar cells need high-temperature process, which is complex, and the cost of power generation can not compete with thermal power and hydropower. In order to solve these problems, researchers have developed many novel solar cells in recent years to reduce the manufacturing cost. Among them, graphene/silicon Schottky junction solar cells with graphene as transparent electrode are considered as a new generation of low-cost and high-efficiency solar cells.
However, the efficiency of graphene/silicon Schottky junction solar cells are much lower than that of traditional silicon-based solar cells due to its low work function, high sheet resistance, serious recombination of charge carriers along the interface, and high plane silicon reflectivity. Therefore, in recent years, the main research focuses on the graphene doping modification, suppressing carrier recombination at the interface and the reduction of reflectivity of devices. At present, the photoelectric conversion efficiency (PCE) of graphene/silicon Schottky junction solar cells has increased from 1.65% to 16.61%.
At present, the successful application of graphene dopants to improve the performance of devices mainly includes HNO₃, metal nanoparticles, bis(trifluoromethanesulfonyl)-amide(TFSA) and so on. Among them, HNO₃ is the most widely used, but its stability is poor. Physical doping such as metal nanoparticles can simultaneously improve the PCE and stability of the device. The introduction of Al₂O₃, MoS₂, quantum dots and other interface layers and surface passivation between graphene and silicon can effectively reduce the suspended bonds on the silicon surface and inhibit carrier recombination, so as to improve the performance of devices. In addition, by introducing antireflective films such as TiO₂, PMMA, MgF₂/ZnS on the surface of graphene, or introducing microstructures such as nanowires and porous silicon on the surface of silicon, the researchers can reduce the reflectivity of the device and improve the utilization of light.
In this paper, the research progress of graphene/silicon solar cells in recent years is summarized, and the structure and principle of the device are briefly introduced, with emphasis on graphene doping, graphene layer selection, nano or micro structure of silicon, antireflection film and interface optimization. The problems and prospects of commercialization of graphene/silicon Schottky junction solar cells are analyzed, in order to provide some reference for the preparation of novel graphene/silicon Schottky junction solar cells with high efficiency and strong stability.

Key words： graphene silicon Schottky junction solar cells interface layer

Published: 31 May 2021

CLC number:

TM914.4

Fund:National Natural Science Foundation of China(61764009, 51762043, 51974143), National Key R&D Program of China(2018YFC1901801, 2018YFC1901805), Major Science and Technology Projects in Yunnan Province (2019ZE007), Key Project of Yunnan Province Natural Science Fund(2018FA027).

About author:: Jiasen Liu graduated from Chongqing Jiaotong University in June 2018 with a bachelor's degree in materials science and engineering. He is now a postgraduate student in Yunnan University, conducting research under the guidance of professor Xiuhua Chen. At present, the main research field is graphene-based silicon solar cells.
Xiuhua Chen, Ph.D., professor, School of Materials Science and Engineering, Yunnan University, gradua-ted from mineral processing engineering, department of resource development, Kunming University of Science and Technology in 2001. From 2002 to 2004, she was engaged in post-doctoral research on ULSI-Cu interconnect layer materials in materials engineering, University of Tokyo, Japan. At present, she is mainly engaged in the research and development of new energy environment materials and solar silicon battery materials.

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	LIU Jiasen
	CHEN Xiuhua
	LI Shaoyuan
	MA Wenhui
	LI Yi
	HU Huanran
	MA Zhuang

Cite this article:

LIU Jiasen,CHEN Xiuhua,LI Shaoyuan, et al. Research Progress of Graphene/Silicon Schottky Junction Solar Cells[J]. Materials Reports, 2021, 35(9): 9115-9122.

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http://www.mater-rep.com/EN/10.11896/cldb.19120150 OR http://www.mater-rep.com/EN/Y2021/V35/I9/9115

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