苯并噁嗪树脂的研究新进展:智能化应用及能源、环境领域应用

doi:10.11896/cldb.20030056

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Abstract Benzoxazine resin is a kind of high-performance thermosetting resin. Because of its high thermal stability, high char yield, flame retardant, low water absorption, low shrinkage, limited or no by-products during curing, and good mechanical properties, it has become an effective substitute for phenolic resin, bismaleimide resin and other high-performance polymers and been widely used in aerospace, electronic circuit board, blends and alloys industry.
Although benzoxazine resins are widely used in several applications, the research of polybenzoxazine mainly focuses on the synthesis of composite materials and the substitution of traditional epoxy resin and phenolic resin. Because polybenzoxazine contains unique molecular structures such as tertiary amines and phenolic hydroxyl groups that can form hydrogen bonds, and has high flexibility in molecular design, its application potential in many emerging fields also deserves attention. In terms of intelligent application, electrochemically active coatings and hydrophobic surfaces can be easily obtained from polybenzoxazine; and self-healing function can be imparted to benzoxazine resin by virtue of the supramolecular structure of polybenzoxazine and its precursors; in addition, shape memory polymer, near infrared (NIR) and polychromatic electrochromic materials can also be constructed based on benzoxazine resin. In the fields of energy and environment, benzoxazine resin can be used to adsorb metal ions in water due to the metal binding ability of N and O atoms or functional groups such as mercaptans and carboxylic acids; moreover, sulfur-containing benzoxazine resin also can be used as positive electrode of lithium-sulfur battery.
In this paper, the intelligent application of polybenzoxazine materials and their applications in the energy and environmental fields are reviewed, and the relationship between the properties and structures of polybenzoxazine is discussed.

Key words： polybenzoxazine self-healing hydrophobic surface smart materials shape memory polymer lithium-sulfur battery electrochromic material

Published: 19 February 2021

CLC number:

TQ311

Fund:This work was financially supported by Chongqing Technology Innovation and Application Development Project (cstc2019jscx-msxmX0050), Science and Technology Research Project of Chongqing Education Committee (KJQN201900829), Innovation Group of New Technologies for Industrial Pollution Control of Chongqing Education Commission (CXQT19023), Open Fund of Chongqing Key Laboratory of Catalysis and New Environmental Materials (CQCM-2017-02), and Youth Project of Chongqing Technology and Business University (1952015).

About author:: Xiaodan Li received her B.E. degree in polymer material from Sichuan University in 2007 and received her Ph.D. degree in polymer science and engineering from Sichuan University, College of Polymer Science and Engineering, in 2012. After two-year postdoctoral research at Sichuan University, she is currently a full associate professor in Chongqing Technology and Business University. Her research interests are functional polymer materials, nanocomposites and environmental functional materials, especially the theories and applications of high performance benzoxazine resin.

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	LI Xiaodan
	HU Xinyu
	LIU Xiaoping
	LIU Xiaoqing
	SHEN Yu
	TANG Ying
	FENG Jiacheng

Cite this article:

LI Xiaodan,HU Xinyu,LIU Xiaoping, et al. A Review on the New Development of Benzoxazine Resin: Use in Smart Materials and Energy and Environmental Applications[J]. Materials Reports, 2021, 35(3): 3209-3218.

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http://www.mater-rep.com/EN/10.11896/cldb.20030056 OR http://www.mater-rep.com/EN/Y2021/V35/I3/3209

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