锰基氧化物上甲苯催化氧化的研究进展

doi:10.11896/cldb.20070096

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Abstract The control of volatile organic compounds (VOCs) has attracted attention in both academic and industrial communities. Catalytic oxidation is considered to be one of the most promising methods for the removal of VOCs due to the high efficiency, low reaction temperature and low cost. The catalytic removal of toluene, which is one of the typical VOCs, is very important for the control of VOCs. Catalyst plays a key role for the catalytic oxidation of toluene. Considering the good redox property, high hydrothermal stability and the low cost of MnO_x, many researchers have conducted intensive study on the catalytic oxidation of toluene over MnO_x-based catalysts.
MnO_x-based catalysts can be classified into heterogeneous MnO_x, transition metal-doped MnO_x and supported MnO_x. For the heterogeneous MnO_x, such as α@β-MnO₂, the advantages of different MnO_x phase can be made full use of. In addition, more oxygen vacancies are generated in the phase interface, promoting the oxygen flow and thereby improving the reaction efficiency. Introduction of transition metals to MnO_x would contribute to the electron transfer between metals and enhance the oxygen mobility of the catalyst, thus enhancing the redox property. In the case of supported MnO_x the strong metal-support interaction is beneficial for the improvement of the catalytic performance. Morphology control and the acid treatment of MnO_x-based catalysts can also lead to improved activity by regulating the specific surface area, the active oxygen species and the redox ability of the catalysts. The oxidation of toluene on the MnO_x-based catalyst follows Mars-van Krevelen (MVK) or Langmuir-Hinshelwood(L-H) mechanism. For both mechanisms the intermediate with an aromatic ring is formed.
In this review, the types of MnO_x catalysts, influencing factors and mechanism of the catalytic oxidation of toluene over manganese-based oxide have been summarized and discussed. And the perspective on MnO_x-based catalysts for the catalytic oxidation of toluene has been proposed.

Key words： manganese-based oxide toluene catalytic oxidation

Published: 24 December 2020

CLC number:

X701

Fund:This work was financially supported by the National Key R&D Program of China (2017YFC0210700)

About author:: Ke Yin received her B.E. degree in Shandong University of Science and Technology in 2018. She is currently pursuing her M.E. at the Beijing University of Chemical Technology (BUCT), and is studying under the supervision of Prof. Zhiming Liu. Her research has focused on catalytic oxidation of benzene and toluene.
Zhiming Liu received his Ph.D. degree at Tsinghua University in 2004. He successively worked as a post-doctoral fellow in Korea Advanced Institute of Science and Technology (KAIST) (2004—2006), University of Alberta (2006) and Clemson University (2007—2008). In 2008 he joined in Beijing University of Chemical Technology. His research is focused on the environmental catalysis and air pollution control. He was selected as the Excellent Young Scholar of Fok Ying Tung Education Foundation in 2010 and New Century Excellent Talents of the Chinese Ministry of Education in 2013.

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Cite this article:

YIN Ke,CHEN Ruiyang,LIU Zhiming. Catalytic Removal of Toluene Over Manganese-Based Oxide Catalysts[J]. Materials Reports, 2020, 34(23): 23051-23056.

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http://www.mater-rep.com/EN/10.11896/cldb.20070096 OR http://www.mater-rep.com/EN/Y2020/V34/I23/23051

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