Materlals and Sustainable Development:Environment-Friendly Materials and Materials for Environmental Remediation |
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Research Progress of Hydrogen Permeable Membrane of 5B Group (Nb,V and Ta) Alloys |
CHEN Yuncan1, YAN Erhu1,*, DI Chongbo1, WANG Jinhua1, HUANG Haoran1,2, WANG Hao1, LIU Wei1, XU Fen1, SUN Lixian1
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1 Guangxi Key Laboratory of Information Laboratory, Guilin University of Electronic Technology, Guilin 541004, China 2 School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China |
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Abstract Hydrogen is a clean energy carrier with sustainable development, which has the advantages of high calorific value and zero pollution, and has become the focus of global scramble to explore in recent years. The hydrogen produced by the traditional hydrogen preparation technology (e.g. Natural gas steam reforming to produce hydrogen) contains different levels of impurity gas. Therefore, hydrogen permeation (or hydrogen purification) technology has become an important part of the preparation of pure hydrogen. Palladium and its alloys have been successfully developed in the past 30 years, but they are too expensive. So it is urgent to develop some new type of hydrogen permeable membranes which are not only inexpensive but also possess an excellent hydrogen permeability. To resolve above problem, 5B group metals (Nb, V and Ta) and their alloy membranes have attracted much attention due to their low price and high hydrogen permeability. And scholars from various countries have carried out a lot of research work. In this paper, we firstly summarize the development process of the above alloy membranes in the past ten years, and different alloy systems are also discussed, respectively. Secondly, the preparation process of the alloy membranes is analyzed and compared, and its influence on the hydrogen permeation performance of these alloys is described. Finally, the key factors affecting the hydrogen permeability of the above alloy membranes are summarized, and the prosperous future of these alloys in hydrogen separation studies is expected.
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Published: 17 November 2020
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Fund:This work was supported by National Natural Science Foundation of China (51761009,51701048), the Innovation Project of Guet Graduate Education (2019YCXS109), the Guangxi Key Laboratory of Information Laboratory (191021-Z). |
About author:: Yuncan Chen received his B.E. degree in material for-ming and control engineering from Guilin University of Electronic Technology in 2018. He is currently pursuing his M.E. at the School of Materials Science and En-gineering, Guilin University of Electronic Technology under the supervision of Prof. Erhu Yan. His research has focused on new types of hydrogen permeably alloys/theory of solidification of multicomponent alloys. Erhu Yan is an associate professor at Guilin University of Electronic Technology of China. He received his B.E. degree from Hebei University of Science and Technology, and received his M.E. and Ph.D. degrees from Harbin Institute of Technology in 2011 and 2014, respectively. He is working at Guilin University of Electronic Technology after graduation. He worked as a visiting research fellow at Institut National de la Recherche Scientifique (INRS)-Energy, Materials and Telecommunications of Canada from November 2018 to November 2019. He is currently focusing on research in theory of alloys directional solidification/new energy materials and devices, including research on phase diagram thermodynamics and solidification beha-vior of multicomponent alloys, development and application of new hydrogen permeably/hydrogen storage alloy materials and their devices. |
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