高铁酸盐在环境修复中的应用综述

doi:10.11896/cldb.19100238

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Abstract Ferrate (Fe(Ⅵ)) has been widely employed due to its oxidant/disinfectant and further utilization of the ensuing Fe(Ⅲ) oxides/hydroxide as coagulants in environmental remediation. Therefore, this review diverse synthesis recipes for Fe(Ⅵ) and their associated physicochemical properties as oxidants, coagulants, and disinfectants for the elimination of a diverse range of chemical and biological species from water/wastewater samples. These introduces involve: (1) Preparation and characteristics of ferrate. (2) The role of pH in the kinetics of the reactions and in determining the removal efficiency of pollutants is highlighted; the rates of competing reactions of Fe(Ⅵ) with itself, water, and the contaminants, which are highly pH dependent, determine the optimum pH ranges of maximum efficacy. (3) Oxidation mechanism of Fe(Ⅵ) through 1-e^- and 2-e^- transfer processes and further reactions of Fe(Ⅴ) and Fe(Ⅳ) with contaminants; the reduction products Fe(Ⅴ) and Fe(Ⅳ) can continue to react with pollutants through 1-e^- and 2-e^- electron transfer; cyanide has been studied for the comparative oxidizing capability of ferrates in various oxidation states. The result suggests the rates for the reactivity of ferrates with cyanide to be Fe(Ⅴ)>Fe(Ⅳ)>Fe(Ⅵ). (4) Fe(Ⅵ) can oxidize cell wall, protoplasm, DNA and other vital microorganism organs which kills them immediately. Meanwhile, Fe(Ⅵ) is gradually converted to Fe(Ⅲ) which is a strong coagulant, therefore, colloidal particles including the microorganisms are coagulated and removed from the water. (5) The high reactivity of most EDCs and PPCPs with ferrate(Ⅵ) may be attributed to electron donation by the specific group to the naphthalene moiety. (6) Ames and zebrafish embryos test indicate that Fe(Ⅵ) do not produce mutagenic by products for the study conditions. These results will make it possible to unlock the true potential of ferrates for degrading emerging toxins and pollutants, and in the purified and potable water for humanity in the 21st.

Key words： ferrate water remediation oxidant disinfection coagulants

Published: 05 November 2020

CLC number:

X703

Fund:This work was financially supported by the National Natural Science Foundation of China(41673092,41472038), the Science and Technology Project of Guangdong Province(2016B020242004), the Science and Technology Project of Guangzhou City(201604020064) and the Guangdong Special Support Program for Millions of Leading Engineering Talents(201626011).

About author:: Yihao Li received his MFA in Environmental Biotechnology from Donghua University in 2017. He is currently pursuing his Ph.D. at the School of Environment and Energy, South China University of Technology under the supervision of Prof. Pingxiao Wu. His research has focused on the application of ferrate in environmental remediation.
李义豪,2017年3月毕业于东华大学,获得工学硕士学位。现为华南理工大学环境与能源学院博士研究生,在吴平霄教授的指导下进行研究。目前主要研究方向为高铁酸盐在环境修复中的应用。

Pingxiao Wu received his B.S., M.S., and Ph.D. degrees from Nanjing University, China University of Geosciences and Guangzhou Institute of Geochemistry, Chinese Academy of Sciences in 1990, 1995, and 1998, respectively. After two-year postdoctoral research at South China Agricultural University, he is currently a full professor in South China University of Technology. His research focuses on the application of functional clay minerals in environmental remediation. In recent years, numerous research papers have been published in top journals, including Applied Catalysis B: Environmental, Environment International, Journal of Hazardous Materials, Chemical Engineering Journal, Science of the Total Environment, etc.

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Cite this article:

LI Yihao,WU Pingxiao,JIANG Lu, et al. Progress on Application of Ferrate(Ⅵ) for the Environmental Remediation[J]. Materials Reports, 2020, 34(19): 19003-19009.

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http://www.mater-rep.com/EN/10.11896/cldb.19100238 OR http://www.mater-rep.com/EN/Y2020/V34/I19/19003

1 Sharma V K, Zboril R, Varma R S. Accounts of Chemical Research,2015,48(2),182.
2 Jiang J Q. Journal of Hazardous Materials,2007,146(3),617.
3 Ghernaout D, Naceur M W. Desalination and Water Treatment,2011,30(1-3),319.
4 Yates B J, Zboril R, Sharma V K. Journal of Environmental Science and Health Part a-Toxic/Hazardous Substances & Environmental Engineering,2014,49(14),1603.
5 Deng J, Wu H D, Wang S J, et al. Environmental Technology,2019,40(12),1585.
6 Jiang J Q, Lloyd B. Water Research,2002,36(6),1397.
7 Chen J, Qi Y M, Pan X X, et al. Water Research,2019,158,338.
8 Sharma V K. Coordination Chemistry Reviews,2013,257(2),495.
9 Yang T, Wang L, Liu Y, et al. Environmental Science & Technology,2018,52(22),13325.
10 Luo C, Feng M, Sharma V K, et al. Environmental Science & Technology,2019,53(9),5272.
11 Ghosh M, Manoli K, Renaud J B, et al. Chemosphere,2019,230,416.
12 He H, Liu Y, Wang X, et al. Chemical Engineering Journal,2018,343,520.
13 Xie Sitao, Wu Kehong, Tang Zhijian. Journal of Environment and Health,2001,18(3),190(in Chinese).
谢思桃,吴克宏,唐志坚.环境与健康杂志,2001,18(3),190.
14 Stahl G E. Halae-Magdeburgiae,1702,742.
15 Fremy E C R. Académie des Sciences, Paris,1841,12,23.
16 Thompson G W, Ockerman L T, Schreyer J M. Journal of the American Chemical Society,1951,73,1379.
17 Licht S, Wang B H, Ghosh S. Science,1999,285(5430),1039.
18 Bouzek K, Rousar I. Journal of Applied Electrochemistry,1997,27(6),679.
19 Bouzek K, Schmidt M J, Wragg A A. Electrochemistry Communications,1999,1(9),370.
20 Wood R H. Journal of the American Chemical Society,1958,80(9),2038.
21 Nowik I, Herber R H, Koltypin M, et al. Journal of Physics and Chemistry of Solids,2005,66(7),1307.
22 Ettl V, Veprek-Siska J. Collection of Czechoslovak Chemical Communications,1969,34,2182.
23 Gai Y C. In: The 4^th Joint China/Japan Chemical Engineering Sympo-sium. Chengdu, China,2007,pp.19.
24 Gai Yongcai. Preparation of potassium ferrate(VI) and its application in DNBP treatment. Master's Thesis, Dalian University of Technology, China,2008(in Chinese).
盖永才,高铁酸盐的合成及在氧化降解DNBP中的应用.硕士学位论文,大连理工大学,2008.
25 Schreyer J M, Thompson G W, Ockerman L T. Journal of the American Chemical Society,1950,22,1426.
26 Sharma V K. Abstracts of Papers of the American Chemical Society,2000,219,U619.
27 Venkatadri A S, Wagner W F, Bauer H H. Analytical Chemistry,1971,43,1115.
28 Macova Z, Bouzek K, Hives J, et al. Electrochimica Acta,2009,54(10),2673.
29 Licht S, Naschitz V, Halperin L, et al. Journal of Power Sources,2001,101(2),167.
30 Luo Z, Strouse M, Jiang J Q, et al. Journal of Environmental Science and Health Part a-Toxic/Hazardous Substances & Environmental Engineering,2011,46(5),453.
31 Lee Y, Cho M, Kim J Y, et al. Journal of Industrial and Engineering Chemistry,2004,10(1),161.
32 Lee Y, Yoon J, Von G U. Water Research,2005,39(10),1946.
33 Mura S, Malfatti L, Greppi G, et al. Reviews in Environmental Science and Bio-Technology,2017,16(1),15.
34 Huang R F, Wang C J, Chelme-Ayala P, et al. Science of the Total Environment,2019,672,906.
35 Sharma V K, Rendon R A, Millero F J, et al. Marine Chemistry,2000,70(1-3),235.
36 Sharma V K, Burnett C R, O'Connor D B. Abstracts of Papers of the American Chemical Society,2000,220,U359.
37 Sharma V K. Journal of Environmental Science and Health Part a-Toxic/Hazardous Substances & Environmental Engineering,2010,45(6),645.
38 Sharma V K, Graham N J D, Li X Z, et al. Environmental Science and Pollution Research,2010,17(2),453.
39 Sharma V K, Rivera W, Joshi V N, et al. Environmental Science & Technology,1999,33(15),2645.
40 Sharma V K. Journal of Environmental Management,2011,92(4),1051.
41 Lee Y, Zimmermann S G, Kieu A T, et al. Environmental Science & Technology,2009,43(10),3831.
42 Wang H, Zhang R, Li H, et al. Water Environment Research : a Research Publication of the Water Environment Federation,2019,91(7),628.
43 Aryal M, Ziagova M M. Liakopoulou K. Chemical Engineering Journal,2011,169(1-3),100.
44 Xie X, Cheng H. Environment International,2019,127,730.
45 Huang Z S, Wang L, Liu Y L, et al. Environmental Science & Technology,2018,52(23),13897.
46 Jiang Y, Goodwill J E, Tobiason J E, et al. Environmental Science & Technology,2015,49(5),2841.
47 Talaiekhozani A, Fulazzaky M A, Ponraj M, et al. Desalination and Water Treatment,2014,52(19-21),3663.
48 Robinson R K. Water Research,1974,8,543.
49 Talaiekhozani A, TalaeiS M R, Rezania S. Journal of Environmental Chemical Engineering,2017,5(2),1828.
50 Mattice J S, Zittel H E. Journal-Water Pollution Control Federation,1976,48(10),2284.
51 Rai P K, Lee J, Kailasa S K, et al. Environmental Research,2018,160,420.
52 Jiang J Q. In: 2013 International Symposium on Environmental Science and Technology. Dalian, China,2013.
53 Lee Y, Von G U. Water Research,2010,44(2),555.
54 Lee Y, Yoon J, Von G U. Environmental Science & Technology,2005,39(22),8978.
55 Vanden B K, Verheyen R, Witters H. Science of the Total Environment,2003,309(1-3),127.
56 Sharma V K, Sohn M, Anquandah G A K, et al. Chemosphere,2012,87(6),644.
57 Shao B, Dong H, Sun B, et al. Environmental Science & Technology,2019,53,894.