MFI型分子筛在VOCs去除领域的研究进展

doi:10.11896/cldb.19110003

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Abstract Volatile organic compounds (VOCs) do great harm to both the environment and human health and therefore it is urgent to develop new technologies for VOCs removal. Commonly, the treatment methods of VOCs include adsorption, biological, absorption, condensation and catalytic combustion, etc. In recent years, the treatment route of combining both adsorption and catalytic combustion was proposed, aiming at the treatment of VOCs with low concentration, large air volume and low temperature produced in industrial production.
Adsorbent is the key for the adsorption technology. The common adsorption materials contain activated carbon, silica gel, molecular sieves, etc. Among them, zeolites with MFI topology have been widely used in the field of VOCs removal due to the special pore structure and adjustable Si/Al ratio. MFI zeolite mainly includes ZSM-5, Silicalite-1 and TS-1 according to the different compositions. As an adsorbent, the adsorption results of different VOCs have been influenced by its pore structure and surface properties. In the industrial purification process, the water in VOCs greatly reduces the adsorption capacity of zeolites. Therefore, in recent years, except for studying to improve the saturated adsorption capacity of zeolites for VOCs, the researchers paid more and more attention to improving the adsorption capacity of adsorbents under humid atmosphere. Generally, methods of increasing the silicon-alumina ratio and by surface silanization modification are applied to increase the adsorption perfor-mance of MFI-type zeolites in humid conditions.
MFI-type zeolites can also be used as catalyst supports. For the supported catalyst, both the active components and supports properties determine the VOCs removal efficiency of catalysts. The VOCs catalytic oxidation performance of catalysts can be effectively improved by choosing appropriate composite active components, suitable support structures as well as superior catalyst preparation methods.
In this paper, the main research results and progress of MFI-type zeolites applied in the field of VOCs removal were summarized. In detail, the structure, properties of MFI-type zeolites as well as their application in VOCs removal via adsorption or catalytic oxidation technology were illustrated. Based on these, the application prospect of MFI-type zeolites is analyzed and prospected, according to the emission characteristics of industrial VOCs sources.

Key words： MFI-type zeolites volatile organic compound adsorption catalytic oxidation

Published: 02 September 2020

CLC number:

X511

Fund:Beijing Science and Technology Planning Project (Z181100005418008), the Fundamental Research Funds for the Central Universities (FRF-TP-18-011A3), the National Natural Science Foundation of China (21876010), Special Program for Guiding Local Science and Technology Development by the Central Government (19943816G)

About author:: Yongchao Feng graduated from Hebei University of Science and Technology in June 2018 with a bachelor degree in engineering. He is currently a graduate student in the School of Energy and Environmental Engineering, University of Science and Technology Beijing, under the supervision of Prof. Honghong Yi. His research has focused on the MFI-type zeolites adsorption-catalytic removal of VOCs.
Honghong Yi, Professor of the School of Energy and Environmental Engineering, University of Science and Technology Beijing. She mainly engaged in the collaborative purification of gaseous pollutants and the research of typical VOCs purification technology. She is selected as new century outstanding talents of the ministry of education, reserve talent for young and middle-aged academic and technical leaders in Yunnan Province. She was awarded the first prize of Yunnan Technology Invention, the second prize of China Nonferrous Metals Industry Science and Technology, and the China Environmental Science Society Youth Science and Technology Award. She has presided over more than 10 key projects of the National Natural Science Foundation of China, the National 863 Program Key Project, the Beijing Science and Technology Plan Project, and the Hebei Science and Technology Support Program. She has published more than 170 SCI papers; published 6 papers; she is also a member of the Working Committee of the Technical Experts of the China Nonferrous Metals Society, and a member of the editorial board of Environmental Engineering.

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	FENG Yongchao
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	ZHANG Yuanyuan
	ZHUANG Ruijie

Cite this article:

FENG Yongchao,YU Qingjun,YI Honghong, et al. Research Progress of MFI-type Zeolites in the Field of VOCs Removal[J]. Materials Reports, 2020, 34(17): 17089-17098.

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http://www.mater-rep.com/EN/10.11896/cldb.19110003 OR http://www.mater-rep.com/EN/Y2020/V34/I17/17089

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