类玻璃高分子材料的研究进展

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Abstract Polymer materials have become an indispensable material in modern production and life, thermosetting materials have better performance than thermoplastic materials due to the stable crosslinked structure in the molecular. However, the cross-linking of thermosetting materials is an irreversible process, and once formed, it cannot be reprocessed and recycled anymore, which will not only cause great waste of resources and environmental pollution, but also limit the application of thermosetting materials in some fields. Polymers containing dynamic reversible covalent bonds can form covalent adaptable networks which endow these polymers with interesting properties for material processing such as reshaping, reprocessing and recycling. Covalent adaptable networks can be classified as dissociative and associative covalent adaptable networks according to the exchange mechanism. Based on associative covalent adaptable networks, a new class of polymer was synthesized named as vitrimer. Vitrimers have attracted wide attention for their unique properties and defined as the third class of polymer materials besides thermosetting and thermoplastic materials. This paper mainly introduces the different exchange reaction mechanisms and research progress of classic vitrimer materials and vitrimer-like materials.This paper introduces the research background and characteristics of vitrimer materials, classic vitrimer materials and vitrimer-like materials are divided according to whether can completely meet the performance requirements of vitrimer. The research progress of vitrimer materials based on different exchange mechanisms in recent years are discussed, and forecasts the development prospect of such materials.

Key words： vitrimer dynamic covalent bond selh-healing covalent adaptable network

Published: 01 July 2020

CLC number:

TQ317

About author:: Lisheng Zhou received his Ph. D. degree in chemistry from Northwestern Polytechnical University in 2018. Now he is the assistant research fellow of Xi'an Modern Chemistry Research Institute. His current research work is mainly focused on the self-healing materials and solid propellant coating ; Shishan Yang received his Ph. D. degree in applied chemistry from Xi'an Modern Chemistry Research Institute in 2011. Now he works as research fellow at Xi'an Modern Chemistry Research Institute. His research field including solid propellant charge, formula and process of solid propellant coatings.

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	ZHOU Lisheng
	LIU Jianxia
	WU Shuxin
	CHEN Guohui
	YANG Shishan
	YANG Libo

Cite this article:

ZHOU Lisheng,LIU Jianxia,WU Shuxin, et al. Research Progress of Vitrimer Materials[J]. Materials Reports, 2020, 34(Z1): 585-591.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2020/V34/IZ1/585

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