二维材料的合成方法及在催化领域应用的研究进展

doi:10.11896/cldb.19030253

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Abstract As one of the important means in the field of energy conversion and environmental pollution control, catalytic technology has played a huge role in improving the quality of human living environment. With the deepening of practical application requirements, researchers are committed to developing new catalytic materials with larger specific surface area, more highly exposed reaction sites and shorter reactant/product diffusion pathways.
Low-dimensional nanomaterials induce rich physical and chemical properties due to the reduction in dimensions. The two-dimensional (2D) nanomaterials benefit from theirs ultra-thin layered structure, large specific surface area, high density of surface active sites, excellent photoelectric and mechanical properties, and easy interface transmission and shorter diffusion, which is suitable for being used as a catalyst. In recent years, researchers have been working on the development of new 2D materials, actively researching the unique advantages of 2D materials in the field of catalysis, and optimizing their synthesis methods in order to achieve large-scale applications as early as possible.
At present, various 2D materials such as graphene, black phosphorus (BP), transition metal sulfides (TMDs), transition metal oxides (TMOs), and layered double hydroxides (LDHs) have been discovered. Top-down peeling method (micromechanical cleavage, oxidation/reduction-based intercalation-assisted exfoliation, mechanical force-assisted exfoliation, ion exchange-assisted exfoliation, and etching-assisted exfoliation) and bottom-up controllable synthesis strategies (chemical vapor deposition and wet chemical methods) were applied to prepare higher quality ultra-thin 2D nanomaterials according to whether the bulk materials have a layered structure. However, the research on 2D materials is still not mature enough. The yield and quality are far away from industrialization and commercialization. At the same time, micro-fine control of 2D material properties is needed to further optimize its catalytic performance. Due to their highly exposed surface atoms, excellent electronic properties and mechanical properties, in energy catalytic reactions such as hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO₂RR), etc., and environmental catalytic reactions such as selective catalytic reduction (SCR) and catalytic conversion of volatile organic compounds (VOC) exhibit excellent catalytic performance. And the micro-fine control of 2D material properties can be carried out through surface modification/functionalization and phase engineering strategies to further optimize its catalytic performance.
Based on the classification, characteristics and application fields of 2D materials, this paper focuses on the structural characteristics and synthesis methods of 2D materials, summarizes their research hotspots and progress in the field of catalysis, and proposes prospects for the research and application of 2D materials in the field of catalysis.

Key words： two-dimensional material controllable synthesis catalytic reaction layered structure catalytic performance

Published: 24 June 2020

CLC number:

X511

Fund:National Natural Science Foundation of China (51808037, 21806009), China Postdoctoral Science Foundation (2019T120049, 2018M631344)

About author:: Chen Yanggraduated from the School of Environmental and Municipal Engineering of North China University of Water Resources and Electric Power in June 2018. She is currently a master student of the School of Energy and Environmental Engineering, University of Science and Technology Beijing, and is conducting research in the academic echelon of air pollution control and resource management conducted by Prof. Tang Xiaolong. Her main research has focused on two-dimensional metal oxide denitration catalysts.
Xiaolong Tangreceived his master’s degree from Kunming University of Science and Technologyin in 1999, and received his Ph.D. degree in Environmental Engineering from Beijing Institute of Technology (co-trai-ning with Tsinghua University) in 2006. He is currently a full professor in University of Science and Technology Beijing. His research focuses on air pollution control technology, industrial waste gas recycling, and environmental functional materials. He has published more than 200 papers, including more than 90 research papers published by the first or corresponding author in SCI academic journals such as Chemical Engineering Journal, Journal of Hazardous Material, Ultrasonics Sonochemistry and Journal of Cleaner Production, and authorized more than 20 invention patents, published 4 books.

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	YANG Chen
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	YU Qingjun
	ZHAO Shunzheng

Cite this article:

YANG Chen,GAO Fengyu,TANG Xiaolong, et al. Review on the Synthesis Techniques of Two-dimensional Materials and Their Application in the Field of Catalysis[J]. Materials Reports, 2020, 34(13): 13005-13016.

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http://www.mater-rep.com/EN/10.11896/cldb.19030253 OR http://www.mater-rep.com/EN/Y2020/V34/I13/13005

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