Ni-BaCe0.7Y0.3-xTaxO3-δ(x=0,0.05,0.1)金属陶瓷氢分离膜的氢渗透性能

doi:10.11896/cldb.19040122

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (4019KB)

Suppl. Info.
Export: BibTeX | EndNote (RIS)

Abstract With a 100% selectivity for hydrogen,the proton-electron mixed conducting separation membranes have great potential in the application of hydrogen separation and purification. Ni-BaCe_0.7Y_0.3-xTa_xO_3-δ (x=0, 0.05, 0.1) cermet hydrogen separation membranes were prepared by liquid phase method, and the hydrogen permeability and stability of the cermet membrane were tested. Both the conductivity and hydrogen permeability of BaCe_0.7Y_0.3-xTa_xO_3-δ (x=0, 0.05, 0.1) decrease under the wet 20vol% H₂+80vol% N₂ atmosphere with the increase of Ta element doping amount, which increases with increasing temperature. In the feed gas containing 3vol% CO₂ and 10vol% CO₂, the hydrogen permeability of Ni-BaCe_0.7Y_0.2Ta_0.1O_3-δ remained nearly stable, while the hydrogen permeability of Ni-BaCe_0.7Y_0.3O_3-δ and Ni-BaCe_0.7Y_0.25Ta_0.05O_3-δ increase continually. This may be because the reaction between BaCe_0.7Y_0.3-xTa_xO_3-δ(x=0, 0.05) and CO₂ is more severe and the product generated is not dense, which causes the effective thickness of the sample is reduced.

Key words： cermet hydrogen separation membrane conductivity hydrogen permeability stability

Published: 29 May 2020

CLC number:	O614
	TM911

Fund:This work was financially supported by the National Natural Science Foundation Youth Fund of China (21506168), Natural Science Basic Research Plan in Shaanxi Province of China (2015JQ5168).

About author:: Qiang Lyu studying at the College of Materials Science and Engineering, Xi'an University of Architecture and Technology, mainly engaged in the preparation and application of proton conductors of perovskite structure.
Chunli Yang received her Ph.D. degree in materials from University of Science and Technology of China in July 2010. She is currently an associate professor in College of Materials Science and Engineering, Xi'an University of Architecture and Technology and participates in the development of hollow fiber tubes, mixed conductor gas separation membranes, and preparation and characterization of solid oxide fuel cells.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LYU Qiang
	YANG Chunli
	CHEN Hong
	MA Xinyu
	CHEN Xi
	ZHANG Qiang
	DU Jing

Cite this article:

LYU Qiang,YANG Chunli,CHEN Hong, et al. Hydrogen Permeability of Ni-BaCe_0.7Y_0.3-xTa_xO_3-δ (x=0, 0.05, 0.1) Cermet Hydrogen Separation Membranes[J]. Materials Reports, 2020, 34(12): 12045-12049.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.19040122 OR http://www.mater-rep.com/EN/Y2020/V34/I12/12045

1 Tao Z T, Yan L T, Qiao J L, et al. Progress in Materials Science,2015,74,1.
2 Barretpa L, Makihira A, Riahia K. International Journal of Hydrogen Energy,2003,28,267.
3 Vispute T P, Zhang H, Sanna A, et al. Science,2010,330,1222.
4 Barelli L, Bidini G, Gallorini F, et al. Energy,2008,33,554.
5 Tuiner J A. Science,2004,305(5686),972.
6 Lu G Q, Diniz D C J C, Duke M, et al. Journal of Colloid and Interface Science,2007,314,589.
7 Gore C M, White J O, Wachsman E D, et al. Journal of Materials Che-mistry A,2014,7,2363.
8 Magraso A, Hervoches C H, Ahmed I, et al. Journal of Materials Che-mistry A,2013,11,3774.
9 Magraso A, Haugsrud R. Journal of Materials Chemistry A,2014,32,12630.
10 Amsif M, Magraso A, Marrero-Lopez D, et al. Chemistry of Materials,2012,24,3868.
11 Escolastico S, Somacescu S, Serra J M. Chemistry of Materials,2014,26,982.
12 Escolastico S, Solis C, Kjolseth C, et al. Energy & Environmental Science,2014,7,3736.
13 Escolastico S, Seeger J, Roitsch S, et al. ChemSusChem,2013,6,1523.
14 Seeger J, Ivanova M E, Meulenberg W A, et al. Inorganic Chemistry,2013,52,10375.
15 Holt D, Forster E, Ivanova M E, et al. Journal of the European Ceramic Society,2014,34,2381.
16 Fang S M. Study on hydrogen permeation performance and stability of dense cermet composite membrane. Ph.D. Thesis, University of Science and Technology of China, China,2008(in Chinese).
方曙民.致密金属陶瓷复合膜的氢渗透性能和稳定性研究.博士学位论文,中国科学技术大学,2008.
17 Kim H, Kim B, Lee J, et al. Ceramics International,2014,40(3),4117.
18 Medvedev D, Murashkina A, Pikalova E, et al. Progress in Materials Science,2014,60(3),72.
19 Phair J W, Badwal S P S. Ionics,2006,12(12),103.
20 Zakowsky N, Williamson S, Irvine J T S. Solid State Ionics,2005,176(39),3019.
21 Tanner C W, Virkar A V. Journal of the Electrochemical Society,1996,143(4),1386.
22 Bi L, Zhang S Q, Fang S M, et al. Electrochemistry Communications,2008,10(10), 1598.
23 Bi L, Fang S M, Tao Z T, et al. Journal of the European Ceramic Society,2009,29(12),2567.
24 Bi Lei. Preparation and electrochemical study of proton conductor solid oxide fuel cell. Ph.D. Thesis, University of Science and Technology of China, China,2009(in Chinese).
毕磊.质子导体固体氧化物燃料电池的制备及其电化学研究.博士学位论文,中国科学技术大学,2008.
25 Lv Q, Yang C L, Ma X Y, et al. Journal of Functional Materials,2018,4(49),4161(in Chinese).
吕强,杨春利,马欣宇,等.功能材料,2018,4(49),4161.
26 Radojkovic A, Zunic M, Savic S M, et al. Ceramics International,2013,39,307.
27 Xie K, Zhou J, Meng G. Journal of Alloys and Compounds,2010,506,8.
28 Kreure K D, Dippel T, Yu M, et al. Solid State Ionics,1996,86-88(1),613.
29 Kreure K D, Adams S, Munch W, et al. Solid State Ionics,2001,145(1-4),295.
30 Kreure K D, Schonherr E, Maier J. Solid State Ionics,1994,70-71(1),278.
31 Wang S W, Zhang L, Zhang L L, et al. Electrochimica Acta,2013,87,194.
32 Norby T, Larring Y. Solid State Ionics,2000,136-137(1-2),139.