INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
Effect of CoO and Cr2O3 Composite Doping on Densification and High-temperature Oxidation Resistance of Cermets |
LIN Qiquan, ZHOU Hang, DONG Wenzheng, QING Chunkai
|
Hunan Key Laboratory of Welding Robots and Applied Technologies, Xiangtan University, Xiangtan 411105, China |
|
|
Abstract The 17Ni/ (10NiO-NiFe2O4) cermets doped with CoO and Cr2O3 compound additives were prepared by powder metallurgy method. XRD, SEM and other means of detection and analysis were used to explore the impact of the CoO and Cr2O3 compound doped on 17Ni/ (10NiO-NiFe2O4) cermet on the phase composition, microstructure, sintering densification and high temperature oxidation resistance. The results showed that CoO and Cr2O3 become solid solution in the NiFe2O4 lattice after composite doping, accelerated the sintering-densification.The CoO and Cr2O3 complex additives helped 17Ni/ (10NiO-NiFe2O4) cermet form a dense oxide layer,which can reduce the diffusion rate of O2 and me-tal Ni,and improved the high temperature oxidation resistance. When the composite doped amount of CoO and Cr2O3 is 1wt% (m (CoO)∶m (Cr2O3)=2∶1),the sample has the best high temperature oxidation resistance, which the oxidation weight gain per unit was 56.28% less than the undoped sample.
|
Published: 12 March 2020
|
|
Fund:This work was financially supported by the Special Project on International Cooperation of the Ministry of Science and Technology (2010DFA52130),National Natural Science Foundation of China (51575467). |
About author:: Qiquan Lin, professor, doctoral supervisor, Xiangtan University. Focusing on the research of metal plastic forming theory and simulation technology, plate forging technology and preparation of special materials; Wenzheng Dong, associate professor, Xiangtan University. Focusing on the research of advanced plastic processing technology and equipment, plastic proces-sing friction and lubrication. |
|
|
1 Jiang Y J.World Nonferrous Metals,2007 (11),15 (in Chinese). 姜玉敬.世界有色金属,2007 (11),15. 2 He H B,Zhou K C,Li Z Y,et al. Transacation of Nonferrous Metals Society of China,2008,5, 1134. 3 Tian Z L,Lai Y Q,Li J,et al.Journal of Central South University (Science and Technology), 2004, 35 (6),902 (in Chinese). 田忠良, 赖延清, 李劼, 等.中南大学学报 (自然科学版), 2004, 35 (6),902. 4 Xiong H W. A study on oxidation and molten salt corrosion behavior of Cu-Ni/ (10NiO-NiFe2O4) cermets.Master's Thesis, Central South University, China,2012 (in Chinese). 熊慧文. Cu-Ni/ (10NiO-NiFe2O4)金属陶瓷的氧化与熔盐腐蚀行为的研究. 硕士学位论文,中南大学, 2012. 5 Zhang G,Li J,Lai Y Q,et al.Acta Materiae Compositae Sinica, 2007 (6),110 (in Chinese). 张刚, 李劼, 赖延清,等. 复合材料学报, 2007 (6),110. 6 Wang Q P,Liu L H,Wu W H,et al.China Ceramics, 2013 (3),21 (in Chinese). 王黔平,刘立红, 吴卫华, 等. 中国陶瓷, 2013 (3),21. 7 Xi J H,Yao G C,Liu Y H,et al.Journal of Northeastern University (Natural Science), 2006 (3),296 (in Chinese). 席锦会, 姚广春, 刘宜汉, 等. 东北大学学报, 2006 (3),296. 8 Lin Q Q,Yang F,Dong W Z,et al.Materials Reports B:Research Papers, 2016,30 (11),133 (in Chinese). 林启权, 阳菲, 董文正, 等. 材料导报:研究篇, 2016,30 (11),133. 9 Wu H M,Li Z Y,Gan X P,et al.Materials Science and Engineering of Powder Metallurgy, 2011 (2),206 (in Chinese). 吴海明, 李志友, 甘雪萍,等.粉末冶金材料科学与工程, 2011 (2),206. 10 Liu B H,Lin Q Q,Liu J P,et al.Journal of Chinese Electron Microscopy Society, 2017 (4),342 (in Chinese). 刘槟赫, 林启权, 刘建鹏, 等. 电子显微学报, 2017 (4),342. 11 Lin Q Q,Zhao X,Jiang T,et al.The Chinese Journal of Nonferrous Metals, 2015 (5),1270 (in Chinese). 林启权, 赵爽, 姜滔, 等.中国有色金属学报, 2015 (5),1270. 12 Shi D K.Material science foundation,China Machine Press,China,2003. 石德珂.材料科学基础,机械工业出版社,2003. 13 Shao M L,Hou X Q,Zhang X S,et al.Ceramics Science & Art,1998 (2),3 (in Chinese). 邵明梁,侯宪钦,章希胜,等.陶瓷工程,1998 (2),3. 14 Li W, Zhang G, Li J, et al. JOM, 2009,61 (5),39. 15 Lin Q Q,Long Y P. Journal of the Chinese Ceramic Society,2014 (12),1537 (in Chinese). 林启权, 龙燕萍.硅酸盐学报, 2014 (12),1537. |
|
|
|